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Volume 102
Main Index

Issue 1


Nuclear spin-spin coupling via nonbonded interactions. 1. Conformational and substituent effects on vicinal carbon-13-proton and carbon-13-carbon-13 coupling constants
Michael Barfield
pp 1 - 7; DOI:
10.1021/ja00521a001
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Nuclear spin-spin coupling via nonbonded interactions. 2. .gamma.-Substituent effects for vicinal coupling constants involving carbon-13
M. Barfield, J. L. Marshall, and E. D. Canada
pp 7 - 12; DOI:
10.1021/ja00521a002
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A study of the conformation of 2-dialkylamino-1,3-dimethyl-1,3,2-diazaphospholanes by dynamic carbon-13 NMR and nitrogen-15 NMR
J. H. Hargis, W. B. Jennings, S. D. Worley, and M. S. Tolley
pp 13 - 17; DOI:
10.1021/ja00521a003
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Carbon-13 nuclear magnetic resonance spectroscopy of naturally occurring substances. 68. An unusual solvent dependence of the carbon-13 nuclear magnetic resonance spectral features of some glycosides as studied by relaxation-time measurements
Nera Bellavita, Jean Marie Bernassau, Paolo Ceccherelli, Muppala S. Raju, and Ernest Wenkert
pp 17 - 20; DOI:
10.1021/ja00521a004
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Oxygen-17 NMR studies of carbonic anhydrase
K. D. Rose and R. G. Bryant
pp 21 - 24; DOI:
10.1021/ja00521a005
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Fast and slow conformational fluctuations of RNA and DNA. Subnanosecond internal motion correlation times determined by phosphorus-31 NMR
Philip H. Bolton and Thomas L. James
pp 25 - 31; DOI:
10.1021/ja00521a006
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Solution characterization of "intermediate-spin" iron(III) porphyrins by NMR spectroscopy
Harold Goff and Eric Shimomura
pp 31 - 37; DOI:
10.1021/ja00521a007
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Vibrational spectra and a potential function for the monofluorocyclopropenyl-d0 and -d2 cations
Norman C. Craig, Ronnie K. Y. Lai, Lawrence G. Matus, J. Houston Miller, and Stephen L. Palfrey
pp 38 - 46; DOI:
10.1021/ja00521a008
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A UV photoelectron spectroscopic investigation of the bonding in some tri-, tetra-, and pentacoordinated dialkylamino compounds of chromium, molybdenum, niobium, and tantalum
M. H. Chisholm, A. H. Cowley, and M. Lattman
pp 46 - 50; DOI:
10.1021/ja00521a009
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Helium (HeI) and (HeII) photoelectron spectra of alloxazines and isoalloxazines
Jan K. Eweg, Franz Mueller, Henk Van Dam, Andries Terpstra, and Ad Oskam
pp 51 - 61; DOI:
10.1021/ja00521a010
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Picosecond laser photophysics. Group 3A phthalocyanines
James H. Brannon and Douglas Magde
pp 62 - 65; DOI:
10.1021/ja00521a011
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Photocalorimetric studies of singlet oxygen reactions
John Olmsted
pp 66 - 71; DOI:
10.1021/ja00521a012
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Relative rates and kinetic isotope effects of reactions in solution
Joseph R. Murdoch
pp 71 - 78; DOI:
10.1021/ja00521a013
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Kinetic isotope-effect probes of transition-state structure. Vibrational analysis of model transition states for carbonyl addition
John L. Hogg, James Rodgers, Ildiko Kovach, and Richard L. Schowen
pp 79 - 85; DOI:
10.1021/ja00521a014
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p.pi.p.pi. Interactions in organic molecules. 3. Theoretical search for a new nonclassical carbonium ion: the .sigma.-allyl cation
Kenny B. Lipkowitz, Raima M. Larter, and Donald B. Boyd
pp 85 - 92; DOI:
10.1021/ja00521a015
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Organized monolayers by adsorption. 1. Formation and structure of oleophobic mixed monolayers on solid surfaces
Jacob Sagiv
pp 92 - 98; DOI:
10.1021/ja00521a016
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Molecular structure of 1,8-bis(trimethylelement)naphthalenes
John F. Blount, Franco Cozzi, James R. Damewood, Linda D. Iroff, Ulf Sjostrand, and Kurt Mislow
pp 99 - 103; DOI:
10.1021/ja00521a017
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Conditions favoring retention of configuration in SN2 reactions. A perturbational study
Nguyen Trong Anh and Christian Minot
pp 103 - 107; DOI:
10.1021/ja00521a018
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The perpendicular conformation of 2-hydroxythiophenol. Intramolecular hydrogen bonding to a specific lone pair
Ted Schaefer, Timothy A. Wildman, and Salman R. Salman
pp 107 - 110; DOI:
10.1021/ja00521a019
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Magnetic exchange in transition metal complexes. 12. Calculation of cluster exchange coupling constants with the X.alpha.-scattered wave method
A. P. Ginsberg
pp 111 - 117; DOI:
10.1021/ja00521a020
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Polarity of chemical bonds via hyperpolarizabilities. Determination of the direction of the phosphorus-hydrogen bond dipole of lithium dihydrogen phosphite from measurements of nonlinear optical coefficients
J. G. Bergman, A. P. Ginsberg, and M. Maurin
pp 118 - 122; DOI:
10.1021/ja00521a021
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Spin inversion in triplet Diels-Alder reactions
Sason S. Shaik and Nicolaos D. Epiotis
pp 122 - 131; DOI:
10.1021/ja00521a022
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Interactions of gallium(III) with bleomycin antibiotics
Robert E. Lenkinski, Brian E. Peerce, Jerry L. Dallas, and Jerry D. Glickson
pp 131 - 135; DOI:
10.1021/ja00521a023
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Dynamic features of the ethylenediaminetetraacetate complexes of calcium, strontium, barium, and cobalt(II) in aqueous solutions studied by the ultrasonic absorption method
Shoji Harada, Yoshinori Funaki, and Tatsuya Yasunaga
pp 136 - 139; DOI:
10.1021/ja00521a024
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Triligating 11-membered rings containing tert-phosphino sites. Synthesis and structure
Evan P. Kyba, A. Meredith John, S. Bruce Brown, Carl W. Hudson, Michael J. McPhaul, Adrienne Harding, Katharine Larsen, Suzanne Niedzwiecki, and Raymond E. Davis
pp 139 - 147; DOI:
10.1021/ja00521a025
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Studies of solution character by molecular spectroscopy. 8. Ion sites in solutions of sodium tetracarbonylcobaltate in several solvents doped with cryptand C221
Walter Edgell and Soun Chanjamsri
pp 147 - 155; DOI:
10.1021/ja00521a026
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Paramagnetic organometallic molecules. 9. Metal-metal interaction in X2Co2(CO)6. Analysis of the ESR spectra of [RC2R']Co2(CO)6-.cntdot.
Barrie M. Peake, Philip H. Rieger, Brian H. Robinson, and Jim Simpson
pp 156 - 163; DOI:
10.1021/ja00521a027
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The methylmercury heavy atom effect. Phosphorescence polarization and triplet spin sublevel radiative activities of the methylmercury(II)-benzimidazole and methylmercury(II)-tryptophan complexes
R. R. Anderson and A. H. Maki
pp 163 - 167; DOI:
10.1021/ja00521a028
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Spectroscopic studies of stellacyanin, plastocyanin, and azurin. Electronic structure of the blue copper sites
Edward I. Solomon, Jeffrey W. Hare, David M. Dooley, John H. Dawson, Philip J. Stephens, and Harry B. Gray
pp 168 - 178; DOI:
10.1021/ja00521a029
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Acetylene and ethylene complexes of copper and silver atoms. Matrix isolation ESR study
Paul H. Kasai, D. McLeod, and T. Watanabe
pp 179 - 190; DOI:
10.1021/ja00521a030
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A convenient synthesis of cyclopentanones via rhodium(I)-catalyzed intramolecular hydroacylation of unsaturated aldehydes
R. C. Larock, K. Oertle, and G. F. Potter
pp 190 - 197; DOI:
10.1021/ja00521a031
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Porphyrins. 39. Ammine and nitridoosmium porphyrins. Ligand effects on the electronic structure of osmium octaethylporphyrins
Artemis Antipas, Johann W. Buchler, Martin Gouterman, and Paul D. Smith
pp 198 - 207; DOI:
10.1021/ja00521a032
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Transition metal hydrides as electron donors. Formation, detection, and dimerization of transient, paramagnetic radical cations from the electrochemical oxidation of tungstenocene hydrides and the crystal structure of the binuclear (Cp2W)2H3+ product
R. J. Klingler, J. C. Huffman, and J. K. Kochi
pp 208 - 216; DOI:
10.1021/ja00521a033
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Mechanism of formation of Grignard reagents. Kinetics of reaction of alkyl halides in diethyl ether with magnesium
Harold R. Rogers, Craig L. Hill, Yuzo Fujiwara, Randall J. Rogers, H. Lee Mitchell, and George M. Whitesides
pp 217 - 226; DOI:
10.1021/ja00521a034
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Mechanism of formation of Grignard reagents. The rate of reaction of cyclopentyl bromide with magnesium is transport limited in diethyl ether
Harold R. Rogers, John Deutch, and George M. Whitesides
pp 226 - 231; DOI:
10.1021/ja00521a035
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Mechanism of formation of Grignard reagents. Kinetics of reaction of substituted aryl bromides with magnesium and with tri-n-butyltin hydride in ethereal solvents
Harold R. Rogers, Randall J. Rogers, H. Lee Mitchell, and George M. Whitesides
pp 231 - 238; DOI:
10.1021/ja00521a036
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Reductive cleavage of carbon-halogen bonds by tri-n-butyltin hydride, lithium 4,4'-dimethylbenzophenone ketyl, and metallic magnesium
James J. Barber and George M. Whitesides
pp 239 - 243; DOI:
10.1021/ja00521a037
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Reaction of 1,1-dichloro-2,2-difluoroethylene with alkyl Grignard reagents. Evidence for radical reaction involving .beta.-hydrogen atom abstraction from Grignard reagents. Implication regarding the mechanism of reduction by Grignard reagents
Kunio Okuhara
pp 244 - 252; DOI:
10.1021/ja00521a038
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Studies on organic fluorine compounds. 28. Synthesis and some reactions of tetrakis(trifluoromethyl)-1,4-diphosphabenzene
Yoshiro Kobayashi, Hiroshi Hamana, Shomi Fujino, Akio Ohsawa, and Itsumaro Kumadaki
pp 252 - 255; DOI:
10.1021/ja00521a039
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Laser-stimulated chemical reaction of iodine + acetylene
Vikram S. Kushawaha
pp 256 - 258; DOI:
10.1021/ja00521a040
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Decomposition of azocumene on silica surfaces
J. E. Leffler and J. J. Zupancic
pp 259 - 267; DOI:
10.1021/ja00521a041
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Mechanism of hydrolysis of allenyl acetates
Doris J. Scheffel, A. Randolph Cole, Dorothy M. Jung, and M. D. Schiavelli
pp 267 - 270; DOI:
10.1021/ja00521a042
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Gas-phase nitrosation of benzene. Implications for solution electrophilic aromatic substitution reactions
W. D. Reents and B. S. Freiser
pp 271 - 276; DOI:
10.1021/ja00521a043
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Dimerization and cycloaddition reactions of a trimethylenemethane derivative, 2-isopropylidenecyclopenta-1,3-diyl. Mechanistic separation of triplet and singlet reactions
Leonard R. Corwin, Dale M. McDaniel, Richard J. Bushby, and Jerome A. Berson
pp 276 - 287; DOI:
10.1021/ja00521a044
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Reaction of ozonide with antimony pentachloride or chlorosulfuric acid. Participation of antimony pentachloride-complexed or protonated carbonyl oxide
Masahiro Miura and Masatomo Nojima
pp 288 - 291; DOI:
10.1021/ja00521a045
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Intramolecular electrostatic and general acid catalysis in the hydrolysis of O,S-thioacetals
Thomas H. Fife and Theodore J. Przystas
pp 292 - 299; DOI:
10.1021/ja00521a046
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Electron-donating properties of oxygen vs. sulfur. Redox potentials for some pyrylium and thiapyrylium salts
F. D. Saeva and G. R. Olin
pp 299 - 303; DOI:
10.1021/ja00521a047
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Reactivity in methyl transfer reactions. 4. Powerful methylating agents with neutral nucleophiles
Edward S. Lewis, Semyon Kukes, and Carl D. Slater
pp 303 - 306; DOI:
10.1021/ja00521a048
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Chemiluminescence of dimethyldioxetanone. Unimolecular generation of excited singlet and triplet acetone. Chemically initiated electron-exchange luminescence, the primary light generating reaction
Steven P. Schmidt and Gary B. Schuster
pp 306 - 314; DOI:
10.1021/ja00521a049
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Absence of stereoelectronic control in the photochemistry of two diastereomeric .beta.,.gamma.-epoxy ketones
Semiramis Ayral-Kaloustian and William C. Agosta
pp 314 - 323; DOI:
10.1021/ja00521a050
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Solid-state photooligomerization of an extended chiral bifunctional monomer, (+)-2,4:3,5-di-O-methylene-D-mannitol 1,6-di-trans-cinnamate
Joel Bernstein, Bernard S. Green, and Miriam Rejto
pp 323 - 328; DOI:
10.1021/ja00521a051
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Kinetic applications of electron paramagnetic resonance spectroscopy. 35. The search for a dialkylaminyl rearrangement. Ring opening of N-cyclobutyl-N-n-propylaminyl
Y. Maeda and K. U. Ingold
pp 328 - 331; DOI:
10.1021/ja00521a052
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Propellanes. 13. Magnitude of the norcaradiene-cycloheptatriene energy difference
Philip M. Warner and Shih-Lai Lu
pp 331 - 337; DOI:
10.1021/ja00521a053
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A stereoselective total synthesis of the Prelog-Djerassi lactone
Paul A. Bartlett and Jerry L. Adams
pp 337 - 342; DOI:
10.1021/ja00521a054
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Stereospecificity in the oxidation of NADH by flavopapain
Howard L. Levine and E. T. Kaiser
pp 343 - 345; DOI:
10.1021/ja00521a055
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Oxygen exchange as a function of epimerization of 15(R)- and 15(S)-methylprostaglandin E2. Evidence for asymmetric carbonium ion intermediates
Margaret V. Merritt, George E. Bronson, Lubomir Baczynskyj, and James R. Boal
pp 346 - 351; DOI:
10.1021/ja00521a056
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Direct formation of the steroid nucleus by a biomimetic cyclization
William S. Johnson, Brian E. McCarry, R. L. Markezich, and Sharon G. Boots
pp 352 - 359; DOI:
10.1021/ja00521a057
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A spectrophotometric method for studying the rates of reaction of disulfides with protein thiol groups applied to bovine serum albumin
Janet M. Wilson, Dorothy Wu, Rossana Motiu-DeGrood, and D. J. Hupe
pp 359 - 363; DOI:
10.1021/ja00521a058
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Octaethylisobacteriochlorin, a model of the sirohydrochlorin ring system of siroheme enzymes: preparation and spectroscopic and electrochemical properties of the free base and its zinc(II) complex
Alan M. Stolzenberg, Larry O. Spreer, and R. H. Holm
pp 364 - 370; DOI:
10.1021/ja00521a059
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Lifetime of chlorophyll a radical cation in water-containing acetonitrile
Tadashi Watanabe and Kenichi Honda
pp 370 - 372; DOI:
10.1021/ja00521a060
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Organic photochemistry. 44. Intramolecular aryl-assisted photolytic cleavage of 2-benzonorbornenyl derivatives. A high excited-state exo/endo reactivity ratio and a novel Wagner-Meerwein rearrangement
Harry Morrison and Alan Miller
pp 372 - 373; DOI:
10.1021/ja00521a061
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Functionalized nitrones. A highly stereoselective and regioselective synthesis of dl-retronecine
Joseph J. Tufariello and George E. Lee
pp 373 - 374; DOI:
10.1021/ja00521a062
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Structural dependence of oxygen-18 isotope shifts in carbon-13 NMR spectra
John C. Vederas
pp 374 - 376; DOI:
10.1021/ja00521a063
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Disproportionation of trimethylsilyl at 25.degree.C. Mercury photosensitization of trimethylsilane
S. K. Tokach and R. D. Koob
pp 376 - 377; DOI:
10.1021/ja00521a064
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Disproportionation of trimethylsilyl radicals to a sila olefin in the liquid phase
Becky J. Cornett, Kwang Yul Choo, and Peter P. Gaspar
pp 377 - 378; DOI:
10.1021/ja00521a065
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Disproportionation and hydrogen abstraction reactions of trimethylsilyl radicals
L. Gammie, I. Safarik, O. P. Strausz, R. Roberge, and C. Sandorfy
pp 378 - 380; DOI:
10.1021/ja00521a066
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Chemical geometrodynamics: gravitational fields can influence the course of prochiral chemical reactions
Ralph C. Dougherty
pp 380 - 381; DOI:
10.1021/ja00521a067
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Asymmetric synthesis in a confined vortex: gravitational fields can cause asymmetric synthesis
Deborah Edwards, Keith Cooper, and Ralph C. Dougherty
pp 381 - 382; DOI:
10.1021/ja00521a068
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Stereochemically nonrigid silanes, germanes, and stannanes. 7. Mechanism of metallotropic shifts in fluxional monohaptocyclopentadienyl metal derivatives
Rupert D. Holmes-Smith and Stephen R. Stobart
pp 382 - 384; DOI:
10.1021/ja00521a069
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Proton NMR assignment of the C-5' protons of B12 coenzyme and the synthesis of B12 coenzyme chirally labeled in the C-5' position
Alex Cheung, Ronald Parry, and Robert H. Abeles
pp 384 - 385; DOI:
10.1021/ja00521a070
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Rediscovery of the gas-phase chemistry of difluorosilylene generated by thermal reduction
Tsai-Lih Hwang and Chao-Shiuan Liu
pp 385 - 386; DOI:
10.1021/ja00521a071
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Mechanisms of photooxygenation. 1. Substituent effects on the [2 + 2] cycloaddition of singlet oxygen to vinyl ethers
K. A. Zaklika, Bashir Kaskar, and A. Paul Schaap
pp 386 - 389; DOI:
10.1021/ja00521a072
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Mechanisms of photooxygenation. 2. Formation of 1,2-dioxetanes via 9,10-dicyanoanthracene-sensitized electron-transfer processes
A. Paul Schaap, K. A. Zaklika, Bashir Kaskar, and L. W. M. Fung
pp 389 - 391; DOI:
10.1021/ja00521a073
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Electron-transfer photooxidation. 3. Detection of radical-ion intermediates in the cyanoaromatic-sensitized photooxidation of trans- and cis-stilbene
Lonnie T. Spada and Christopher S. Foote
pp 391 - 393; DOI:
10.1021/ja00521a074
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Phenyl participation in the cleavage of .beta.-phenethyl-palladium bonds by cupric chloride
Jan E. Baeckvall and Ruth E. Nordberg
pp 393 - 395; DOI:
10.1021/ja00521a075
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Proton nuclear magnetic resonance characterization of the electronic structure of horseradish peroxidase compound I
Gerd N. La Mar and Jeffrey S. De Ropp
pp 395 - 397; DOI:
10.1021/ja00521a076
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Effect of A(1,3) strain on the stereochemical course of N-acyliminium ion cyclizations
David J. Hart
pp 397 - 398; DOI:
10.1021/ja00521a077
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Stabilities of carbonium ions in solution. 10. A thermochemical comparison of the relative stabilities of long-lived 2-norbornyl and butyl cations in sulfuryl chloride fluoride/antimony pentafluoride
Edward M. Arnett, Norbert Pienta, and Craig Petro
pp 398 - 400; DOI:
10.1021/ja00521a078
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Two-dimensional correlated nuclear magnetic resonance of spin-coupled boron-11-proton systems
David C. Finster, William C. Hutton, and Russell N. Grimes
pp 400 - 401; DOI:
10.1021/ja00521a079
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Preferential anion binding to the lactim tautomers of 2-hydroxypyridines
Olivier Bensaude, Marianne Chevrier, Jean Guillerez, and Jacques Emile Dubois
pp 401 - 403; DOI:
10.1021/ja00521a080
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Nucleo- and electrophilicity of (C5H5)2Mn2(CO)4(.mu.-.eta.1-CCH2). New paths to carbyne and allene ligands
Larry N. Lewis, John C. Huffman, and Kenneth G. Caulton
pp 403 - 404; DOI:
10.1021/ja00521a081
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Cyclic peroxides. 92. Oxygen atom transfer by furan endoperoxides
Waldemar Adam and Augusto Rodriguez
pp 404 - 406; DOI:
10.1021/ja00521a082
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Nucleophilic attacks on carbon-carbon double bonds. 26. Stereoconvergence in nucleophilic vinylic substitution of an activated nitro olefin
Zvi Rappoport and Alain Topol
pp 406 - 407; DOI:
10.1021/ja00521a083
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An experimental study of nucleophilic addition to formaldehyde in the gas phase
D. K. Bohme, G. I. Mackay, and S. D. Tanner
pp 407 - 409; DOI:
10.1021/ja00521a084
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Photochemistry of ketones in solution. 57. Synthesis and photochemistry of a constrained 2-cyclohexenone
David I. Schuster and Saadat Hussain
pp 409 - 410; DOI:
10.1021/ja00521a085
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Electron-beam-induced Wolff rearrangement
J. Pacansky and H. Coufal
pp 410 - 412; DOI:
10.1021/ja00521a086
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Photochemical Wagner-Meerwein rearrangement of 2-diphenylmethylenefenchane
Stephen S. Hixson, Roberta O. Day, Lothar A. Franke, and V. Ramachandra Rao
pp 412 - 413; DOI:
10.1021/ja00521a087
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Perfluorocyclopentadienone
M. W. Grayston, W. D. Saunders, and D. M. Lemal
pp 413 - 414; DOI:
10.1021/ja00521a088
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A fixed-geometry study of the SH2 reaction on the peroxide bond
Ned A. Porter, M. Amelia Cudd, Richard W. Miller, and Andrew T. McPhail
pp 414 - 416; DOI:
10.1021/ja00521a089
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Hydration behavior of chlorophyll a: a field desorption mass spectral study
Ralph C. Dougherty, Peter A. Dreifuss, James Sphon, and Joseph J. Katz
pp 416 - 418; DOI:
10.1021/ja00521a090
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Natural abundance carbon-13 NMR spectroscopy of double-stranded DNA
Randolph L. Rill, Peter R. Hilliard, J. Terry Bailey, and George C. Levy
pp 418 - 420; DOI:
10.1021/ja00521a091
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Synthesis of a nitrogen derivative of closo-2,4-dicarbaheptaborane
Gowit Siwapinyoyos and Thomas Onak
pp 420 - 421; DOI:
10.1021/ja00521a092
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Selective transamination and optical induction by a .beta.-cyclodextrin-pyridoxamine artificial enzyme
Ronald Breslow, Milton Hammond, and Manfred Lauer
pp 421 - 422; DOI:
10.1021/ja00521a093
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Initiation of acetylene polymerization by metal carbenes
Thomas J. Katz and Steven J. Lee
pp 422 - 424; DOI:
10.1021/ja00521a094
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Theoretical calculations of the aqueous medium effects on the basicities of primary amines
M. Taagepera, D. DeFrees, W. J. Hehre, and R. W. Taft
pp 424 - 426; DOI:
10.1021/ja00521a095
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Coupling of nonvicinal glycols by low-valent titanium
Harry M. Walborsky and Martha Pass Murari
pp 426 - 428; DOI:
10.1021/ja00521a096
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Sensitivity enhancement in nitrogen-15 NMR: polarization transfer using the INEPT pulse sequence
Gareth A. Morris
pp 428 - 429; DOI:
10.1021/ja00521a097
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Analysis and optimization of gas-phase reactions. 13. Silatoluene
H. Bock, R. Allen Bowling, B. Solouki, T. J. Barton, and G. T. Burns
pp 429 - 430; DOI:
10.1021/ja00521a098
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Criteria for establishing the existence of nuclear spin isotope effects
Ronald G. Lawler
pp 430 - 431; DOI:
10.1021/ja00521a099
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A copper(I)-bicarbonato complex. A water-stable reversible carbon dioxide carrier
Tetsuo Tsuda, Yoshiki Chujo, and Takeo Saegusa
pp 431 - 433; DOI:
10.1021/ja00521a100
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Book Reviews

pp 433 - 438; DOI:
10.1021/ja00521a600
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Issue 2


The mechanism of the ene reaction of singlet oxygen with olefins
Lawrence B. Harding and William A. Goddard
pp 439 - 449; DOI:
10.1021/ja00522a001
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How some simple solids hold together. The use of the fragment formalism in crystal chemistry
Jeremy K. Burdett
pp 450 - 460; DOI:
10.1021/ja00522a002
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Solid state phase transformation of a diacetylene by solvation. Crystal structure of a moderately reactive monomer form
G. N. Patel, Eileen N. Duesler, David Y. Curtin, and Iain C. Paul
pp 461 - 466; DOI:
10.1021/ja00522a003
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Cation complexing properties of synthetic macrocyclic polyether-diester ligands containing the pyridine subcyclic unit
J. S. Bradshaw, G. E. Maas, J. D. Lamb, R. M. Izatt, and J. J. Christensen
pp 467 - 474; DOI:
10.1021/ja00522a004
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A systematic study of the effect of macrocycle ring size and donor atom type on the log K, .DELTA.H, and T.DELTA.S of reactions at 25.degree.C in methanol of mono- and divalent cations with crown ethers
J. D. Lamb, R. M. Izatt, C. S. Swain, and J. J. Christensen
pp 475 - 479; DOI:
10.1021/ja00522a005
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Cation complexes of crown ether diesters. Stabilities, selectivities, enthalpies, and entropies of reaction at 25.degree.C in methanol
J. D. Lamb, R. M. Izatt, C. S. Swain, J. S. Bradshaw, and J. J. Christensen
pp 479 - 482; DOI:
10.1021/ja00522a006
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Ion and electron transport in stable, electroactive tetrathiafulvalene polymer coated electrodes
F. B. Kaufman, A. H. Schroeder, E. M. Engler, S. R. Kramer, and J. Q. Chambers
pp 483 - 488; DOI:
10.1021/ja00522a007
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The isomer dependence of oscillator strengths in retinal and related molecules. Spectroscopic assignments
Barry Honig, Uri Dinur, Robert R. Birge, and Thomas G. Ebrey
pp 488 - 494; DOI:
10.1021/ja00522a008
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Vibrational optical activity. Circular differential Raman scattering from a series of chiral terpenes
Tom Brocki, Martin Moskovits, and B. Bosnich
pp 495 - 500; DOI:
10.1021/ja00522a009
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Absolute stereochemistry and chiroptical properties of chiral tribenzotriptycene and benzotriptycenes
Nobuyuki Harada, Yasufumi Tamai, Yuki Takuma, and Hisashi Uda
pp 501 - 506; DOI:
10.1021/ja00522a010
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Circular dichroic power of chiral triptycenes
Nobuyuki Harada, Yasufumi Tamai, and Hisashi Uda
pp 506 - 511; DOI:
10.1021/ja00522a011
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Conformation of dimethyl tartrate in solution. Vibrational circular dichroism results
C. N. Su and T. A. Keiderling
pp 511 - 515; DOI:
10.1021/ja00522a012
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A local mode description of the CH-stretching overtone spectra of the cycloalkanes and cycloalkenes
Bryan R. Henry, I-Fu Hung, Richard A. MacPhail, and Herbert L. Strauss
pp 515 - 519; DOI:
10.1021/ja00522a013
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A study of proton relaxation mechanisms, stereochemistry, and dynamics of the decapeptide tyrocidine A
Mei-Chang Kuo, Torbjorn Drakenberg, and William A. Gibbons
pp 520 - 524; DOI:
10.1021/ja00522a014
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Proton and carbon-13 nuclear magnetic resonance studies on purine
Doris M. Cheng, Lou S. Kan, Paul O. P. Ts'o, Claude Giessner-Prettre, and Bernard Pullman
pp 525 - 534; DOI:
10.1021/ja00522a015
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Proton magnetic resonance of NADH in water-methanol mixtures. Conformational change and behavior of exchangeable proton resonances as a function of temperature
James Tropp and Alfred G. Redfield
pp 534 - 538; DOI:
10.1021/ja00522a016
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Proton NMR spectroscopic study of cyclic proton exchange between acetic acid and methanol in tetrahydrofuran-d8
Hans Heinrich Limbach and Wolfgang Seiffert
pp 538 - 542; DOI:
10.1021/ja00522a017
PDF
Quantum and statistical mechanical studies of liquids. 7. Structure and properties of liquid methanol
William L. Jorgensen
pp 543 - 549; DOI:
10.1021/ja00522a018
PDF
Formation of the stable bilayer assemblies in dilute aqueous solution from ammonium amphiphiles with the diphenylazomethine segment
Toyoki Kunitake and Yoshio Okahata
pp 549 - 553; DOI:
10.1021/ja00522a019
PDF
Fluorescence decay of tryptophan conformers in aqueous solution
A. G. Szabo and D. M. Rayner
pp 554 - 563; DOI:
10.1021/ja00522a020
PDF
A photoelectron spectroscopic investigation of tetra-tert-butyltetrahedrane and of tetra-tert-butylcyclobutadiene
Edgar Heilbronner, Taylor B. Jones, Adolf Krebs, Guenther Maier, Klaus Dieter Malsch, Juergen Pocklington, and Andreas Schmelzer
pp 564 - 568; DOI:
10.1021/ja00522a021
PDF
The photoelectron spectrum of the dimethyl ether-hydrogen chloride complex
F. Carnovale, M. K. Livett, and J. B. Peel
pp 569 - 573; DOI:
10.1021/ja00522a022
PDF
Theoretical study of the reaction of water with the 1,3 dipoles fulminic acid and acetonitrile oxide. Concerted reactions with a proton slide at the transition state
M. T. Nguyen, M. Sana, G. Leroy, K. J. Dignam, and A. F. Hegarty
pp 573 - 580; DOI:
10.1021/ja00522a023
PDF
A theoretical study on the photochemical reaction of carbon suboxide with ethylene
Tsutomu Minato, Yoshihiro Osamura, Shinichi Yamabe, and Kenichi Fukui
pp 581 - 589; DOI:
10.1021/ja00522a024
PDF
An intermediate neglect of differential overlap technique for spectroscopy of transition-metal complexes. Ferrocene
Michael C. Zerner, Gilda H. Loew, Robert F. Kirchner, and Ulrich T. Mueller-Westerhoff
pp 589 - 599; DOI:
10.1021/ja00522a025
PDF
Cis-trans photoisomerization in Ru(bpy)2(OH2)22+. Crystal structure of trans-[Ru(bpy)2(OH2)(OH)](ClO4)2
Bill Durham, Scott R. Wilson, Derek J. Hodgson, and Thomas J. Meyer
pp 600 - 607; DOI:
10.1021/ja00522a026
PDF
A linear, trinuclear, mixed-valence chloro complex of ruthenium, [Ru3Cl12]4-
Avi Bino and F. Albert Cotton
pp 608 - 611; DOI:
10.1021/ja00522a027
PDF
Cytochrome oxidase models. 2. .mu.-Bipyrimidyl mixed-metal complexes as synthetic models for the iron/copper binuclear active site of cytochrome oxidase
Randall H. Petty, Byron R. Welch, Lon J. Wilson, Lawrence A. Bottomley, and Karl M. Kadish
pp 611 - 620; DOI:
10.1021/ja00522a028
PDF
Volatility and molecular structure of neptunium(IV) borohydride
Rodney H. Banks, Norman M. Edelstein, Brock Spencer, David H. Templeton, and Allan Zalkin
pp 620 - 623; DOI:
10.1021/ja00522a029
PDF
An NMR spectroscopic and x-ray crystallographic study of the reaction of tris(dimethylamino)chlorosilane with aluminum chloride. A quest for the elusive silicenium cation
A. H. Cowley, M. C. Cushner, and P. E. Riley
pp 624 - 628; DOI:
10.1021/ja00522a030
PDF
Synthesis and crystal structure of bis(triphenylantimony catecholate) hydrate. A new square-pyramidal antimony(V) compound
Michael Hall and D. Bryan Sowerby
pp 628 - 632; DOI:
10.1021/ja00522a031
PDF
Model networks of end-linked polydimethylsiloxane chains. 5. Dependence of the elastomeric properties on the functionality of the network junctions
J. E. Mark and M. A. Llorente
pp 632 - 636; DOI:
10.1021/ja00522a032
PDF
Silver(I) catalyzed rearrangements of strained .sigma. bonds. 38. Regiospecificity of cyclopropylidene carbon-hydrogen insertion reactions within [m.n.1]propellane frameworks
Leo A. Paquette, Ernest Chamot, and Alan R. Browne
pp 637 - 643; DOI:
10.1021/ja00522a033
PDF
Silver(I) catalyzed rearrangements of strained .sigma. bonds. 39. Twofold cyclopropylidene carbon-hydrogen insertion as a route to hexacyclic bis(bicyclo[1.1.0]butanes) and their silver(I) ion promoted rearrangement. A direct synthesis of heptalene from naphthalene
Leo A. Paquette, Alan R. Browne, Ernest Chamot, and John F. Blount
pp 643 - 651; DOI:
10.1021/ja00522a034
PDF
Kinetics of dissociation of potassium and thallium cryptates
R. Gresser, D. W. Boyd, A. M. Albrecht-Gary, and J. P. Schwing
pp 651 - 653; DOI:
10.1021/ja00522a035
PDF
Radical anions of syn- and anti-[2.2](1,4)anthracenophanes studied by electron-nuclear double resonance spectroscopy
Fujito Nemoto, Kazuhiko Ishizu, Toshihiro Toyoda, Yoshiteru Sakata, and Soichi Misumi
pp 654 - 656; DOI:
10.1021/ja00522a036
PDF
Synthesis and characterization of 1,8,15,22-tetraoxa[8.8]paracyclophane-3,5,17,19-tetrayne-10,25-dicarboxylic acid, a novel water-soluble and donut-shaped molecule
E. T. Jarvi and H. W. Whitlock
pp 657 - 662; DOI:
10.1021/ja00522a037
PDF
Orbital interactions. 6. The Birch reduction as a tool for exploring orbital interactions through bonds. Through-three-bond interactions
Michael N. Paddon-Row and Robert Hartcher
pp 662 - 670; DOI:
10.1021/ja00522a038
PDF
Orbital interactions. 7. The Birch reduction as a tool for exploring orbital interactions through bonds. Through-four-, -five-, and -six-bond interactions
Michael N. Paddon-Row and Robert Hartcher
pp 671 - 678; DOI:
10.1021/ja00522a039
PDF
Conversion of benzo- and naphthonorcaradien-7-yl to benzo- and naphthotropyl radicals
Martin Pomerantz and N. L. Dassanayake
pp 678 - 682; DOI:
10.1021/ja00522a040
PDF
Stable carbocations. 210. .sigma.-Bond bridged carbonium ions. 8. The chemistry of protoadamantane. 7. Rapidly equilibrating unsymmetrically bridged 1,3,5,7-tetramethyl- and rapidly equilibrating trivalent 1,2,3,5,7-pentamethyl-2-adamantyl cations. Addivity of carbon-13 NMR chemical shifts relating the classical vs. nonclassical nature of carbocations
Paul v. R. Schleyer, Dieter Lenoir, Pierre Mison, Gao Liang, G. K. Surya Prakash, and George A. Olah
pp 683 - 691; DOI:
10.1021/ja00522a041
PDF
Polar radicals. 14. Mechanism of trialkylstannane reductions. Positive .rho. values for the tri-n-butylstannane reduction of benzyl halides. A correlation with .sigma.-
Edward V. Blackburn and Dennis D. Tanner
pp 692 - 697; DOI:
10.1021/ja00522a042
PDF
Substituent effect on the rate constants for the reactions between benzenethiyl radicals and stable free radicals estimated by flash photolysis
Michiaki Nakamura, Osamu Ito, and Minoru Matsuda
pp 698 - 701; DOI:
10.1021/ja00522a043
PDF
Bredt's rule kinetically stabilized nitrogen-centered radical cations and radicals in the 9-azabicyclo[3.3.1]nonyl system
Stephen F. Nelsen, Carl R. Kessel, and David J. Brien
pp 702 - 711; DOI:
10.1021/ja00522a044
PDF
Cycloaddition reaction of some representative 1-cyclopropyl-1,3-butadienes with tetracyanoethylene and reaction of the resultant vinylcyclobutanes. An easy vinylcyclobutane-cyclohexene rearrangement
Fumio Kataoka, Nobujiro Shimizu, and Shinya Nishida
pp 711 - 716; DOI:
10.1021/ja00522a045
PDF
The ultraviolet transitions of benzoic acid. 3. Effects of hydrogen bonding on the emission properties
J. Clayton Baum
pp 716 - 719; DOI:
10.1021/ja00522a046
PDF
The ultraviolet transitions of benzoic acid. 4. High-resolution spectral studies of hydrogen bonding in the excited states of the benzoic acid dimer
J. Clayton Baum and Donald S. McClure
pp 720 - 727; DOI:
10.1021/ja00522a047
PDF
Photochemistry of 1,5-diaryl-1,5-diketones
J. P. Bays, M. V. Encinas, R. D. Small, and J. C. Scaiano
pp 727 - 734; DOI:
10.1021/ja00522a048
PDF
Photolysis of alkyl azides. Evidence for a nonnitrene mechanism
Evan P. Kyba and Rudolph A. Abramovitch
pp 735 - 740; DOI:
10.1021/ja00522a049
PDF
Kinetics and mechanism of nitromethane chlorination. A new rate expression
Jon A. Orvik
pp 740 - 743; DOI:
10.1021/ja00522a050
PDF
Flash vacuum pyrolysis of 1,3-oxathiolan-5-ones
Tim B. Cameron and Harold W. Pinnick
pp 744 - 747; DOI:
10.1021/ja00522a051
PDF
Preparation of substituted 2-pyridones by thermal rearrangement of propargylic pyrrolidine pseudoureas
Larry E. Overman, Sadao Tsuboi, Jan P. Roos, and Garry F. Taylor
pp 747 - 754; DOI:
10.1021/ja00522a052
PDF
Nucleophilic esterolytic and displacement reactions of a micellar thiocholine surfactant
Robert A. Moss, George O. Bizzigotti, and Ching-Wen Huang
pp 754 - 762; DOI:
10.1021/ja00522a053
PDF
Improved acylation rates within cyclodextrin complexes from flexible capping of the cyclodextrin and from adjustment of the substrate geometry
Ronald Breslow, Michael F. Czarniecki, Jack Emert, and Hiroshi Hamaguchi
pp 762 - 770; DOI:
10.1021/ja00522a054
PDF
1,N6-Etheno-bridged adenines and adenosines. Alkyl substitution, fluorescence properties, and synthetic applications
Prem D. Sattsangi, Jorge R. Barrio, and Nelson J. Leonard
pp 770 - 774; DOI:
10.1021/ja00522a055
PDF
Stereochemical study of the [3,3] sigmatropic rearrangement of 1,5-diene-3-alkoxides. Application to the stereoselective synthesis of (.+-.)-juvabione
David A. Evans and John V. Nelson
pp 774 - 782; DOI:
10.1021/ja00522a056
PDF
Total synthesis of dl-bisnorvernolepin
G. R. Kieczykowski, Martha L. Quesada, and R. H. Schlessinger
pp 782 - 790; DOI:
10.1021/ja00522a057
PDF
The ambient temperature Ullmann reaction and its application to the total synthesis of (.+-.)-steganacin
Frederick E. Ziegler, Irene Chliwner, Kerry W. Fowler, Sheldon J. Kanfer, Stephen J. Kuo, and Nanda D. Sinha
pp 790 - 798; DOI:
10.1021/ja00522a058
PDF
Synthesis of chartreusin aglycone
T. Ross Kelly, Joseph A. Magee, and Franz R. Weibel
pp 798 - 799; DOI:
10.1021/ja00522a059
PDF
Biomimetic polyene cyclizations. Participation of the methylacetylenic terminator and nitroalkanes. A synthesis of testosterone
Michael B. Gravestock, Douglas R. Morton, Sharon G. Boots, and William S. Johnson
pp 800 - 807; DOI:
10.1021/ja00522a060
PDF
Mass spectrometry in structural and stereochemical problems. 254. Elucidation of the course of the electron impact induced fragmentation of .alpha.,.beta.-unsaturated 3-keto steroids
Frederick J. Brown and Carl Djerassi
pp 807 - 817; DOI:
10.1021/ja00522a061
PDF
Proton, deuteron, and carbon-13 ENDOR studies of labeled bis(biphenylenyl)propenyl type radicals in isotropic solutions and in liquid crystals
B. Kirste, H. Kurreck, W. Lubitz, and H. Zimmermann
pp 817 - 825; DOI:
10.1021/ja00522a062
PDF
Electron nuclear double resonance spectra of stellacyanin, a blue copper protein
James E. Roberts, Theodore G. Brown, Brian M. Hoffman, and Jack Peisach
pp 825 - 829; DOI:
10.1021/ja00522a063
PDF
A new class of indolizidine alkaloids from the poison frog, Dendrobates tricolor. X-ray analysis of 8-hydroxy-8-methyl-6-(2'-methylhexylidene)-1-azabicyclo[4.3.0]nonane
J. W. Daly, T. Tokuyama, T. Fujiwara, R. J. Highet, and I. L. Karle
pp 830 - 836; DOI:
10.1021/ja00522a064
PDF
Biosynthesis of amino acids. Investigation of the mechanism of .beta.-tyrosine formation
Ronald J. Parry and Z. Kurylo-Borowska
pp 836 - 837; DOI:
10.1021/ja00522a065
PDF
Flash vacuum thermolysis of 1,2-diazetidines
Michael E. Landis, Lawrence M. Bell, David C. Madoux, John C. Mitchell, Jean M. Schmidt, and John A. Spencer
pp 837 - 838; DOI:
10.1021/ja00522a066
PDF
Interception and characterization of a hydridoalkylrhodium intermediate in a homogeneous catalytic hydrogenation reaction
A. S. C. Chan and Jack Halpern
pp 838 - 840; DOI:
10.1021/ja00522a067
PDF
Spectroscopic observation of matrix-isolated silatoluene
C. L. Kreil, O. L. Chapman, G. T. Burns, and T. J. Barton
pp 841 - 842; DOI:
10.1021/ja00522a068
PDF
Conversion of the cyanocyclohexadienyl ligand in the cation [(.eta.5-RC6H5CN)Mo(.mu.-SMe)4Mo(.eta.6-RC6H5)]+ (R = hydrogen or methyl) into a .pi.-cyanoarene ligand. Electrochemical evidence for a two-electron oxidation-proton elimination mechanism
William E. Silverthorn
pp 842 - 844; DOI:
10.1021/ja00522a069
PDF
Reaction between 2-methyl-2-nitrosopropane and ethylene coordinated to platinum(II): formation of .sigma.-alkyl-nitrone complexes
D. Mansuy, M. Dreme, J. C. Chottard, J. P. Girault, and J. Guilhem
pp 844 - 845; DOI:
10.1021/ja00522a070
PDF
Dioxygen ligand transfer. Synthesis and rearrangement of a heterobimetallic dioxygen adduct
Henri Arzoumanian, Richard Lai, Rafael Lopez Alvarez, Jean Francois Petrignani, Jacques Metzger, and Juergen Fuhrhop
pp 845 - 847; DOI:
10.1021/ja00522a071
PDF
Drastic fluorescence enhancement and photochemical stabilization of cyanine dyes through micellar systems
Robin Humphry-Baker, Michael Graetzel, and Rolf Steiger
pp 847 - 848; DOI:
10.1021/ja00522a072
PDF
Models of siroheme and sirohydrochlorin. .pi. Cation radicals of iron(II) isobacteriochlorin
C. K. Chang and J. Fajer
pp 848 - 851; DOI:
10.1021/ja00522a073
PDF
Carbon-carbon cleavage during Birch-Hueckel-type reductions
Clair J. Collins, Hans Peter Hombach, Brian Maxwell, Madge C. Woody, and Ben M. Benjamin
pp 851 - 853; DOI:
10.1021/ja00522a074
PDF
An ethylene and terminal olefin equivalent in [4 + 2] .pi. cycloadditions. General synthetic application of phenyl vinyl sulfone to the construction of functionalized six-membered rings
Richard V. C. Carr and Leo A. Paquette
pp 853 - 855; DOI:
10.1021/ja00522a075
PDF
Bond cleavage of the solvated methyl chloride anion: a primary electrochemical event
E. Canadell, P. Karafiloglou, and L. Salem
pp 855 - 857; DOI:
10.1021/ja00522a076
PDF
Synthesis of 2,5,6-trideoxystreptamine and its transformation into bioactive pseudodisaccharides by microbial and chemical methods
Claudine Colas, Beatrice Quiclet-Sire, Jeanine Cleophax, Jeanne Marie Delaumeny, Anne Marie Sepulchre, and Stephan D. Gero
pp 857 - 858; DOI:
10.1021/ja00522a077
PDF
Synthesis and structure of a bis[terpyridineplatinum(II)] complex and its evaluation as a metallointercalator
John C. Dewan, Stephen J. Lippard, and William R. Bauer
pp 858 - 860; DOI:
10.1021/ja00522a078
PDF
Copper(I) promoted acylation reactions. A transition metal mediated version of the Friedel-Crafts reaction
Alan P. Kozikowski and Anthony Ames
pp 860 - 862; DOI:
10.1021/ja00522a079
PDF
Stereocontrolled synthesis of sterol side chains
Masato Tanabe and Koji Hayashi
pp 862 - 863; DOI:
10.1021/ja00522a080
PDF
An efficient and versatile generation of o-xylylenes by fluoride anion induced 1,4 elimination of o-(.alpha.-trimethylsilylalkyl)benzyltrimethylammonium halides
Yoshihiko Ito, Masashi Nakatsuka, and Takeo Saegusa
pp 863 - 865; DOI:
10.1021/ja00522a081
PDF
Catalyzed sigmatropic rearrangements. 5. Palladium(II) chloride catalyzed Cope rearrangements of acyclic 1,5-dienes
Larry E. Overman and Frederick M. Knoll
pp 865 - 867; DOI:
10.1021/ja00522a082
PDF
Reduction of .alpha.,.beta.-acetylenic ketones with B-3-pinanyl-9-borabicyclo[3.3.1]nonane. High asymmetric induction in aliphatic systems
M. Mark Midland, Deborah C. McDowell, Robert L. Hatch, and Alfonso Tramontano
pp 867 - 869; DOI:
10.1021/ja00522a083
PDF
Stereoselective generation of a nonaromatic, 3,5-dioxygenated steroidal system through tricyclization of polyene oxide
E. E. Van Tamelen and D. G. Loughhead
pp 869 - 870; DOI:
10.1021/ja00522a084
PDF
Studies directed toward the total synthesis of streptogramin antibiotics. Enantiospecific approach to the nine-membered macrocycle of griseoviridin
A. I. Meyers and Richard A. Amos
pp 870 - 872; DOI:
10.1021/ja00522a085
PDF
Inelastic electron tunneling spectroscopy of zirconium tetraborohydride supported on aluminum oxide
H. E. Evans and W. H. Weinberg
pp 872 - 873; DOI:
10.1021/ja00522a086
PDF
Enhanced CD spectra in cis-bis(nucleotide)platinum(II) complexes. Comparison with the CD enhancement induced in DNA by the antitumor agent, cisPt
Luigi G. Marzilli and Purush Chalilpoyil
pp 873 - 875; DOI:
10.1021/ja00522a087
PDF
Californium-252 plasma desorption mass spectrometry of palytoxin
R. D. Macfarlane, Daisuke Uemura, Katsuhiro Ueda, and Yoshimasa Hirata
pp 875 - 876; DOI:
10.1021/ja00522a088
PDF
Electrically conductive polyimide films containing palladium coordination complexes
A. K. St. Clair, V. C. Carver, L. T. Taylor, and T. A. Furtsch
pp 876 - 878; DOI:
10.1021/ja00522a089
PDF
Synthesis and direct spectroscopic observation of N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene. Comparison of five- and six-membered cyclic 1,1-dialkyldiazenes
Peter G. Schultz and Peter B. Dervan
pp 878 - 880; DOI:
10.1021/ja00522a090
PDF
Stereochemical course of the Cope-Claisen rearrangement of the stereoisomeric 2-vinyl-3-isopropenylcyclohexylvinyl ethers. A system having .DELTA.GClaisen.++. .mchgt. .DELTA.GCope.++.
Frederick E. Ziegler and John J. Piwinski
pp 880 - 882; DOI:
10.1021/ja00522a091
PDF
Nitrogen 1s photoelectron spectra of octaethylporphyrin and tetraphenylporphine complexes of lanthanides
Kazuyuki Tatsumi and Minoru Tsutsui
pp 882 - 884; DOI:
10.1021/ja00522a092
PDF
Mechanism of inactivation of mitochondrial monoamine oxidase by N-cyclopropyl-N-arylalkyl amines
Richard B. Silverman and Stephen J. Hoffman
pp 884 - 886; DOI:
10.1021/ja00522a093
PDF
Aromatization of 1,4-cyclohexadiene with tetracyanoethylene: an ene reaction
Barry M. Jacobson
pp 886 - 887; DOI:
10.1021/ja00522a094
PDF
Total synthesis and revised structural assignment of (+)-furanomycin
Madeleine M. Joullie, Pen C. Wang, and J. Edward Semple
pp 887 - 889; DOI:
10.1021/ja00522a095
PDF
A total synthesis of dl-pentalenolactone
W. H. Parsons, R. H. Schlessinger, and Martha L. Quesada
pp 889 - 890; DOI:
10.1021/ja00522a096
PDF
Additions and Corrections - Three-Electron Oxidations. VIII. Direct Evidence for the Synchronous Character of Three-Electron Oxidations
Fariza Hasan, and Jan Rocek
pp 890 - 890; DOI:
10.1021/ja00522a600
PDF
Additions and Corrections - Three-Electron Oxidations. IX. Chromic Acid Oxidation of Glycolic Acid.
Fariza Hasan, and Jan Rocek
pp 890 - 890; DOI:
10.1021/ja00522a601
PDF
Additions and Corrections - Three-Electron Oxidations. X. Cooxidation of Isopropyl Alcohol and Glycolic Acid
Fariza Hasan, and Jan Rocek
pp 890 - 890; DOI:
10.1021/ja00522a602
PDF
Additions and Corrections - Hydrogen Atom Exchange between Nitroxides and Hydroxylamines.
Martin A. Schwartz, J. Wallace Parce, and Harden M. McConnell
pp 890 - 891; DOI:
10.1021/ja00522a603
PDF
Additions and Corrections - A Stereocontrolled Synthesis of the (±) Djerassi-Prelog Lactonic Acid
Gilbert Stork, and Vijay Nair
pp 891 - 891; DOI:
10.1021/ja00522a604
PDF
Additions and Corrections - Reaction of a Metal Alkyl with Ethylene as a Model for Ziegler-Natta Polymerization. Evidence for the Olefin Insertion Mechanism.
Eric R. Evitt, and Robert G. Bergman
pp 891 - 891; DOI:
10.1021/ja00522a605
PDF
Additions and Corrections - Coal Chemistry. 8. Reaction of Tetralin with Coal and with Some Carbon-14-Containing Model Compounds.
Clair J. Collins, F. Raaen, Ben M. Benjamin, P. H. Maupin, and W. Howard Roark
pp 891 - 891; DOI:
10.1021/ja00522a606
PDF
Additions and Corrections - Optically Active Amines. 28. Spectral Observations on Chiral N-Substituted p-Nitroanilines.
Howard E. Smith, William I. Cozart, Tomas De Paulis, and Fu-Ming Chen
pp 891 - 891; DOI:
10.1021/ja00522a607
PDF
Additions and Corrections - Metallacyclopentane to Metallacyaclobutabe Ring Contraction
Stephan J. McClain, José Sancho, and Richard R. Schrock
pp 891 - 891; DOI:
10.1021/ja00522a608
PDF
Book REviews

pp 892 - 896; DOI:
10.1021/ja00522a609
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Issue 3


An NMR study of the structure of the antibiotic ristocetin A. The negative nuclear Overhauser effect in structure elucidation
John R. Kalman and Dudley H. Williams
pp 897 - 905; DOI:
10.1021/ja00523a001
PDF
An NMR study of the interaction between the antibiotic ristocetin A and a cell wall peptide analog. Negative nuclear Overhauser effects in the investigation of drug binding sites
John R. Kalman and Dudley H. Williams
pp 906 - 912; DOI:
10.1021/ja00523a002
PDF
Isotopic oxygen-18 shifts in phosphorus-31 NMR of adenine nucleotides synthesized with oxygen-18 in various positions
Mildred Cohn and Angela Hu
pp 913 - 916; DOI:
10.1021/ja00523a003
PDF
Nucleoside complexing. A Raman and carbon-13 NMR spectroscopic study of the binding of hard and soft metal species
Luigi G. Marzilli, Baltazar De Castro, John P. Caradonna, Robert Charles Stewart, and C. P. Van Vuuren
pp 916 - 924; DOI:
10.1021/ja00523a004
PDF
NMR in molten [N(Bu)4]2MBr4. 1. Contact and pseudocontact shifts
Richard A. Friedman, Edward G. Malawer, Yun Wei Wong, and Benson R. Sundheim
pp 925 - 931; DOI:
10.1021/ja00523a005
PDF
Effects of molecular structure on basicity. Gas-phase proton affinities of cyclic phosphites
Ronald V. Hodges, F. A. Houle, J. L. Beauchamp, R. A. Montag, and J. G. Verkade
pp 932 - 935; DOI:
10.1021/ja00523a006
PDF
Nucleophilic reactions of anions with trimethyl phosphate in the gas phase by ion cyclotron resonance spectroscopy
Ronald V. Hodges, S. A. Sullivan, and J. L. Beauchamp
pp 935 - 938; DOI:
10.1021/ja00523a007
PDF
Self-consistent molecular orbital methods. 21. Small split-valence basis sets for first-row elements
J. Stephen Binkley, John A. Pople, and Warren J. Hehre
pp 939 - 947; DOI:
10.1021/ja00523a008
PDF
A theoretical study of the structure and charge distribution of some alkynylcarbenium ions
M. Dorado, O. Mo, and M. Yanez
pp 947 - 950; DOI:
10.1021/ja00523a009
PDF
Franck-Condon analysis of transition-metal complexes
H. Yersin, H. Otto, Jeffrey I. Zink, and G. Gliemann
pp 951 - 955; DOI:
10.1021/ja00523a010
PDF
Electronic structures and photoelectron spectra of the metal atom cluster species tri-.mu.-chloro-hexachlorotrirhenium, tri-.mu.-bromo-hexabromotrirhenium, and tri-.mu.-chloro-nonachlorotrirhenate(3-)
Bruce E. Bursten, F. Albert Cotton, Jennifer C. Green, Elaine A. Seddon, and George G. Stanley
pp 955 - 968; DOI:
10.1021/ja00523a011
PDF
Luminescent photoelectrochemical cells. 2. Doped cadmium sulfide photoelectrodes as probes of excited-state processes which influence optical to electrical energy conversion
Bradley R. Karas and Arthur B. Ellis
pp 968 - 980; DOI:
10.1021/ja00523a012
PDF
A delocalized two-electron three-center carbon-hydrogen-metal interaction. Single crystal neutron (30 and 110 K) and x-ray (298 K) diffraction study of [Fe(P(OCH3)3)3(.eta.3-C8H13)]+[BF4]-
Richard K. Brown, Jack M. Williams, Arthur J. Schultz, Galen D. Stucky, Steven D. Ittel, and Richard L. Harlow
pp 981 - 987; DOI:
10.1021/ja00523a013
PDF
Asymmetric hydrogenation catalyzed by cationic ferrocenylphosphine rhodium(I) complexes and the crystal structure of a catalyst precursor
William R. Cullen, Frederick W. B. Einstein, Chung-Hsi Huang, Anthony C. Willis, and E. Shan Yeh
pp 988 - 993; DOI:
10.1021/ja00523a014
PDF
1,1'-Diphosphaferrocenes. Synthesis, basic chemistry, and structure
Guillaume De Lauzon, Bernard Deschamps, Jean Fischer, Francois Mathey, and Andre Mitschler
pp 994 - 1000; DOI:
10.1021/ja00523a015
PDF
Reactions of coordinated dinitrogen. 4. Reactions of bromoalkanes with bis(dinitrogen)bis[ethylenebis(diphenylphosphine)]molybdenum. Formation of ammonia and amines
Gerald E. Bossard, David C. Busby, Molly Chang, T. Adrian George, and S. D. Allen Iske
pp 1001 - 1008; DOI:
10.1021/ja00523a016
PDF
The chemistry of bis(fulvalene)divanadium
James C. Smart and Barry L. Pinsky
pp 1009 - 1015; DOI:
10.1021/ja00523a017
PDF
One-electron reduction of ferrideuterioporphyrin IX and reaction of the oxidized and reduced forms with chlorinated methyl radicals
D. Brault, C. Bizet, P. Morliere, M. Rougee, E. J. Land, R. Santus, and A. J. Swallow
pp 1015 - 1020; DOI:
10.1021/ja00523a018
PDF
Mechanistic studies of the homogeneous catalysis of the water gas shift reaction by rhodium carbonyl iodide
Edgar C. Baker, Dan E. Hendriksen, and Richard Eisenberg
pp 1020 - 1027; DOI:
10.1021/ja00523a019
PDF
Homogeneous catalysis of the water gas shift reaction using iron pentacarbonyl
Allen D. King, R. B. King, and D. B. Yang
pp 1028 - 1032; DOI:
10.1021/ja00523a020
PDF
Preparation and catalytic oxidizing potential of polymer supported chelating amine and Schiff base complexes
Russell S. Drago, John Gaul, Alan Zombeck, and Darel K. Straub
pp 1033 - 1038; DOI:
10.1021/ja00523a021
PDF
N-Acetylbenzotriazole hydrolysis and aminolysis. Broensted relationships and rate-determining steps in the uncatalyzed and catalyzed aminolysis
Michele Reboud-Ravaux
pp 1039 - 1046; DOI:
10.1021/ja00523a022
PDF
Palladium(II) tert-butyl peroxide carboxylates. New reagents for the selective oxidation of terminal olefins to methyl ketones. The role of peroxymetalation in selective oxidative processes
Hubert Mimoun, Robert Charpentier, Andre Mitschler, Jean Fischer, and Raymond Weiss
pp 1047 - 1054; DOI:
10.1021/ja00523a023
PDF
Crystal and molecular structure of methyltri(p-nitrophenoxy)phosphonium chloride. Evidence for hydrogen bonds with a methyl group as hydrogen donor
D. Schomburg
pp 1055 - 1058; DOI:
10.1021/ja00523a024
PDF
The trindene trianion
Thomas J. Katz and Wojciech Slusarek
pp 1058 - 1063; DOI:
10.1021/ja00523a025
PDF
Synthesis and chemistry of 5,6-dihydropyridinium salt adducts. Synthons for general electrophilic and nucleophilic substitution of the piperidine ring system
David S. Grierson, Martin Harris, and Henri Philippe Husson
pp 1064 - 1082; DOI:
10.1021/ja00523a026
PDF
Geometric dependence to long-range interaction of fused cyclopropane rings in tris-.sigma.-homotropylium cations
Katsuo Ohkata and Leo A. Paquette
pp 1082 - 1092; DOI:
10.1021/ja00523a027
PDF
Sulfoxylate ion (HSO2-), the hydride donor in dithionite-dependent reduction of NAD+ analogs
Gunter Blankenhorn and Edwin G. Moore
pp 1092 - 1098; DOI:
10.1021/ja00523a028
PDF
Biosynthesis of the Cephalotaxus alkaloids. Investigations of the early and late stages of cephalotaxine biosynthesis
Ronald J. Parry, Michael N. T. Chang, John M. Schwab, and B. M. Foxman
pp 1099 - 1111; DOI:
10.1021/ja00523a029
PDF
Observation of 3 .fwdarw. 1 intramolecular hydrogen bonds (.gamma. turns) in the cyclic tetrapeptides, [Ala4]-desdimethylchlamydocin and cyclo-(D-Phe-Pro-D-Phe-Pro), by NMR spectrometry. Effect of solvent on solution conformation
Daniel H. Rich and Ronald D. Jasensky
pp 1112 - 1119; DOI:
10.1021/ja00523a030
PDF
Denaturation studies by carbon-13 nuclear magnetic resonance on modified basic pancreatic trypsin inhibitor using the novel S-[13C]methyl methionyl probe
Benjamin M. Harina, Douglas F. Dyckes, M. Robert Willcott, and Warren C. Jones
pp 1120 - 1124; DOI:
10.1021/ja00523a031
PDF
Proton, sodium-23, and phosphorus-31 NMR studies of the self-assembly of the 5'-guanosine monophosphate dianion in neutral aqueous solution in the presence of sodium cations
Marie Borzo, Christian Detellier, Pierre Laszlo, and Agnes Paris
pp 1124 - 1134; DOI:
10.1021/ja00523a032
PDF
Role of alkali metal and ammonium cations in the self-assembly of the 5'-guanosine monophosphate dianion
Christian Detellier and Pierre Laszlo
pp 1135 - 1141; DOI:
10.1021/ja00523a033
PDF
Comparison of the electron-transfer reactivities of tris(oxalato)cobaltate(III) (Co(ox)33-) and tris(1,10-phenanthroline)cobalt(III) (Co(phen)33+) with metalloproteins
Robert A. Holwerda, David B. Knaff, Harry B. Gray, John D. Clemmer, Robert Crowley, J. Michael Smith, and A. Grant Mauk
pp 1142 - 1146; DOI:
10.1021/ja00523a034
PDF
Liposomal membranes. 2. Synthesis of a novel pyrene-labeled lecithin and structural studies on liposomal bilayers
Junzo Sunamoto, Hiroki Kondo, Tadashi Nomura, and Hiroshi Okamoto
pp 1146 - 1152; DOI:
10.1021/ja00523a035
PDF
The first successful carbonic anhydrase model prepared through a new route to regiospecifically bifunctionalized cyclodextrin
Iwao Tabushi, Yasuhisa Kuroda, and Akira Mochizuki
pp 1152 - 1153; DOI:
10.1021/ja00523a036
PDF
Stereochemistry of the intramolecular imino Diels-Alder reaction
Bassam Nader, Richard W. Franck, and Steven M. Weinreb
pp 1153 - 1155; DOI:
10.1021/ja00523a037
PDF
Total synthesis of lasalocid A (X537A)
Robert E. Ireland, Suvit Thaisrivongs, and Craig S. Wilcox
pp 1155 - 1157; DOI:
10.1021/ja00523a038
PDF
Enantiomer recognition and guest-host configurational correlation in crystals of tri-o-thymotide clathrate inclusion compounds
Rina Arad-Yellin, Bernard S. Green, and Marcel Knossow
pp 1157 - 1158; DOI:
10.1021/ja00523a039
PDF
Crystal lattice control of unimolecular photorearrangements. Differences in cyclohexenone photochemistry in solution and the solid state. Solution results
Wolfgang K. Appel, Trevor J. Greenhough, John R. Scheffer, James Trotter, and Leueen Walsh
pp 1158 - 1160; DOI:
10.1021/ja00523a040
PDF
Crystal lattice control of unimolecular photorearrangements. Differences in cyclohexenone photochemistry in solution and the solid state. Solid-state results
Wolfgang K. Appel, Trevor J. Greenhough, John R. Scheffer, James Trotter, and Leueen Walsh
pp 1160 - 1161; DOI:
10.1021/ja00523a041
PDF
Hydrolysis of phenyl acetates with capped .beta.-cyclodextrins: reversion from meta to para selectivity
Kahee Fujita, Akihiro Shinoda, and Taiji Imoto
pp 1161 - 1163; DOI:
10.1021/ja00523a042
PDF
Activation of carbon-hydrogen bonds by [Rh(diphos)2]0
John A. Sofranko, Richard Eisenberg, and Jack A. Kampmeier
pp 1163 - 1165; DOI:
10.1021/ja00523a043
PDF
Total synthesis of the unique indole alkaloid chuangxinmycin. Application of nitro group displacement reactions in organic synthesis
Alan P. Kozikowski and Michael N. Greco
pp 1165 - 1166; DOI:
10.1021/ja00523a044
PDF
Chiral recognition by nitrogen-15 NMR spectroscopy. 8-Benzyl-5,6,7,8-tetrahydroquinoline
Rainer Dyllick-Brenzinger and John D. Roberts
pp 1166 - 1167; DOI:
10.1021/ja00523a045
PDF
Electron nuclear double resonance of ferric cytochrome P450CAM
Russell LoBrutto, Charles P. Scholes, Gerald C. Wagner, I. C. Gunsalus, and Peter G. Debrunner
pp 1167 - 1170; DOI:
10.1021/ja00523a046
PDF
Applications of light-induced electron-transfer reactions: generation and reaction of silver(0) in solution via visible light photolysis of tris(2,2'-bipyridine)ruthenium(2+)
Thomas K. Foreman, C. Giannotti, and David G. Whitten
pp 1170 - 1171; DOI:
10.1021/ja00523a047
PDF
Photochemical or photomimetic fossil triterpenoids in sediments and petroleum
B. Corbet, P. Albrecht, and G. Ourisson
pp 1171 - 1173; DOI:
10.1021/ja00523a048
PDF
Reactivities of stable rotamers. 3. Differential reactivity of the methyls in a tert-butyl group
Tsutou Morinaga, Shigetaka Seki, Hiromi Kikuchi, Gaku Yamamoto, and Michinori Oki
pp 1173 - 1174; DOI:
10.1021/ja00523a049
PDF
Photoelectron-determined core binding energies and predicted gas-phase basicities for the 2-hydroxypyridine .dblarw. 2-pyridone system
R. S. Brown, A. Tse, and J. C. Vederas
pp 1174 - 1176; DOI:
10.1021/ja00523a050
PDF
Intramolecular 1,1-cycloaddition reactions of diazomethanes to carbon:carbon double bonds
Yoshinori Nishizawa, Tsutomu Miyashi, and Toshio Mukai
pp 1176 - 1177; DOI:
10.1021/ja00523a051
PDF
Comment on the electronic structure of HAlOH and H2O.Al
Henry A. Kurtz and Kenneth D. Jordan
pp 1177 - 1178; DOI:
10.1021/ja00523a052
PDF
pH-Dependent constraint angle effects on the order parameters of bilayer systems
B. J. Forrest, L. Hecker, and L. W. Reeves
pp 1178 - 1180; DOI:
10.1021/ja00523a053
PDF
A proton nuclear magnetic resonance study of "H(phen)2+": self-stacking of protonated phenanthroline
Paul R. Mitchell
pp 1180 - 1181; DOI:
10.1021/ja00523a054
PDF
Metal-ligand synergism in the chemistry of macrocyclic complexes. Base-induced reduction of a cobalt(III) complex
Jay A. Switzer and John F. Endicott
pp 1181 - 1183; DOI:
10.1021/ja00523a055
PDF
Prostaglandin G2
Ned A. Porter, Jim D. Byers, A. E. Ali, and Thomas E. Eling
pp 1183 - 1184; DOI:
10.1021/ja00523a056
PDF
L3-Edge anomalous scattering of x-rays by praseodymium and samarium
Lieselotte K. Templeton, David H. Templeton, and R. Paul Phizackerley
pp 1185 - 1186; DOI:
10.1021/ja00523a057
PDF
Electronic control of stereoselectivity. 3. Stereoselection operative in [4 + 2].pi. cycloadditions to cyclopentadiene rings fused at C2,C3 to bicyclic frameworks
Leo A. Paquette, Richard V. C. Carr, Michael C. Boehm, and Rolf Gleiter
pp 1186 - 1188; DOI:
10.1021/ja00523a058
PDF
Optical activity associated with a highly fluxional molecule. Absolute configuration and chiroptical properties of 2(4)-methylsemibullvalene
Leo A. Paquette, Robert F. Doehner, Jerry A. Jenkins, and John F. Blount
pp 1188 - 1190; DOI:
10.1021/ja00523a059
PDF
Magnetic isotope effect on the thermolysis of 9,10-diphenylanthracene endoperoxide as a means of separation of oxygen-17 from oxygen-16 and oxygen-18
Nicholas J. Turro and Ming-Fea Chow
pp 1190 - 1192; DOI:
10.1021/ja00523a060
PDF
The mechanism of intersystem crossing and ring closure of the triplet 1,8-naphthoquinodimethane biradical
Matthew S. Platz
pp 1192 - 1194; DOI:
10.1021/ja00523a061
PDF
Why some binuclear complexes bridge, while others, even though they might have a quadruple bond available to them, do not
Sason Shaik and Roald Hoffmann
pp 1194 - 1196; DOI:
10.1021/ja00523a062
PDF
A new, general route to functionally substituted .eta.5-cyclopentadienyl metal compounds
William P. Hart, David W. Macomber, and Marvin D. Rausch
pp 1196 - 1198; DOI:
10.1021/ja00523a063
PDF
Synthesis of the alleged genipic acid by photoannelation
S. W. Baldwin and M. T. Crimmins
pp 1198 - 1200; DOI:
10.1021/ja00523a064
PDF
Total synthesis of triptolide and triptonide
Richard S. Buckanin, Samuel J. Chen, Donna M. Frieze, Frank T. Sher, and Glenn A. Berchtold
pp 1200 - 1201; DOI:
10.1021/ja00523a065
PDF
.alpha.-Alkoxyorganolithium reagents. A new class of configurationally stable carbanions for organic synthesis
W. Clark Still and C. Sreekumar
pp 1201 - 1202; DOI:
10.1021/ja00523a066
PDF
Total synthesis of stemolide
E. E. Van Tamelen and E. G. Taylor
pp 1202 - 1203; DOI:
10.1021/ja00523a067
PDF
Spectroscopic characterization of an electrophilic transition-metal-methylene complex, .eta.5-C5H5[(C6H5)2PCH2CH2P(C6H5)2]Fe:CH2+
M. Brookhart, James R. Tucker, Thomas C. Flood, and John Jensen
pp 1203 - 1205; DOI:
10.1021/ja00523a068
PDF
Pressure effects on the thermal cis .fwdarw. trans isomerization of 4-dimethylamino-4'-nitroazobenzene. Evidence for a change of mechanism with solvent
Tsutomu Asano
pp 1205 - 1206; DOI:
10.1021/ja00523a069
PDF
Carbonyl, thiocarbonyl, selenocarbonyl, and tellurocarbonyl complexes derived from a dichlorocarbene complex of osmium
George R. Clark, Karen Marsden, Warren R. Roper, and L. James Wright
pp 1206 - 1207; DOI:
10.1021/ja00523a070
PDF
Correlation of circularly polarized luminescence induced in Tb(dpm)3 by chiral solvents with the absolute configuration of those solvents
Harry G. Brittain
pp 1207 - 1208; DOI:
10.1021/ja00523a071
PDF
Orotidine 5'-monophosphate decarboxylase inhibitors formed by spontaneous reaction of barbituric acid and ribose 5-phosphate, a surprising reaction
H. Komura, K. Nakanishi, B. W. Potvin, H. J. Stern, and R. S. Krooth
pp 1208 - 1210; DOI:
10.1021/ja00523a072
PDF
Thermal isomerization. 9. The role of cyclopropene in the allene to propyne isomerization. A study of the thermal rearrangements of C3H3D isomers
H. Hopf, H. Priebe, and R. Walsh
pp 1210 - 1212; DOI:
10.1021/ja00523a073
PDF
Total internal reflection Raman spectroscopy as a new tool for surface analysis
Reikichi Iwamoto, Masaru Miya, Koji Ohta, and Seiichi Mima
pp 1212 - 1213; DOI:
10.1021/ja00523a074
PDF
Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O
Donald J. Darensbourg, Nyal Walker, and Marcetta Y. Darensbourg
pp 1213 - 1214; DOI:
10.1021/ja00523a075
PDF
The .alpha.-cyano group as a substituent in solvolysis reactions. An evaluation of inductive destabilization vs. mesomeric stabilization of cations by the cyano moiety
Paul G. Gassman and John J. Talley
pp 1214 - 1216; DOI:
10.1021/ja00523a076
PDF
Solvolytic reactivity of .alpha.-trifluoromethylcarbinyl sulfonates. Correlation of rate retardation by electron-withdrawing substituents and solvent participation in tertiary substrates
K. M. Koshy and Thomas T. Tidwell
pp 1216 - 1218; DOI:
10.1021/ja00523a077
PDF
Reductive alkylation of enediones. 1
Gilbert Stork and E. W. Logusch
pp 1218 - 1219; DOI:
10.1021/ja00523a078
PDF
Reductive alkylation of enediones. 2. Synthesis of corticosteroids
Gilbert Stork and E. W. Logusch
pp 1219 - 1220; DOI:
10.1021/ja00523a079
PDF
Flash photolysis of chromium hexacarbonyl in perfluorocarbon solvents. Observation of a highly reactive chromium pentacarbonyl
Roland Bonneau and John M. Kelly
pp 1220 - 1221; DOI:
10.1021/ja00523a080
PDF
A novel oxygen-18 kinetic isotope effect in an .alpha.-chymotrypsin catalyzed transesterification
Chih-Lueh A. Wang, Charlotte M. Trout, K. C. Calvo, Michael H. Klapper, and Lan K. Wong
pp 1221 - 1223; DOI:
10.1021/ja00523a081
PDF
Tris(dialkylamino)sulfonium enolates
R. Noyori, I. Nishida, J. Sakata, and M. Nishizawa
pp 1223 - 1225; DOI:
10.1021/ja00523a082
PDF
Chemistry and crystal structures of mixed-valence copper dithioether complexes with all-tetrahedral copper
W. K. Musker, M. M. Olmstead, R. M. Kessler, M. B. Murphey, C. H. Neagley, P. B. Roush, N. L. Hill, T. L. Wolford, H. Hope, and et al.
pp 1225 - 1226; DOI:
10.1021/ja00523a083
PDF
Book Reviews

pp 1227 - 1228; DOI:
10.1021/ja00523a600
PDF

Issue 4


Effect of substituents on the electron densities in methane. .sigma. and .pi. Interactions in saturated systems
Kenneth B. Wiberg
pp 1229 - 1237; DOI:
10.1021/ja00524a001
PDF
Nonexponential proton spin-lattice relaxation and internal rotation of methyl groups
E. Haslinger and W. Robien
pp 1237 - 1241; DOI:
10.1021/ja00524a002
PDF
Quantitative measurement of intermediate species in sustained Belousov-Zhabotinskii oscillations
C. Vidal, J. C. Roux, and A. Rossi
pp 1241 - 1245; DOI:
10.1021/ja00524a003
PDF
Correlations of gas-phase acidities and basicities with the electrostatic field model
Carolyn S. Yoder and Claude H. Yoder
pp 1245 - 1247; DOI:
10.1021/ja00524a004
PDF
Study of an intramolecular, bifurcated hydrogen bond in 1,3-dioxan-5-ol by microwave spectroscopy
Jose L. Alonso and E. Bright Wilson
pp 1248 - 1251; DOI:
10.1021/ja00524a005
PDF
Synthesis of aliphatic dimeric N-isopropylhydroxamic acids and the crystal and molecular structure of N,N'-dihydroxy-N,N'-diisopropylhexanediamide: a hydroxamic acid in the trans conformation
William L. Smith and Kenneth N. Raymond
pp 1252 - 1255; DOI:
10.1021/ja00524a006
PDF
A molecular orbital study of the benzene oxide-oxepin valence isomerization
David M. Hayes, Sidney D. Nelson, William A. Garland, and Peter A. Kollman
pp 1255 - 1262; DOI:
10.1021/ja00524a007
PDF
On MO calculations of dimeric interactions and their applicability to crystal structures. (TCNQ)2 and (TTF)2
John P. Lowe
pp 1262 - 1269; DOI:
10.1021/ja00524a008
PDF
One-center integrals of the exact effective valence shell Hamiltonian. Empirical analysis for atoms
Danny L. Yeager, Maurice G. Sheppard, and Karl F. Freed
pp 1270 - 1277; DOI:
10.1021/ja00524a009
PDF
Studies of the electronic structure of copper fluorides and copper chlorides
Paulo Correa de Mello, Michael Hehenberger, Sven Larsson, and Michael Zerner
pp 1278 - 1288; DOI:
10.1021/ja00524a010
PDF
Medium and distance effects in optical and thermal electron transfer
Michael J. Powers and Thomas J. Meyer
pp 1289 - 1297; DOI:
10.1021/ja00524a011
PDF
Experimental determination of the deformation electron density in hydrogen peroxide by combination of x-ray and neutron diffraction measurements
J. M. Savariault and M. S. Lehmann
pp 1298 - 1303; DOI:
10.1021/ja00524a012
PDF
Spectroscopic and structural investigation on the pentachloro- and (mixed-pentahalo)cuprates(II) of the N-(2-ammoniumethyl)piperazinium cation. The first case of monomeric pentahalocuprate(II) having square-pyramidal structure. Crystal and molecular structure of the (N-(2-ammoniumethyl)piperazinium) pentachlorocuprate(II) dihydrate
L. Antolini, G. Marcotrigiano, L. Menabue, and G. C. Pellacani
pp 1303 - 1309; DOI:
10.1021/ja00524a013
PDF
Lifetimes, spectra, and quenching of the excited states of polypyridine complexes of iron(II), ruthenium(II), and osmium(II)
Carol Creutz, Mei Chou, Thomas L. Netzel, Mitchio Okumura, and Norman Sutin
pp 1309 - 1319; DOI:
10.1021/ja00524a014
PDF
Influence of crystal packing on the .eta.1 .fwdarw. .eta.3 rearrangement of an allyl ligand. Solution and solid-state structures of the tetraphenylborate and hexafluorophosphate salts of a platinum allyl cation
Carolyn Pratt Brock and Thomas G. Attig
pp 1319 - 1326; DOI:
10.1021/ja00524a015
PDF
Properties and reactions of trimethyl phosphite, trimethyl phosphate, triethyl phosphate, and trimethyl phosphorothionate by ion cyclotron resonance spectroscopy
Ronald V. Hodges, T. J. McDonnell, and J. L. Beauchamp
pp 1327 - 1332; DOI:
10.1021/ja00524a016
PDF
Nickel-catalyzed conjugate addition of alkenylzirconium species to .alpha.,.beta.-unsaturated ketones
Jeffrey Schwartz, Melanie J. Loots, and Hiroshi Kosugi
pp 1333 - 1340; DOI:
10.1021/ja00524a017
PDF
Catalysis of transimination by rate-limiting proton transfer to buffer bases
Helene Fischer, Francis X. DeCandis, Sharon D. Ogden, and William P. Jencks
pp 1340 - 1347; DOI:
10.1021/ja00524a018
PDF
Stereoelectronic control in acid and base catalysis of amide hydrolysis. A theoretical study
Jean Marie Lehn and Georges Wipff
pp 1347 - 1354; DOI:
10.1021/ja00524a019
PDF
Unusual kinetic behavior in the self-reactions of acyl methyl nitroxides
D. Griller and M. J. Perkins
pp 1354 - 1357; DOI:
10.1021/ja00524a020
PDF
Hydrogen abstraction by biradicals. Reactions with tri-n-butylstannane and octanethiol
M. V. Encinas, P. J. Wagner, and J. C. Scaiano
pp 1357 - 1360; DOI:
10.1021/ja00524a021
PDF
Nucleophilic addition to olefins. 2. Reaction of benzylidene Meldrum's acid with water, hydroxide ion, and aryloxide ions. Complete kinetic analysis of the hydrolytic cleavage of the carbon:carbon double bond
Claude F. Bernasconi and Gianni D. Leonarduzzi
pp 1361 - 1366; DOI:
10.1021/ja00524a022
PDF
Carbon-halogen bonding studies. Halogen redistribution reactions between alkyl or acetyl halides and tri-n-butyltin halides
Edwin C. Friedrich and Charles B. Abma
pp 1367 - 1371; DOI:
10.1021/ja00524a023
PDF
Skeletal rearrangement of nitrogen, oxygen-heterocycles. The isoxazolinone to aziridine transformation induced by lithium aluminum hydride
G. Chidichimo, G. Cum, F. Lelj, G. Sindona, and N. Uccella
pp 1372 - 1377; DOI:
10.1021/ja00524a024
PDF
Electrophilic heteroaromatic substitutions. 2. Mechanism of the side-chain halogenation of polysubstituted .alpha.-methylpyrroles with molecular chlorine
Giancarlo Angelini, Gabriello Illuminati, Anna Monaci, Giancarlo Sleiter, and Maurizio Speranza
pp 1377 - 1382; DOI:
10.1021/ja00524a025
PDF
Photooxidation of anti-1,2,3,4,5,6,7,8-octahydro-1,4,5,8-dimethanonaphthalene (sesquinorbornene). Specific steric effects in the hydrocarbon and its precursors
Paul D. Bartlett, Andrew J. Blakeney, Michio Kimura, and William H. Watson
pp 1383 - 1390; DOI:
10.1021/ja00524a026
PDF
Total synthesis of (.+-.)-dendrobine
William R. Roush
pp 1390 - 1404; DOI:
10.1021/ja00524a027
PDF
Carbocyclic thromboxane A2
K. C. Nicolaou, R. L. Magolda, and D. A. Claremon
pp 1404 - 1409; DOI:
10.1021/ja00524a028
PDF
2,4-Methanoproline (2-carboxy-2,4-methanopyrrolidine) and 2,4-methanoglutamic acid (1-amino-1,3-dicarboxycyclobutane) in seeds of Ateleia herbert smithii Pittier (Leguminosae)
E. Arthur Bell, M. Yasin Qureshi, Robert J. Pryce, Daniel H. Janzen, Paula Lemke, and Jon Clardy
pp 1409 - 1412; DOI:
10.1021/ja00524a029
PDF
Solution structure, dynamics, and proton relaxation mechanisms of natural products and biopolymers. N-acetyl-D-alloisoleucine
Neri Niccolai, Maria P. Miles, Sean P. Hehir, and William A. Gibbons
pp 1412 - 1415; DOI:
10.1021/ja00524a030
PDF
Mechanical spectroscopy: a new technique for measuring ring rotation in organometallic complexes
Adi Eisenberg, Alan Shaver, and Tetsuo Tsutsui
pp 1416 - 1417; DOI:
10.1021/ja00524a031
PDF
Stereochemistry of the singlet oxygen olefin-ene reaction
M. Orfanopoulos and L. M. Stephenson
pp 1417 - 1418; DOI:
10.1021/ja00524a032
PDF
2,4-Methano-2,4-dehydroadamantane. A [3.1.1]propellane
Katica Mlinaric-Majerski and Zdenko Majerski
pp 1418 - 1419; DOI:
10.1021/ja00524a033
PDF
Primary quantum yields of ketyl radicals in photoreduction by amines. Abstraction of hydrogen from nitrogen
Shai Inbar, Henry Linschitz, and Saul G. Cohen
pp 1419 - 1421; DOI:
10.1021/ja00524a034
PDF
Electron spin resonance of iminocyclohexadienylidenes: photoinduced triplet geometrical isomerization
H. Murai, M. Torres, and O. P. Strausz
pp 1421 - 1422; DOI:
10.1021/ja00524a035
PDF
Silyl ketone chemistry. Preparation of siloxyallenyl- and -allyllithium reagents
Hans J. Reich, Richard E. Olson, and Mark C. Clark
pp 1423 - 1424; DOI:
10.1021/ja00524a036
PDF
Molecular mechanics calculations of reactivity differences between alicyclic compounds
Hans Joerg Schneider and Fred Thomas
pp 1424 - 1425; DOI:
10.1021/ja00524a037
PDF
Stereochemistry of the addition of dimethylsilylene to cis- and trans-2-butene
Victor J. Tortorelli and Maitland Jones
pp 1425 - 1426; DOI:
10.1021/ja00524a038
PDF
Stabilities of stereoisomeric imine anions
K. N. Houk, Robert W. Strozier, Nelson G. Rondan, Robert R. Fraser, and N. Chuaqui-Offermanns
pp 1426 - 1429; DOI:
10.1021/ja00524a039
PDF
Estimation of strength of the "three-electron .sigma. bond" of a hexaalkylhydrazine monocation radical
Stephen F. Nelsen, Roger W. Alder, Richard B. Sessions, Klaus Dieter Asmus, Karl Otmar Hiller, and Manfred Goebl
pp 1429 - 1430; DOI:
10.1021/ja00524a040
PDF
Synthesis of a class of complexes containing tungsten-tungsten quadruple bonds
Paul R. Sharp and Richard R. Schrock
pp 1430 - 1431; DOI:
10.1021/ja00524a041
PDF
Structural characterization of four quadruply bonded ditungsten compounds and a new trinuclear tungsten cluster
F. A. Cotton, T. R. Felthouse, and D. G. Lay
pp 1431 - 1433; DOI:
10.1021/ja00524a042
PDF
Controlled chemical synthesis of the enzymically produced eicosanoids 11-, 12-, and 15-HETE from arachidonic acid and conversion into the corresponding hydroperoxides (HPETE)
E. J. Corey, Anthony Marfat, J. R. Falck, and John O. Albright
pp 1433 - 1435; DOI:
10.1021/ja00524a043
PDF
Chemical and enzymic syntheses of 5-HPETE, a key biological precursor of slow-reacting substance of anaphylaxis (SRS), and 5-HETE
E. J. Corey, John O. Albright, Alan E. Barton, and Shunichi Hashimoto
pp 1435 - 1436; DOI:
10.1021/ja00524a044
PDF
Stereospecific total synthesis of a "slow reacting substance" of anaphylaxis, leukotriene C-1
E. J. Corey, David A. Clark, Giichi Goto, Anthony Marfat, Charles Mioskowski, Bengt Samuelsson, and Sven Hammarstroem
pp 1436 - 1439; DOI:
10.1021/ja00524a045
PDF
Total synthesis of (-)-N-methylmaysenine
E. J. Corey, Leland O. Weigel, A. Richard Chamberlin, and Bruce Lipshutz
pp 1439 - 1441; DOI:
10.1021/ja00524a046
PDF
Aromatic hydroxylation by oxygen (3P) atoms
Setsuo Takamuku, Hiroyuki Matsumoto, Akira Hori, and Hiroshi Sakurai
pp 1441 - 1443; DOI:
10.1021/ja00524a047
PDF
An electrochemical method for measuring electronic delocalization in mixed-valent species
Robert R. Gagne and Clifford L. Spiro
pp 1443 - 1444; DOI:
10.1021/ja00524a048
PDF
Intramolecular electron transfer and valence isomerization in mononuclear nickel-macrocyclic ligand complexes: formation of paramagnetic nickel(I)-carbonyl complexes
Robert R. Gagne and D. Michael Ingle
pp 1444 - 1446; DOI:
10.1021/ja00524a049
PDF
Heats of formation of SO2Cl- and (SO2)2Cl-
Robert G. Keesee and A. W. Castleman
pp 1446 - 1446; DOI:
10.1021/ja00524a050
PDF
Formation of porphyrin ferryl (FeO2+) complexes through the addition of nitrogen bases to peroxo-bridged iron(III) porphyrins
Der-Hang Chin, Alan L. Balch, and Gerd N. La Mar
pp 1446 - 1448; DOI:
10.1021/ja00524a051
PDF
Association of d6 and d8 metal complexes in solution. Formation of (p-CH3C6H4NH2)Ir(CO)2Cl/(p-CH3C6H4NH2)Ir(CO)2ClI2
Alan L. Balch and Jose R. Yow
pp 1448 - 1449; DOI:
10.1021/ja00524a052
PDF
Population redistribution to enhance NMR sensitivity and allow decoupling of low gyromagnetic ratio nuclei
Philip H. Bolton and Thomas L. James
pp 1449 - 1450; DOI:
10.1021/ja00524a053
PDF
Mechanism of reaction of dimethylsilylene with .alpha.,.beta.-unsaturated epoxides
Dongjaw Tzeng and William P. Weber
pp 1451 - 1451; DOI:
10.1021/ja00524a054
PDF
Bleomycin: synthesis and structural verification of the tripeptide S and tetrapeptide S moieties
Mark D. Levin, K. Subrahamanian, Howard Katz, Michael B. Smith, Donald J. Burlett, and Sidney M. Hecht
pp 1452 - 1453; DOI:
10.1021/ja00524a055
PDF
Ammoximation: direct synthesis of oximes from ammonia, oxygen and ketones
John N. Armor
pp 1453 - 1454; DOI:
10.1021/ja00524a056
PDF
Stereoselective total synthesis of (.+-.)-perhydrogephyrotoxin. Synthetic applications of directed 2-azonia-[3,3]-sigmatropic rearrangements
Larry E. Overman and Chikara Fukaya
pp 1454 - 1456; DOI:
10.1021/ja00524a057
PDF
A new reaction for the conversion of carbon monoxide into methane: proton-induced reduction of carbon monoxide in a metal carbonyl cluster, [Fe4(CO)132-]
Kenton Whitmire and Duward F. Shriver
pp 1456 - 1457; DOI:
10.1021/ja00524a058
PDF
Tandem directed metalation reactions. Short syntheses of polycyclic aromatic hydrocarbons and ellipticine alkaloids
M. Watanabe and V. Snieckus
pp 1457 - 1460; DOI:
10.1021/ja00524a059
PDF
Determination of rotational correlation time from perturbed angular correlation of .gamma. rays: apomyoglobin reconstituted with 111indium(III) mesoprotoporphyrin IX
Alan G. Marshall, K. M. Lee, and Peter W. Martin
pp 1460 - 1462; DOI:
10.1021/ja00524a060
PDF
Structures of novel anthracycline antitumor antibiotics from Micromonospora peucetica
Federico Arcamone, Guiseppe Cassinelli, Franco DiMatteo, Salvatore Forenza, M. Clara Ripamonti, Giovanni Rivola, Aristide Vigevani, Jon Clardy, and Terrence McCabe
pp 1462 - 1463; DOI:
10.1021/ja00524a061
PDF
Hydrogen-deuterium kinetic isotope effects for .gamma.-hydrogen rearrangement in 2-hexanone following photochemical excitation, electron impact ionization, and anodic oxidation
Mark M. Green, G. J. Mayotte, Louis Meites, and David Forsyth
pp 1464 - 1465; DOI:
10.1021/ja00524a062
PDF
The mechanism of flavin 4a substitution which accompanies photolytic decarboxylation of .alpha.-substituted acetic acids. Carbanion vs. radical intermediates
Michael Novak, Audrey Miller, Thomas C. Bruice, and Gordon Tollin
pp 1465 - 1467; DOI:
10.1021/ja00524a063
PDF
Biotin biosynthesis. 2. Stereochemistry of sulfur introduction at C-4 of dethiobiotin
Diane A. Trainor, Ronald J. Parry, and Amy Gitterman
pp 1467 - 1468; DOI:
10.1021/ja00524a064
PDF
An explanation of unusual properties of spin-crossover ferric complexes
Muin S. Haddad, Wayne D. Federer, Michael W. Lynch, and David N. Hendrickson
pp 1468 - 1470; DOI:
10.1021/ja00524a065
PDF
Toward synthetic models for cytochrome oxidase: a binuclear iron(III) porphyrin-copper(II) complex
Maxwell J. Gunter, Lewis N. Mander, George M. McLaughlin, Keith S. Murray, Kevin J. Berry, Paul E. Clark, and David A. Buckingham
pp 1470 - 1473; DOI:
10.1021/ja00524a066
PDF
Book Reviews

pp 1474 - 1478; DOI:
10.1021/ja00524a600
PDF

Issue 5


Aspects of artificial photosynthesis. Photosensitized electron transfer and charge separation in cationic surfactant vesicles
Pierre P. Infelta, Michael Graetzel, and Janos H. Fendler
pp 1479 - 1483; DOI:
10.1021/ja00525a001
PDF
Aspects of artificial photosynthesis. Energy transfer in cationic surfactant vesicles
Tadashi Nomura, Jose R. Escabi-Perez, Junzo Sunamoto, and Janos H. Fendler
pp 1484 - 1488; DOI:
10.1021/ja00525a002
PDF
Semiconductor electrodes. 27. The p- and n-gallium arsenide-N,N'-dimethyl-4,4'-bipyridinium system. Enhancement of hydrogen evolution on p-gallium arsenide and stabilization of n-gallium arsenide electrodes
Fu-Ren F. Fan, Benjamin Reichman, and Allen J. Bard
pp 1488 - 1492; DOI:
10.1021/ja00525a003
PDF
Interrelationships between the pseudorotation parameters P and .tau.m and the geometry of the furanose ring
E. Westhof and M. Sundaralingam
pp 1493 - 1500; DOI:
10.1021/ja00525a004
PDF
The geometry of the phenyl ring in substituted benzene molecules. A molecular orbital approach
J. A. Campos, J. Casado, and M. A. Rios
pp 1501 - 1504; DOI:
10.1021/ja00525a005
PDF
Theoretical studies of the structures and reactions of substituted carbonyl ylides
K. N. Houk, Nelson G. Rondan, Cielo Santiago, Catherine J. Gallo, Ruth Wells Gandour, and Gary W. Griffin
pp 1504 - 1512; DOI:
10.1021/ja00525a006
PDF
Study of the stereochemistry, relaxation mechanisms, and internal motions of natural products utilizing proton relaxation parameters: solution and crystal structures of saxitoxin
Neri Niccolai, Heinrich K. Schnoes, and William A. Gibbons
pp 1513 - 1517; DOI:
10.1021/ja00525a007
PDF
Proton spin-lattice relaxation studies of [D-Ala2-Met5]enkephalin
Neri Niccolai, Victor Garsky, and William A. Gibbons
pp 1517 - 1520; DOI:
10.1021/ja00525a008
PDF
A nuclear magnetic resonance study of the local conformation and molecular motions of poly(N5-(3-hydroxypropyl)-L-glutamine) in aqueous solution
Bruno Perly, Claude Chachaty, and Akihiro Tsutsumi
pp 1521 - 1528; DOI:
10.1021/ja00525a009
PDF
Molecular complexes. 3. Nonparallel and nonlinear slopes of NMR Scatchard plots caused by additional unspecific shielding
Helmut Stamm, Wilfried Lamberty, and Juergen Stafe
pp 1529 - 1531; DOI:
10.1021/ja00525a010
PDF
Nuclear magnetic resonance studies of alkynes as four-electron donor ligands in monomeric tungsten(II) complexes
Bennett C. Ward and Joseph L. Templeton
pp 1532 - 1538; DOI:
10.1021/ja00525a011
PDF
Applications of structure-resonance theory. 12. Resonance energies of .pi.-hydrocarbon-iron tricarbonyl complexes
William C. Herndon
pp 1538 - 1541; DOI:
10.1021/ja00525a012
PDF
Relative reactivities of methyl iodide and methyl tosylate with transition-metal nucleophiles
Ralph G. Pearson and Phillip E. Figdore
pp 1541 - 1547; DOI:
10.1021/ja00525a013
PDF
Silver atoms and small silver clusters in ice and wax matrix supports
Helmut Huber, Peter Mackenzie, and Geoffrey A. Ozin
pp 1548 - 1552; DOI:
10.1021/ja00525a014
PDF
Crystallization of calcium phosphates. A constant composition study
P. Koutsoukos, Z. Amjad, M. B. Tomson, and G. H. Nancollas
pp 1553 - 1557; DOI:
10.1021/ja00525a015
PDF
A study of structure and dynamic stereochemistry in seven coordination: HMo[P(OCH3)3]4[O2CCF3]
S. S. Wreford, J. K. Kouba, J. F. Kirner, E. L. Muetterties, I. Tavanaiepour, and V. W. Day
pp 1558 - 1563; DOI:
10.1021/ja00525a016
PDF
Photochemical reduction of some carboxylatopentaamminecobalt(III) complexes by tris(bipyridine)ruthenium(II). Evidence for cage recombination reactions
Wolfhart Boettcher and Albert Haim
pp 1564 - 1569; DOI:
10.1021/ja00525a017
PDF
Tetra(2-oxopyridinato)chloroditechnitium. A new compound with a technetium-technetium bond of order 3.5 and a remarkable vibronic absorption spectrum
F. Albert Cotton, Phillip E. Fanwick, and Larry D. Gage
pp 1570 - 1577; DOI:
10.1021/ja00525a018
PDF
Synthetic methods. 15. Unsaturated acyl derivatives of silicon, germanium, and tin from metalated enol ethers
John A. Soderquist and Alfred Hassner
pp 1577 - 1583; DOI:
10.1021/ja00525a019
PDF
Bis(trimethylsilyl)-, trimethylsilyltrimethylgermyl-, and bis(trimethylgermyl)diazomethane. Synthesis and chemistry of quantitative silene and germene precursors
Thomas J. Barton and S. Kent Hoekman
pp 1584 - 1591; DOI:
10.1021/ja00525a020
PDF
Gas-phase heats of formation of keto and enol ions of carbonyl compounds
John L. Holmes and F. P. Lossing
pp 1591 - 1595; DOI:
10.1021/ja00525a021
PDF
Ion-molecule complexes in unimolecular fragmentations of gaseous cations. Alkyl phenyl ether molecular ions
Thomas Hellman Morton
pp 1596 - 1602; DOI:
10.1021/ja00525a022
PDF
.gamma.-Alkylation of .alpha.,.beta.-unsaturated ketones. .gamma.-Arylsulfonyl groups as regioselective control elements
Peter T. Lansbury, Robert W. Erwin, and David A. Jeffrey
pp 1602 - 1608; DOI:
10.1021/ja00525a023
PDF
Effect of pH on the behavior of duroquinone triplets
J. C. Scaiano and P. Neta
pp 1608 - 1611; DOI:
10.1021/ja00525a024
PDF
Regioselectivity in the addition of singlet and triplet carbenes to 1,1-dimethylallene. A probe for carbene multiplicity
Xavier Creary
pp 1611 - 1618; DOI:
10.1021/ja00525a025
PDF
Reactivity in methyl transfer reactions. 5. Relation between rates and equilibriums
Edward S. Lewis, Semyon Kukes, and Carl D. Slater
pp 1619 - 1623; DOI:
10.1021/ja00525a026
PDF
Specific substituent effects in the dehalogenation of halobenzene derivatives by the gaseous Broensted acid CH5+
Hei-Wun Leung and Alex G. Harrison
pp 1623 - 1628; DOI:
10.1021/ja00525a027
PDF
Tosylate oxygen scrambling associated with ion-pair return in the threo-3-p-anisyl-2-butyl system
Harlan L. Goering and Barry E. Jones
pp 1628 - 1633; DOI:
10.1021/ja00525a028
PDF
Intra- and intermolecular cyclization of olefinic tosylhydrazones under acidic conditions. A facile synthesis of bicyclic azoalkanes
R. Marshall Wilson, John W. Rekers, Alan B. Packard, and R. C. Elder
pp 1633 - 1641; DOI:
10.1021/ja00525a029
PDF
Mechanism of the reactions of dimethylsilylene with oxetanes
Tai-Yin Yang Gu and William P. Weber
pp 1641 - 1644; DOI:
10.1021/ja00525a030
PDF
Energy separation between secondary and tertiary bicyclo[2.1.1]hexyl cations. Partial bridging in carbocation structures
Lawrence R. Schmitz and Ted S. Sorensen
pp 1645 - 1648; DOI:
10.1021/ja00525a031
PDF
Iminium-ion formation and deuterium exchange by acetone in the presence of pyrrolidine, pyrazolidine, Isoxazolidine, and their acyclic analogs
Jack Hine and Ramon A. Evangelista
pp 1649 - 1655; DOI:
10.1021/ja00525a032
PDF
Thermochemical identification of the structural factors responsible for the thermodynamic instability of 3',5'-cyclic nucleotides
John A. Gerlt, Neal I. Gutterson, Pradip Datta, Bernard Belleau, and Christopher L. Penney
pp 1655 - 1660; DOI:
10.1021/ja00525a033
PDF
Theoretical calculations of hydrolysis energies of "high-energy" molecules. 3. Theoretical calculations on the geometric destabilization of 3',5'- and 2',3'-cyclic nucleotides
Frederick J. Marsh, Paul Weiner, John E. Douglas, Peter A. Kollman, George L. Kenyon, and John A. Gerlt
pp 1660 - 1665; DOI:
10.1021/ja00525a034
PDF
Conformational properties of 5-alkoxy and 5-alkyl substituted trimethylene phosphates in solution
John A. Gerlt, Neal I. Gutterson, Reed E. Drews, and Jay A. Sokolow
pp 1665 - 1670; DOI:
10.1021/ja00525a035
PDF
Structure of avoparcin components
W. J. McGahren, J. H. Martin, G. O. Morton, R. T. Hargreaves, R. A. Leese, F. M. Lovell, G. A. Ellestad, E. O'Brien, and J. S. E. Holker
pp 1671 - 1684; DOI:
10.1021/ja00525a036
PDF
Reactions of vitamin B12r with organic halides
Hans-Ulrich Blaser and Jack Halpern
pp 1684 - 1689; DOI:
10.1021/ja00525a037
PDF
Sulfenyl transfer rearrangement of sulfenimines (thiooximes). A novel synthesis of 7.alpha.-methoxycephalosporins and 6.alpha.-methoxypenicillins
E. M. Gordon, H. W. Chang, C. M. Cimarusti, B. Toeplitz, and J. Z. Gougoutas
pp 1690 - 1702; DOI:
10.1021/ja00525a038
PDF
Streptonigrin biosynthesis. 3. Determination of the primary precursors to the 4-phenylpicolinic acid portion
Steven J. Gould and Chiu Chin Chang
pp 1702 - 1706; DOI:
10.1021/ja00525a039
PDF
Streptonigrin biosynthesis. 4. Details of the tryptophan metabolism
Steven J. Gould, Chiu Chin Chang, Dennis S. Darling, John D. Roberts, and Michael Squillacote
pp 1707 - 1712; DOI:
10.1021/ja00525a040
PDF
Studies on free and enzyme-bound nicotinamide adenine dinucleotide free radicals
B. H. J. Bielski and P. C. Chan
pp 1713 - 1716; DOI:
10.1021/ja00525a041
PDF
Coordination chemistry of metal surfaces - carbon monoxide chemisorption states on platinum(111)
C. M. Friend, R. M. Gavin, E. L. Muetterties, and Min-Chi Tsai
pp 1717 - 1719; DOI:
10.1021/ja00525a042
PDF
Energy and electron-transfer processes of the lowest excited state of the tris(phenanthroline)rhodium(III) complex
Roberto Ballardini, Graziano Varani, and Vincenzo Balzani
pp 1719 - 1720; DOI:
10.1021/ja00525a043
PDF
Photocyclizations involving quinone-olefin charge-transfer exciplexes
R. Marshall Wilson and Arlene K. Musser
pp 1720 - 1722; DOI:
10.1021/ja00525a044
PDF
Synthesis of .eta.2-coordinated enamines by amination of a platinum(II) coordinated allene. A chemical and x-ray diffraction study
Augusto De Renzi, Paolo Ganis, Achille Panunzi, Aldo Vitagliano, and Giovanni Valle
pp 1722 - 1723; DOI:
10.1021/ja00525a045
PDF
2B2 benzoyloxy, a delocalized .sigma. radical
J. Michael McBride and Ronald A. Merrill
pp 1723 - 1725; DOI:
10.1021/ja00525a046
PDF
Metal clusters. 24. Synthesis and structure of heteronuclear metal carbide clusters
M. Tachikawa, A. C. Sievert, E. L. Muetterties, M. R. Thompson, C. S. Day, and V. W. Day
pp 1725 - 1727; DOI:
10.1021/ja00525a047
PDF
Photogeneration of intermediates involved in catalytic cycles. .beta.-Hydride elimination from the 16-electron alkyl species generated by irradiation of tricarbonyl(.eta.5-cyclopentadienyl)(n-pentyl)tungsten(II)
Romas J. Kazlauskas and Mark S. Wrighton
pp 1727 - 1730; DOI:
10.1021/ja00525a048
PDF
Heterodinuclear Di-.mu.-sulfido bridged dimers containing iron and molybdenum or tungsten. Structures of (Ph4P)2(FeMS9) complexes (M = molybdenum, tungsten)
D. Coucouvanis, N. C. Baenziger, E. D. Simhon, P. Stremple, D. Swenson, A. Kostikas, A. Simopoulos, V. Petrouleas, and V. Papaefthymiou
pp 1730 - 1732; DOI:
10.1021/ja00525a049
PDF
Synthesis and structural characterization of the (Ph4P)2[Cl2FeS2MS2FeCl2] complexes (M = molybdenum, tungsten). First example of a doubly bridging thiomolybdate (MoS4) unit and its possible relevance as a structural feature in the nitrogenase active site
D. Coucouvanis, N. C. Baenziger, E. D. Simhon, P. Stremple, D. Swenson, A. Simopoulos, A. Kostikas, V. Petrouleas, and V. Papaefthymiou
pp 1732 - 1734; DOI:
10.1021/ja00525a050
PDF
Allylcarbinyl-cyclopropylcarbinyl rearrangement
A. Effio, D. Griller, K. U. Ingold, A. L. J. Beckwith, and A. K. Serelis
pp 1734 - 1736; DOI:
10.1021/ja00525a051
PDF
Ion beam studies of organometallic chemistry. High energy "sampling" of reaction intermediates involved in carbon-carbon bond cleavage by transition metals
P. B. Armentrout and J. L. Beauchamp
pp 1736 - 1738; DOI:
10.1021/ja00525a052
PDF
Preference for the syn ene additions of 1O2 to 1-methylcycloalkenes. Correlation with ground-state geometry
Karl H. Schulte-Elte and Valentin Rautenstrauch
pp 1738 - 1740; DOI:
10.1021/ja00525a053
PDF
Isolation and characterization of penta-.mu.2-carbonyl-decacarbonylpentarhodate(1-): a key product in rhodium carbonyl chemistry
Alessandro Fumagalli, Thomas F. Koetzle, Fusao Takusagawa, Paolo Chini, Secondo Martinengo, and B. T. Heaton
pp 1740 - 1742; DOI:
10.1021/ja00525a054
PDF
Total synthesis of (.+-.)-aphidicolin
E. J. Corey, Marcus A. Tius, and Jagabandhu Das
pp 1742 - 1744; DOI:
10.1021/ja00525a055
PDF
Carrier-mediated selective transport of nucleotides through a liquid membrane
Iwao Tabushi, Yoshiaki Kobuke, and Junichi Imuta
pp 1744 - 1745; DOI:
10.1021/ja00525a056
PDF
Resolution and assignment of the 270-MHz proton spectrum of cellobiose by homo- and heteronuclear two-dimensional NMR
Laurance D. Hall, Gareth A. Morris, and Subramaniam Sukumar
pp 1745 - 1747; DOI:
10.1021/ja00525a057
PDF
Heterobimetallic hydrogen transfer in the reduction of metal acyl complexes
John A. Marsella and Kenneth G. Caulton
pp 1747 - 1748; DOI:
10.1021/ja00525a058
PDF
Conformations and rotation barriers in 1,8-bis(trimethylelement)naphthalenes
Frank A. L. Anet, Dan Donovan, Ulf Sjostrand, Franco Cozzi, and Kurt Mislow
pp 1748 - 1749; DOI:
10.1021/ja00525a059
PDF
Preparation and reactions of new dioxygen complexes of rhodium
Fumio Sakurai, Hiroharu Suzuki, Yoshihiko Morooka, and Tsuneo Ikawa
pp 1749 - 1751; DOI:
10.1021/ja00525a060
PDF
Selectivity of tertiary amine oxidations
Frederick D. Lewis and Tong-Ing Ho
pp 1751 - 1752; DOI:
10.1021/ja00525a061
PDF
Synthesis, crystal structure, and chemical reactivity of octacarbonyl-.mu.-methylene-diiron
Charles E. Sumner, Paul E. Riley, Raymond E. Davis, and R. Pettit
pp 1752 - 1754; DOI:
10.1021/ja00525a062
PDF
Ground-state quenching of the 2E excited state of tris(2,2'-bipyridine)chromium(3+) and tris(1,10-phenanthroline)chromium(3+)
R. Sriram, Morton Z. Hoffman, Mary A. Jamieson, and Nick Serpone
pp 1754 - 1756; DOI:
10.1021/ja00525a063
PDF
Synthesis of (.+-.)-linderalactone, (.+-.)-isolinderalactone, and (.+-.)-neolinderalactone
Aravamudan Gopalan and Philip Magnus
pp 1756 - 1757; DOI:
10.1021/ja00525a064
PDF
Stereoelectronic effects in the reactions of phosphate diesters, phosphoramidates, and phosphonates. 3. Ab initio molecular orbital calculations of transition states
David G. Gorenstein, Bruce A. Luxon, and Evelyn M. Goldfield
pp 1757 - 1759; DOI:
10.1021/ja00525a065
PDF
Reaction of Group VIB organoimido complexes with organozinc. Reductive elimination across a metal-nitrogen multiple bond
William A. Nugent and Richard L. Harlow
pp 1759 - 1760; DOI:
10.1021/ja00525a066
PDF
Photophysical investigations of chiral recognition in crown ethers
Pietro Tundo and Janos H. Fendler
pp 1760 - 1762; DOI:
10.1021/ja00525a067
PDF

Issue 6


Reaction of acetylene with fulminic acid. The prototype 1,3-dipolar cycloaddition
Andrew Komornicki, John D. Goddard, and Henry F. Schaefer
pp 1763 - 1769; DOI:
10.1021/ja00526a001
PDF
Transition states and selectivities of singlet carbene cycloadditions
Nelson G. Rondan, K. N. Houk, and Robert A. Moss
pp 1770 - 1776; DOI:
10.1021/ja00526a002
PDF
Electronic energy levels in a homologous series of unsubstituted linear polyenes
Kevin L. D'Amico, Christopher Manos, and Ronald L. Christensen
pp 1777 - 1782; DOI:
10.1021/ja00526a003
PDF
Gas phase ESCA studies of 2,5-diaza-1,6-dioxa-6a-thiapentalene and its selenium and tellurium analogs
L. J. Saethre, N. Martensson, S. Svensson, P. A. Malmquist, U. Gelius, and K. Siegbahn
pp 1783 - 1788; DOI:
10.1021/ja00526a004
PDF
Occupation numbers of natural orbitals as a criterion for biradical character. Different kinds of biradicals
Detlef Doehnert and Jaroslav Koutecky
pp 1789 - 1796; DOI:
10.1021/ja00526a005
PDF
Torsional modes in the multiphoton ionization spectrum of tetrachloroethylene
Barbara A. Heath and M. B. Robin
pp 1796 - 1800; DOI:
10.1021/ja00526a006
PDF
Rotating molecules trapped in pseudorotating cages
J. Manz
pp 1801 - 1806; DOI:
10.1021/ja00526a007
PDF
Symmetrical hydrogen bonding: molecular orbital theory of the .pi.-electron component
R. C. Haddon
pp 1807 - 1811; DOI:
10.1021/ja00526a008
PDF
Electronic structures of cephalosporins and penicillins. 11. Parabolic relationships between antibacterial activity of cephalosporins and .beta.-lactam reactivity predicted from molecular orbital calculations
Donald B. Boyd, David K. Herron, W. H. W. Lunn, and Wayne A. Spitzer
pp 1812 - 1814; DOI:
10.1021/ja00526a009
PDF
A theoretical investigation of the magnetic and ground-state properties of model oxyhemoglobin complexes
Zelek S. Herman and Gilda H. Loew
pp 1815 - 1821; DOI:
10.1021/ja00526a010
PDF
Nuclear magnetic resonance of high-spin ferric hemoproteins. Assignment of proton resonances in met-aquo myoglobins using deuterium-labeled hemes
Gerd N. La Mar, David L. Budd, Kevin M. Smith, and Kevin C. Langry
pp 1822 - 1827; DOI:
10.1021/ja00526a011
PDF
X-ray and NMR studies of L-4-hydroxyproline conformation in oligopeptides related to collagen
Christiane Garbay-Jaureguiberry, Bernadette Arnoux, Thierry Prange, Suzanne Wehri-Altenburger, Claudine Pascard, and Bernard P. Roques
pp 1827 - 1837; DOI:
10.1021/ja00526a012
PDF
BC(DEF) parameters. 1. The intrinsic dimensionality of intermolecular interactions in the liquid state
Richard D. Cramer
pp 1837 - 1849; DOI:
10.1021/ja00526a013
PDF
BC(DEF) parameters. 2. An empirical structure-based scheme for the prediction of some physical properties
Richard D. Cramer
pp 1849 - 1859; DOI:
10.1021/ja00526a014
PDF
Kinetics and mechanism of hydrolysis of a silicate triester, tris(2-methoxyethoxy)phenylsilane
K. J. McNeil, J. A. DiCaprio, D. A. Walsh, and R. F. Pratt
pp 1859 - 1865; DOI:
10.1021/ja00526a015
PDF
Stable carbocations. 224. Structure of cyclopropylcarbinyl and cyclobutyl cations. The 2,8-dimethyl-8,9-dehydro-2-adamantyl and 4-phenyl-2,5-dehydro-4-protoadamantyl cations
Roger K. Murray, Thomas M. Ford, G. K. Surya Prakash, and George A. Olah
pp 1865 - 1868; DOI:
10.1021/ja00526a016
PDF
Picosecond photophysics of covalently linked pyrochlorophyllide a dimer. Unique kinetics within the singlet manifold
Michael J. Pellin, Michael R. Wasielewski, and Kenneth J. Kaufmann
pp 1868 - 1873; DOI:
10.1021/ja00526a017
PDF
Photochemistry in organic pigment dispersions. Phthalocyanine-mediated photoproduction of hydrogen peroxide
J. R. Harbour, J. Tromp, and M. L. Hair
pp 1874 - 1876; DOI:
10.1021/ja00526a018
PDF
Relationship between surface morphology and solar conversion efficiency of tungsten diselenide photoanodes
H. J. Lewerenz, A. Heller, and F. J. DiSalvo
pp 1877 - 1880; DOI:
10.1021/ja00526a019
PDF
Homolytic cleavage of the sulfur-sulfur bond in dimethyl disulfide by cobalt ions in partially cobalt(II)-exchanged zeolite A, Co4Na4-A
V. Subramanian and Karl Seff
pp 1881 - 1884; DOI:
10.1021/ja00526a020
PDF
Five-coordinate dioxygen adducts of cobalt(II) complexes
Russell S. Drago, James R. Stahlbush, David J. Kitko, and John Breese
pp 1884 - 1889; DOI:
10.1021/ja00526a021
PDF
Axial ligation constants of iron(II) and cobalt(II) "capped" porphyrins
Paul E. Ellis, Jack E. Linard, Thomas Szymanski, Robert D. Jones, John R. Budge, and Fred Basolo
pp 1889 - 1896; DOI:
10.1021/ja00526a022
PDF
Oxygenation of iron(II) and cobalt(II) "capped" porphyrins
Jack E. Linard, Paul E. Ellis, John R. Budge, Robert D. Jones, and Fred Basolo
pp 1896 - 1904; DOI:
10.1021/ja00526a023
PDF
The x-ray photoelectron spectra of inorganic molecules. 25. X-ray photoelectron spectra of copper(I) and copper(II) complexes derived from macrocyclic ligands
R. R. Gagne, J. L. Allison, C. A. Koval, W. S. Mialki, T. J. Smith, and R. A. Walton
pp 1905 - 1909; DOI:
10.1021/ja00526a024
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A study of the iron borides. 1. Electron spectroscopy
David J. Joyner, Oliver Johnson, and David M. Hercules
pp 1910 - 1917; DOI:
10.1021/ja00526a025
PDF
Tetrakis[bis(difluorophosphino)methylamine]dichlorodimolybdenum. A new type of compound with a metal-metal triple bond
F. Albert Cotton, William H. Ilsley, and Wolfgang Kaim
pp 1918 - 1923; DOI:
10.1021/ja00526a026
PDF
Enthalpy of formation of dicesium octabromodirhenium(III), Cs2Re2Br8, and a thermochemical estimate of the energy of the rhenium-rhenium quadruple bond
Lester R. Morss, Robert J. Porcja, James W. Nicoletti, Joseph San Filippo, and H. Donald B. Jenkins
pp 1923 - 1927; DOI:
10.1021/ja00526a027
PDF
Reduction of coordinated carbon monoxide. Synthesis of neutral metal formyl and hydroxymethyl derivatives of the (cyclopentadienyl)dicarbonyl(nitrosyl)rhenium(1+) cation
Charles P. Casey, Mark A. Andrews, Donald R. McAlister, and James E. Rinz
pp 1927 - 1933; DOI:
10.1021/ja00526a028
PDF
Direct determinations of the ion pairing equilibrium constant and first-order rate constant for outer sphere electron transfer reactions
P. L. Gaus and Jorge L. Villanueva
pp 1934 - 1938; DOI:
10.1021/ja00526a029
PDF
Photochemical reactivity in organized assemblies. 16. Intramicellar electron transfer quenching of excited states. Determination of the binding constant and exchange rates for dimethylviologen
Russell H. Schmehl and David G. Whitten
pp 1938 - 1941; DOI:
10.1021/ja00526a030
PDF
Photophysical and photosensitized generation of singlet molecular oxygen (1.DELTA.g) in micellar solutions at elevated pressures. Measurement of singlet molecular oxygen solvent to micelle transfer rates via both molecular diffusion and energy transfer
I. B. C. Matheson and R. Massoudi
pp 1942 - 1948; DOI:
10.1021/ja00526a031
PDF
Molecular complexes of superoxide ion with maleic anhydride and its analogs
Yoshio Nosaka, Akira Kira, and Masashi Imamura
pp 1949 - 1953; DOI:
10.1021/ja00526a032
PDF
Olefinic nitrone and nitrile oxide [3 + 2] cycloadditions. A short stereospecific synthesis of biotin from cycloheptene
Pat N. Confalone, Giacomo Pizzolato, Dianne Lollar-Confalone, and Milan R. Uskokovic
pp 1954 - 1960; DOI:
10.1021/ja00526a033
PDF
Cyclic peroxides. 99. Stereospecific syntheses of the three trioxides of 1,3,5-cycloheptatriene via the endoperoxide-diepoxide rearrangement
Waldemar Adam and Metin Balci
pp 1961 - 1966; DOI:
10.1021/ja00526a034
PDF
Mercury in organic chemistry. 17. A convenient stereospecific synthesis of enol esters from vinylmercurials
R. C. Larock, K. Oertle, and K. M. Beatty
pp 1966 - 1974; DOI:
10.1021/ja00526a035
PDF
Timed Diels-Alder reactions
George A. Kraus and Michael J. Taschner
pp 1974 - 1977; DOI:
10.1021/ja00526a036
PDF
Production of a fluorescent conjugate acid of 8-methoxypsoralen and an unusual mechanism for its nonradiative decay
Himangshu R. Bhattacharjee, Eva L. Menger, and George S. Hammond
pp 1977 - 1983; DOI:
10.1021/ja00526a037
PDF
The octant rule. 7. Deuterium as an octant perturber
David A. Lightner, Jacek K. Gawronski, and Thomas D. Bouman
pp 1983 - 1990; DOI:
10.1021/ja00526a038
PDF
The .beta.-hydrogen secondary isotope effect in acyl transfer reactions. Origins, temperature dependence, and utility as a probe of transition-state structure
Ildiko M. Kovach, John L. Hogg, Tony Raben, Kevin Halbert, James Rodgers, and Richard L. Schowen
pp 1991 - 1999; DOI:
10.1021/ja00526a039
PDF
Chemistry of oxaziridines. 1. Synthesis and structure of 2-arenesulfonyl-3-aryloxaziridines. A new class of oxaziridines
Franklin A. Davis, Joseph Lamendola Jr., Upender Nadir, Edward W. Kluger, Thomas C. Sedergran, Thomas W. Panunto, Robert Billmers, Robert Jenkins Jr., Ignatius J. Turchi, and et al.
pp 2000 - 2005; DOI:
10.1021/ja00526a040
PDF
Reduction of cis-bicyclo[4.3.0]non-3-ene and its 8-substituted heterocyclic analogs
Bradford P. Mundy and John J. Theodore
pp 2005 - 2010; DOI:
10.1021/ja00526a041
PDF
Rate constants and equilibrium constants for thiol-disulfide interchange reactions involving oxidized glutathione
Richard P. Szajewski and George M. Whitesides
pp 2011 - 2026; DOI:
10.1021/ja00526a042
PDF
Solvolysis of D-glucopyranosyl derivatives in mixtures of ethanol and 2,2,2-trifluoroethanol
Michael L. Sinnott and William P. Jencks
pp 2026 - 2032; DOI:
10.1021/ja00526a043
PDF
Palladium-catalyzed coupling reactions of uracil nucleosides and nucleotides
Christopher F. Bigge, Panos Kalaritis, Joanne R. Deck, and Mathias P. Mertes
pp 2033 - 2038; DOI:
10.1021/ja00526a044
PDF
The penems, a new class of .beta.-lactam antibiotics. 5. Total synthesis of racemic 6-.alpha.-hydroxyethylpenemcarboxylic acids
H. R. Pfaendler, J. Gosteli, and R. B. Woodward
pp 2039 - 2043; DOI:
10.1021/ja00526a045
PDF
Host-guest complexation. 22. Reciprocal chiral recognition between amino acids and dilocular systems
Stephen S. Peacock, David M. Walba, Fred C. A. Gaeta, Roger C. Helgeson, and Donald J. Cram
pp 2043 - 2052; DOI:
10.1021/ja00526a046
PDF
Catalysis of the reversible elimination reactions of substituted N-(.beta.-phenylethyl)quinuclidinium ions in aqueous solution
Sergio Alunni and William P. Jencks
pp 2052 - 2060; DOI:
10.1021/ja00526a047
PDF
Studies on the syntheses of heterocyclic compounds. 800. A formal total synthesis of (.+-.)-thienamycin and a (.+-.)-decysteaminylthienamycin derivative
Tetsuji Kametani, Shyh-Pyng Huang, Shuichi Yokohama, Yukio Suzuki, and Masataka Ihara
pp 2060 - 2065; DOI:
10.1021/ja00526a048
PDF
Conformation and structure of cyclo-(dibenzylglycyl-L-proline) and cyclo-(di-L-prolyl-D-proline) in the crystalline state
J. W. Bats and H. Fuess
pp 2065 - 2070; DOI:
10.1021/ja00526a049
PDF
Crystal structure of 1-[3-(indol-3-yl)propyl]thymine. A model for protein-nucleic acid interactions
Donald Voet
pp 2071 - 2074; DOI:
10.1021/ja00526a050
PDF
Biosynthesis of the Cephalotaxus alkaloids. Investigations of the biosynthesis of deoxyharringtonine, isoharringtonine, and harringtonine
Amy Gitterman, Ronald J. Parry, Richard F. Dufresne, Daniel D. Sternbach, and Michael D. Cabelli
pp 2074 - 2081; DOI:
10.1021/ja00526a051
PDF
Transition-state properties and rate-limiting processes in the acetylation of acetylcholinesterase by natural and unnatural substrates
John L. Hogg, James P. Elrod, and Richard L. Schowen
pp 2082 - 2086; DOI:
10.1021/ja00526a052
PDF
Lithium and sodium 2,6-di-tert-butylphenoxides and the crystal and molecular structure of [Li(OC6H2Me-4-But2-2,6)(OEt2)]2
B. Cetinkaya, I. Gumrukcu, M. F. Lappert, J. L. Atwood, and R. Shakir
pp 2086 - 2088; DOI:
10.1021/ja00526a053
PDF
Bivalent germanium, tin, and lead 2,6-di-tert-butylphenoxides and the crystal and molecular structures of M(OC6H2Me-4-But2-2,6)2 (M = Ge or Sn)
B. Cetinkaya, I. Gumrukcu, M. F. Lappert, J. L. Atwood, R. D. Rogers, and M. J. Zaworotko
pp 2088 - 2089; DOI:
10.1021/ja00526a054
PDF
.beta.-Elimination from 6-alkylmercaptopurine ribonucleosides
Paul Cullis, Sue Kirkman, and Richard Wolfenden
pp 2089 - 2089; DOI:
10.1021/ja00526a055
PDF
Synthesis and molecular structure of Pd4[P(C6H5)2(CH3)]4(CO)5: a new tetranuclear carbonyl cluster
J. Dubrawski, J. C. Kriege-Simondsen, and R. D. Feltham
pp 2089 - 2091; DOI:
10.1021/ja00526a056
PDF
Conversion of aryl azides on nickel centers into tetraazadiene-nickel complexes [Ni0(Ar2N4)2], [CpNiI(Ar2N4)], and [(RNC)2Ni0(Ar2N4)]. Crystal structure of [Ni0{1,4-(3,5-Me2C6H3)2N4}2]
Peter Overbosch, Gerard Van Koten, and Ok Overbeek
pp 2091 - 2093; DOI:
10.1021/ja00526a057
PDF
Nitrilimines
Nils Henrik Toubro and Arne Holm
pp 2093 - 2094; DOI:
10.1021/ja00526a058
PDF
Palladium(0)-catalyzed reaction of .alpha.,.beta.-epoxy ketones leading to .beta.-diketones
M. Suzuki, A. Watanabe, and R. Noyori
pp 2095 - 2096; DOI:
10.1021/ja00526a059
PDF
Generation of a m-xylylene derivative and formation of a 2,2-metacyclophane
Joseph J. Gajewski, Ming Jing Chang, Peter J. Stang, and Thomas E. Fisk
pp 2096 - 2097; DOI:
10.1021/ja00526a060
PDF
Total synthesis of dl-coriolin
Samuel Danishefsky, Robert Zamboni, Michael Kahn, and Sarah Jane Etheredge
pp 2097 - 2098; DOI:
10.1021/ja00526a061
PDF
Reactions of arc generated carbon atoms with benzene
Keith A. Biesiada, Charles T. Koch, and Philip B. Shevlin
pp 2098 - 2100; DOI:
10.1021/ja00526a062
PDF
Transition-state binding energies and the nature of the reaction coordinate in inner-sphere electron-transfer reactions: a unified approach to methyl- and halogen-bridged reactions
John F. Endicott, Chung-Lai Wong, James M. Ciskowski, and K. P. Balakrishnan
pp 2100 - 2103; DOI:
10.1021/ja00526a063
PDF
Oxidative addition from a six-coordinate to an eight-coordinate complex. Single-crystal structures of dichlorobis[o-phenylenebis(dimethylarsine)]technetium perchlorate and tetrachlorobis[o-phenylenebis(dimethylarsine)]technetium hexafluorophosphate
Kenneth A. Glavan, Robert Whittle, Judith Faye Johnson, R. C. Elder, and Edward Deutsch
pp 2103 - 2104; DOI:
10.1021/ja00526a064
PDF
Bond energy and conformation of the molybdenum-to-molybdenum triple bond
Michael B. Hall
pp 2104 - 2106; DOI:
10.1021/ja00526a065
PDF
Mechanism of .beta.-peroxylactone decarboxylation
Waldemar Adam, Omar Cueto, and Luis N. Guedes
pp 2106 - 2107; DOI:
10.1021/ja00526a066
PDF
2,3-Benzobicyclo[2.2.2]oct-2-ene-5,7-diyl diradical as a common intermediate in the di-.pi.-methane rearrangement of 6,7-benzobicyclo[3.2.1]octa-2,6-diene and the denitrogenation of the corresponding tricycloazoalkane
Waldemar Adam, Nestor Carballeira, and Ottorino De Lucchi
pp 2107 - 2109; DOI:
10.1021/ja00526a067
PDF
Unusual thermal and photochemical transformations of the azoalkane 2,3-diaza-7,8-benzotricyclo[4.3.0.04,9]nona-2,7-diene
Waldemar Adam and Ottorino De Lucchi
pp 2109 - 2110; DOI:
10.1021/ja00526a068
PDF
.alpha.,.alpha.' Dianions of aliphatic ketones and the 1,3,5 trianion of 2,4-pentanedione: strongly nucleophilic carbonyl synthons
James S. Hubbard and Thomas M. Harris
pp 2110 - 2112; DOI:
10.1021/ja00526a069
PDF
Prediction of angles in tetrahedral complexes and pseudotetrahedral complexes with stereoactive pairs
I. D. Brown
pp 2112 - 2113; DOI:
10.1021/ja00526a070
PDF
Alkyltin(IV)-mediated carbocyclization
Timothy L. Macdonald and Sankaran Mahalingam
pp 2113 - 2115; DOI:
10.1021/ja00526a071
PDF
Reversing the selectivity of cyclodextrin bisimidazole ribonuclease mimics by changing the catalyst geometry
Ronald Breslow, Philippe Bovy, and Carol Lipsey Hersh
pp 2115 - 2117; DOI:
10.1021/ja00526a072
PDF
Synthesis of the polyether antibiotic monensin. 1. Strategy and degradations
David B. Collum, John H. McDonald, and W. Clark Still
pp 2117 - 2118; DOI:
10.1021/ja00526a073
PDF
Synthesis of the polyether antibiotic monensin. 2. Preparation of intermediates
David B. Collum, John H. McDonald, and W. Clark Still
pp 2118 - 2120; DOI:
10.1021/ja00526a074
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Synthesis of the polyether antibiotic monensin. 3. Coupling of precursors and transformation to monensin
David B. Collum, John H. McDonald, and W. Clark Still
pp 2120 - 2121; DOI:
10.1021/ja00526a075
PDF
Total synthesis of dl-antibiotic 593A
Tohru Fukuyama, R. Keith Frank, and Charles F. Jewell
pp 2122 - 2123; DOI:
10.1021/ja00526a076
PDF
Photochemistry and photocatalytic activity of a polynuclear metal carbonyl hydride: dodecacarbonyltetrahydridotetraruthenium
James L. Graff and Mark S. Wrighton
pp 2123 - 2125; DOI:
10.1021/ja00526a077
PDF
Convenient method for regiospecific carbon-carbon bond formation at the .gamma. position of allylic halides
Katsuyuki Ogura, Shigeko Furukawa, and Genichi Tsuchihashi
pp 2125 - 2127; DOI:
10.1021/ja00526a078
PDF
Singlet oxygenation of ketene acetals: formation of 1,2-dioxetanes and their thermal rearrangement to .alpha.-peroxy esters
Waldemar Adam, Javier Del Fierro, Fernando Quiroz, and Faris Yany
pp 2127 - 2128; DOI:
10.1021/ja00526a079
PDF
Half-sandwich cyclooctatetraenethorium compounds
Carole Le Vanda, Jeffrey P. Solar, and Andrew Streitwieser
pp 2128 - 2129; DOI:
10.1021/ja00526a080
PDF
Olefin epoxidation by an intermediate formed in the metal ion catalyzed oxygenation of azibenzil
Hong-Son Ryang and Christopher S. Foote
pp 2129 - 2131; DOI:
10.1021/ja00526a081
PDF
Synthesis and absolute configuration of 4,5-diazatwist-4-ene
Jerry A. Jenkins, Robert E. Doehner, and Leo A. Paquette
pp 2131 - 2133; DOI:
10.1021/ja00526a082
PDF
Minor and trace sterols in marine invertebrates. 15. Ficisterol (23-ethyl-24-methyl-27-norcholesta-5,25-dien-3.beta.-ol). A biosynthetically unprecedented sterol from the marine sponge Petrosia ficiformis
M. Wahid Khalil, Lois J. Durham, Carl Djerassi, and Donato Sica
pp 2133 - 2134; DOI:
10.1021/ja00526a083
PDF
Helixanes. The first primary helical molecules: Polyoxapolyspiroalkanones
David Gange, Philip Magnus, Lawrence Bass, Edward V. Arnold, and Jon Clardy
pp 2134 - 2135; DOI:
10.1021/ja00526a084
PDF
Book Reviews

pp 2135 - 2140; DOI:
10.1021/ja00526a600
PDF

Issue 7


Charge-transfer mechanism for electrophilic reactions. SE2 cleavage of alkylmetals with iodine
S. Fukuzumi and J. K. Kochi
pp 2141 - 2152; DOI:
10.1021/ja00527a001
PDF
Vertical and "nonvertical" energy transfer processes. A general classical treatment
Vincenzo Balzani, Fabrizio Bolletta, and Franco Scandola
pp 2152 - 2163; DOI:
10.1021/ja00527a002
PDF
Is there a nitroalkane anomaly?
Noam Agmon
pp 2164 - 2167; DOI:
10.1021/ja00527a003
PDF
Studies on monolayers. 1. Surface tension and absorption spectroscopic measurements of monolayers of surface-active azo and stilbene dyes
Juergen Heesemann
pp 2167 - 2176; DOI:
10.1021/ja00527a004
PDF
Studies on monolayers. 2. Designed monolayer assemblies of mixed films of surface-active azo dyes
Juergen Heesemann
pp 2176 - 2181; DOI:
10.1021/ja00527a005
PDF
Study of electrolytic solution process using the scaled-particle theory. 2. The standard entropy of solvation
Utpal Sen
pp 2181 - 2188; DOI:
10.1021/ja00527a006
PDF
Structure determination of 1-butene by gas electron diffraction, microwave spectroscopy, molecular mechanics, and molecular orbital constrained electron diffraction
D. Van Hemelrijk, L. Van den Enden, H. J. Geise, H. L. Sellers, and L. Schaefer
pp 2189 - 2195; DOI:
10.1021/ja00527a007
PDF
Molecular dynamics of cis-trans isomerization in rhodopsin
Robert R. Birge and Lynn M. Hubbard
pp 2195 - 2205; DOI:
10.1021/ja00527a008
PDF
Berry pseudorotation in ML5 molecules and microwave dielectric absorption
E. N. DiCarlo
pp 2205 - 2209; DOI:
10.1021/ja00527a009
PDF
Alkali hydroxide ion pairs. A Raman study
M. Moskovits and K. H. Michaelian
pp 2209 - 2215; DOI:
10.1021/ja00527a010
PDF
Carbon-13 nuclear magnetic resonance studies of the monocarboxylic acids of cyanocobalamin. Assignments of the b-, d-, and e-monocarboxylic acids
David L. Anton, Harry P. C. Hogenkamp, Thomas E. Walker, and Nicholas A. Matwiyoff
pp 2215 - 2219; DOI:
10.1021/ja00527a011
PDF
The structure of biologically important carbohydrates. A carbon-13 nuclear magnetic resonance study of tautomeric equilibriums in several hexulosonic acids and related compounds
Thomas C. Crawford, Glenn C. Andrews, Herman Faubl, and Gwendolyn N. Chmurny
pp 2220 - 2225; DOI:
10.1021/ja00527a012
PDF
Aluminum-27 NMR, a quadrupolar probe for the entatic state and stability of metallochromophores. A study of ferrichrome peptides at 65.1 MHz
Miguel Llinas and Antonio De Marco
pp 2226 - 2230; DOI:
10.1021/ja00527a013
PDF
The effect of spin saturation on nuclear Overhauser effects
Joseph H. Noggle
pp 2230 - 2232; DOI:
10.1021/ja00527a014
PDF
Aqueous lanthanide shift reagents. 8. Chiral interactions and stereochemical assignments of chemically and isotopically chiral ligands
Jacques Reuben
pp 2232 - 2237; DOI:
10.1021/ja00527a015
PDF
Anisotropy of the 1J(PSe) spin-spin coupling. X-ray and liquid crystal NMR study of trimethylphosphine selenide
A. Cogne, A. Grand, J. Laugier, J. B. Robert, and L. Wiesenfeld
pp 2238 - 2242; DOI:
10.1021/ja00527a016
PDF
Macrocyclization of poly(thiaethylene)
Wayne L. Mattice
pp 2242 - 2245; DOI:
10.1021/ja00527a017
PDF
Structures and stabilities of C3H6O+. isomers. An ab initio molecular orbital study
William J. Bouma, John K. MacLeod, and Leo Radom
pp 2246 - 2252; DOI:
10.1021/ja00527a018
PDF
A theoretical approach to substituent effects. Structural consequences of methyl hyperconjugation. Methyl tilt angles and carbon-hydrogen bond lengths
Addy Pross, Leo Radom, and Noel V. Riggs
pp 2253 - 2259; DOI:
10.1021/ja00527a019
PDF
Ab initio study of the conformations of the cyclohexyl and 1-hydroxycyclohexyl radicals
Roger V. Lloyd, J. Guy Causey, and Frank A. Momany
pp 2260 - 2263; DOI:
10.1021/ja00527a020
PDF
Molecular orbital study of tetrahedral, planar, and pyramidal structures of the isoelectronic series BH4-, CH4, NH4+, AlH4-, SiH4, and PH4+
Mary Beth Krogh-Jespersen, Jayaraman Chandrasekhar, Ernst Ulrich Wuerthwein, John B. Collins, and Paul Von Rague Schleyer
pp 2263 - 2268; DOI:
10.1021/ja00527a021
PDF
An MO study on the structure and the stability of the CH5+(CH4)n cluster (n = 0, 1, 2, and 3)
Shinichi Yamabe, Yoshihiro Osamura, and Tsutomu Minato
pp 2268 - 2273; DOI:
10.1021/ja00527a022
PDF
A study of the inclusive and exclusive cesium cryptates in nonaqueous solvents by cesium-133 NMR
Elisabeth Kauffmann, James L. Dye, Jean Marie Lehn, and A. I. Popov
pp 2274 - 2278; DOI:
10.1021/ja00527a023
PDF
Electrochemical studies of europium and ytterbium cryptate formation in aqueous solution. Effects of varying the metal oxidation state upon cryptate thermodynamics and kinetics
Edmund L. Yee, Otto A. Gansow, and Michael J. Weaver
pp 2278 - 2285; DOI:
10.1021/ja00527a024
PDF
Formation of 1-silacyclopenta-2,4-diene through recoil silicon atom reactions
E. E. Siefert, K. L. Loh, R. A. Ferrieri, and Y. N. Tang
pp 2285 - 2289; DOI:
10.1021/ja00527a025
PDF
Specific sequestering agents for the actinides. 3. Polycatecholate ligands derived from 2,3-dihydroxy-5-sulfobenzoyl conjugates of diaza- and tetraazaalkanes
Frederick L. Weitl and Kenneth N. Raymond
pp 2289 - 2293; DOI:
10.1021/ja00527a026
PDF
Preparation, physical properties, and x-ray structure of the mixed-valence compounds diferrocenylselenium iodine triiodide hemi(methylene chloride)
Jack A. Kramer, Frank H. Herbstein, and David N. Hendrickson
pp 2293 - 2301; DOI:
10.1021/ja00527a027
PDF
High-spin iron(II) in the porphyrin plane. Structural characterization of (meso-tetraphenylporphinato)bis(tetrahydrofuran)iron(II)
Christopher A. Reed, Toshio Mashiko, W. Robert Scheidt, K. Spartalian, and George Lang
pp 2302 - 2306; DOI:
10.1021/ja00527a028
PDF
Isotopic perturbation of degeneracy. A new technique for distinguishing monohapto and pentahapto cyclopentadienyl rings in fluxional systems with low rearrangement barriers
J. W. Faller, H. H. Murray, and M. Saunders
pp 2306 - 2309; DOI:
10.1021/ja00527a029
PDF
Chemically catalyzed net electrochemical oxidation of alcohols, aldehydes, and unsaturated hydrocarbons using the system (trpy)(bpy)Ru(OH2)2+/(trpy)(bpy)RuO2+
Bruce A. Moyer, Mark S. Thompson, and Thomas J. Meyer
pp 2310 - 2312; DOI:
10.1021/ja00527a030
PDF
Substitution and cleavage in the reaction of some benzyl(carbonyl)metal complexes with trifluoroacetic acid
Stewart N. Anderson, Christopher J. Cooksey, Steven G. Holton, and Michael D. Johnson
pp 2312 - 2318; DOI:
10.1021/ja00527a031
PDF
Lewis acid mediated reactions of organocopper reagents. A remarkably enhanced regioselective .gamma.-attack of allylic halides and direct alkylation of allylic alcohols via RCu.cntdot.BF3 system
Yoshinori Yamamoto, Shinichi Yamamoto, Hidetaka Yatagai, and Kazuhiro Maruyama
pp 2318 - 2325; DOI:
10.1021/ja00527a032
PDF
Tunneling model for hydrogen abstraction reactions in low-temperature solids. Application to reactions in alcohol glasses and acetonitrile crystals
Robert J. Le Roy, Hisao Murai, and Ffrancon Williams
pp 2325 - 2334; DOI:
10.1021/ja00527a033
PDF
Coenzyme models. 20. Flavin trapping of carbanion intermediates as catalyzed by cyanide ion and cationic micelle
Seiji Shinkai, Takaharu Yamashita, Yumiko Kusano, Toyoko Ide, and Osamu Manabe
pp 2335 - 2340; DOI:
10.1021/ja00527a034
PDF
Cyclobutane-bicyclobutane system. 3. Free, hydrogen-bonded, and cation-stabilized carbanions .alpha. to a cyano group in a cyclobutane ring
Shmaryahu Hoz and Doron Aurbach
pp 2340 - 2345; DOI:
10.1021/ja00527a035
PDF
Formation kinetics of an amino carboxy type merostabilized free radical
Richard W. Bennett, Donald L. Wharry, and Tad H. Koch
pp 2345 - 2349; DOI:
10.1021/ja00527a036
PDF
A ranking of diylophilic reactivities of olefins toward the singlet and triplet forms of the trimethylenemethane biradical, 2-isopropylidenecyclopenta-1,3-diyl
Charles D. Duncan, Leonard R. Corwin, James H. Davis, and Jerome A. Berson
pp 2350 - 2358; DOI:
10.1021/ja00527a037
PDF
Direct measurements of the absolute rates of dimerization and capture of the 2-isopropylidenecyclopenta-1,3-diyl species by electron paramagnetic resonance spectroscopy
Matthew S. Platz and Jerome A. Berson
pp 2358 - 2364; DOI:
10.1021/ja00527a038
PDF
Nitrogen-15 nuclear magnetic resonance spectroscopy. Products and rearrangements in the reaction of p-toluenesulfonyl azide-3-15N with the sodium salt of p-toluenesulfonamide. An in situ nitrogen-15 NMR study
Carla Casewit and John D. Roberts
pp 2364 - 2368; DOI:
10.1021/ja00527a039
PDF
Charge-transfer quenching of singlet excited complexes
Richard A. Caldwell, David Creed, D. C. DeMarco, Lynn A. Melton, Hiroyuki Ohta, and Paul H. Wine
pp 2369 - 2377; DOI:
10.1021/ja00527a040
PDF
Novel photochemical rearrangements of citral and related compounds at elevated temperatures
Steven Wolff, Francis Barany, and William C. Agosta
pp 2378 - 2386; DOI:
10.1021/ja00527a041
PDF
Temperature dependence of bromine kinetic isotope effects for reactions of n-butyl and tert-butyl bromides
John F. Willey and James W. Taylor
pp 2387 - 2391; DOI:
10.1021/ja00527a042
PDF
Thio-Claisen and Cope rearrangements. A general method for the synthesis of .alpha.,.beta.,.alpha.,.zeta.-unsaturated thioamides
Yoshinao Tamaru, Toshiro Harada, and Zenichi Yoshida
pp 2392 - 2398; DOI:
10.1021/ja00527a043
PDF
Mass spectrometry of phosphate esters. Phosphoacetoin and its methyl esters
Seymour Meyerson, Eugene S. Kuhn, Fausto Ramirez, James F. Marecek, and Hiroshi Okazaki
pp 2398 - 2409; DOI:
10.1021/ja00527a044
PDF
Star-branched polymers. 5. The .theta. temperature depression for 8- and 12-arm polyisoprenes in dioxane
B. J. Bauer, N. Hadjichristidis, L. J. Fetters, and J. E. L. Roovers
pp 2410 - 2413; DOI:
10.1021/ja00527a045
PDF
An annelation approach to the synthesis of eudesmane and elemane sesquiterpene lactones. Total synthesis of dl-dihydrocallitrisin, dl-7,8-epialantolactone, dl-7,8-epiisoalantolactone, and dl-atractylon
Arthur G. Schultz and Jollie D. Godfrey
pp 2414 - 2428; DOI:
10.1021/ja00527a046
PDF
Nuclear magnetic resonance studies on new six-coordinate high-spin ferric porphyrin complexes as models for aquometmyoglobin. 1. Formation of alcohol-coordinated octaethylporphyrin complexes in solution
Isao Morishima, Susumu Kitagawa, Eizo Matsuki, and Toshiro Inubushi
pp 2429 - 2437; DOI:
10.1021/ja00527a047
PDF
Bacteriochlorophylls c from Chloropseudomonas ethylicum. Composition and NMR studies of the pheophorbides and derivatives
Kevin M. Smith, Michael J. Bushell, John Rimmer, and John F. Unsworth
pp 2437 - 2448; DOI:
10.1021/ja00527a048
PDF
Rhodium-103 NMR evidence for charge separation and fluxionality among rhodium atoms in metal clusters
Otto A. Gansow, Devinder S. Gill, Frank J. Bennis, James R. Hutchinson, Jose L. Vidal, and Richard C. Schoening
pp 2449 - 2450; DOI:
10.1021/ja00527a049
PDF
A novel [1,2] alkyl shift in a blocked aromatic anion
Bernard Miller and Ajit K. Bhattacharya
pp 2450 - 2451; DOI:
10.1021/ja00527a050
PDF
Pyridine-containing polymers: new matrices for protein immobilization
F. Pittner, T. Miron, G. Pittner, and M. Wilchek
pp 2451 - 2452; DOI:
10.1021/ja00527a051
PDF
Highly selective membrane transport of lead(2+) ion from aqueous metal ion mixtures using macrocyclic carriers
J. D. Lamb, R. M. Izatt, P. A. Robertson, and J. J. Christensen
pp 2452 - 2454; DOI:
10.1021/ja00527a052
PDF
Cadmium-113 NMR spectrum of substituted horse liver alcohol dehydrogenase
Barrett R. Bobsein and Rollie J. Myers
pp 2454 - 2455; DOI:
10.1021/ja00527a053
PDF
Stepwise reduction of an ethynyl-iron complex to a neopentylidene complex
Alan Davison and John P. Selegue
pp 2455 - 2456; DOI:
10.1021/ja00527a054
PDF
Novel transformation of primary, secondary, and tertiary amines to organoselenides with ruthenium catalyst
Shunichi Murahashi and Tsuneo Yano
pp 2456 - 2458; DOI:
10.1021/ja00527a055
PDF
Synthesis and crystal structures of cycloheptatrienylidene complexes of iron
Paul E. Riley, Raymond E. Davis, Neil T. Allison, and W. M. Jones
pp 2458 - 2460; DOI:
10.1021/ja00527a056
PDF
Stereospecific alkylation of a carbanion in the solid state
J. F. Biellmann, J. F. Blanzat, and J. J. Vicens
pp 2460 - 2461; DOI:
10.1021/ja00527a057
PDF
Light-induced charge separation by functional micellar assemblies
Pierre Alain Brugget and Michael Graetzel
pp 2461 - 2463; DOI:
10.1021/ja00527a058
PDF
Total synthesis of (.+-.)-coronafacic acid: use of anionic oxy-Cope rearrangements on aromatic substrates in synthesis
Michael E. Jung and James P. Hudspeth
pp 2463 - 2464; DOI:
10.1021/ja00527a059
PDF
Secondary deuterium isotope effects on epoxide methanolysis reactions
Robert P. Hanzlik and Richard B. Westkaemper
pp 2464 - 2467; DOI:
10.1021/ja00527a060
PDF
Vesicle formation by two novel synthetic amphiphiles carrying micropolarity reporter head groups
Ernst J. R. Sudhoelter, Jan B. F. N. Engberts, and Dick Hoekstra
pp 2467 - 2469; DOI:
10.1021/ja00527a061
PDF
Stereochemistry of the thermal walk rearrangement of optically active 2,7-dimethyl-7-methoxymethyl-1,3,5-cycloheptatriene: 1,5-carbon migration with inversion, no one-center epimerization at C-7
Frank Gerrit Klaerner and Barbara Brassel
pp 2469 - 2470; DOI:
10.1021/ja00527a062
PDF
Light-induced simultaneous photooxidation and photoreduction of zinc tetraphenylporphyrin radical cation
W. Potter, R. N. Young, and G. Levin
pp 2471 - 2473; DOI:
10.1021/ja00527a063
PDF
Synthesis of allylcarboxylic acids from olefins with diethyl oxomalonate, an enophilic equivalent of carbon dioxide
Mary F. Salomon, Simon N. Pardo, and Robert G. Salomon
pp 2473 - 2475; DOI:
10.1021/ja00527a064
PDF
trans-Bromo(2-, 3-, and 4-pyridyl)bis(triethylphosphine)palladium(II) complexes
Kiyoshi Isobe, Eiko Kai, Yukio Nakamura, Kichisuke Nishimoto, Toshio Miwa, Shinichi Kawaguchi, Kenji Kinoshita, and Kazumi Nakatsu
pp 2475 - 2476; DOI:
10.1021/ja00527a065
PDF
Structural characterization of a technetium-99-diphosphonate complex. Implications for the chemistry of technetium-99m skeletal imaging agents
Karen Libson, Edward Deutsch, and B. L. Barnett
pp 2476 - 2478; DOI:
10.1021/ja00527a066
PDF
Shape-selective Fischer-Tropsch synthesis catalyzed by zeolite-entrapped cobalt clusters
Dan Fraenkel and Bruce C. Gates
pp 2478 - 2480; DOI:
10.1021/ja00527a067
PDF
Platinum(II) antitumor agents. A new class of intrastrand crosslinking models exhibiting significant intracomplex base-base interactions
Luigi G. Marzilli, Purush Chalilpoyil, Chian C. Chiang, and Thomas J. Kistenmacher
pp 2480 - 2482; DOI:
10.1021/ja00527a068
PDF
Gas-phase heats of formation of C2H5+ and C3H7+
Tomas Baer
pp 2482 - 2483; DOI:
10.1021/ja00527a069
PDF
Solvent effects on ion-molecule reactions. Vinyl anions vs. conjugate addition
John E. Bartmess
pp 2483 - 2484; DOI:
10.1021/ja00527a070
PDF
Clusters and catalysis: on the requirement for multinuclear centers to catalyze the hydrogenation of carbon monoxide
Alan Brenner and Dennis A. Hucul
pp 2484 - 2487; DOI:
10.1021/ja00527a071
PDF
Sequence dependent binding of cis-dichlorodiammineplatinum(II) to DNA
Gary L. Cohen, Jay A. Ledner, William R. Bauer, H. Michael Ushay, Carl Caravana, and Stephen J. Lippard
pp 2487 - 2488; DOI:
10.1021/ja00527a072
PDF
Mechanism of oxidative cleavage of .alpha.-hydroxyalkylchromium complexes
James H. Espenson and Andreja Bakac
pp 2488 - 2489; DOI:
10.1021/ja00527a073
PDF
The chemistry of sulfines. 6. Dimer of the onion lachrymatory factor: the first stable 1,2-dithietane derivative
Eric Block, Ali A. Bazzi, and Larry K. Revelle
pp 2490 - 2491; DOI:
10.1021/ja00527a074
PDF
Kinetic .alpha.-deuterium isotope effects for acylation of chymotrypsin by 4-methoxyphenyl formate and for deacylation of formylchymotrypsin
Guillermo Lehrmann, Dan Quinn, and E. H. Cordes
pp 2491 - 2492; DOI:
10.1021/ja00527a075
PDF
Trapping of free alkyl radical intermediates in the reaction of alkyl bromdies with magnesium
Lynnette M. Lawrence and George M. Whitesides
pp 2493 - 2494; DOI:
10.1021/ja00527a076
PDF
Photochemical and thermal decomposition of hydridotetracarbonylcobalt(I). Evidence for a radical pathway involving octacarbonyldicobalt
R. W. Wegman and Theodore L. Brown
pp 2494 - 2495; DOI:
10.1021/ja00527a077
PDF
Adamantyl allenic rhodopsin. Leniency of the ring binding site in bovine opsin
Richard A. Blatchly, John D. Carriker, Valeria Balogh-Nair, and Koji Nakanishi
pp 2495 - 2497; DOI:
10.1021/ja00527a078
PDF
Nonradical intermediates in the photolysis of decacarbonyldimanganese
Arnold Fox and Anthony Poe
pp 2497 - 2499; DOI:
10.1021/ja00527a079
PDF
Stereochemical analysis of the homoserine dehydrogenase reaction and preparation of chiral 4-deuteriohomoserines
Michael N. Chang and Christopher Walsh
pp 2499 - 2501; DOI:
10.1021/ja00527a080
PDF
Prostaglandin endoperoxides. 11. Mechanism of amine-catalyzed fragmentation of 2,3-dioxabicyclo[2.2.1]heptane
Michael G. Zagorski and Robert G. Salomon
pp 2501 - 2503; DOI:
10.1021/ja00527a081
PDF
Chemistry of superoxide ion. 4. Singlet oxygen is not a major product of dismutation
C. S. Foote, F. C. Shook, and R. A. Abakerli
pp 2503 - 2504; DOI:
10.1021/ja00527a082
PDF
Host-guest complex formation between a water-soluble polyparacyclophane and a hydrophobic guest molecule
Kazunori Odashima, Akiko Itai, Yoichi Iitaka, and Kenji Koga
pp 2504 - 2505; DOI:
10.1021/ja00527a083
PDF
Inorganic pyrophosphate is released from 2'-chloro-2'-deoxyuridine 5'-diphosphate by ribonucleoside diphosphate reductase
JoAnne Stubbe and John W. Kozarich
pp 2505 - 2507; DOI:
10.1021/ja00527a084
PDF
An ab initio SCF study of the structure and vibrational spectrum of thiirene
B. Andes Hess, L. J. Schaad, and Carl S. Ewig
pp 2507 - 2508; DOI:
10.1021/ja00527a085
PDF
Synthetic applications of transition-metal-stabilized carbenium ions. Selective alkylation of ketones and ketone derivatives with (propargyl)dicobalt hexacarbonyl cations
Kenneth M. Nicholas, Margaret Mulvaney, and Michael Bayer
pp 2508 - 2510; DOI:
10.1021/ja00527a086
PDF
Biosynthetic incorporation of propionate and methionine into streptolydigin
Cedric J. Pearce, Stephen E. Ulrich, and Kenneth L. Rinehart
pp 2510 - 2512; DOI:
10.1021/ja00527a087
PDF
Additions and Corrections - Determination of the Absolute Configuration of a Secondary Hydroxy Group in a Chiral Secondary Alcohol Using Glycosidation Shifts in Carbon-13 Nuclear Magnetic Resonance Spectroscopy
Shujiro Seo, Yutaka Tomita, Kazuo Tori, and Yohko Yoshimura
pp 2512 - 2512; DOI:
10.1021/ja00527a600
PDF
Additions and Corrections - Calculated Infrared and Raman Spectra of the 1Ag Ground States of Rectangular Cyclobutadiene and Tetradeuteriocyclobutadiene
L. J. Schaad, B. Andes Hess, Jr., and Carl S. Ewig
pp 2512 - 2513; DOI:
10.1021/ja00527a601
PDF
Additions and Corrections - Effect of Electron Correlation on Theoretical Equilibrium Geometries
Douglas J. DeFrees, Beverly A. Levi, Steven K. Pollack, Warren J. Hehre, J. Stephen Binkley, and J. A. Pople
pp 2513 - 2513; DOI:
10.1021/ja00527a602
PDF
Additions and Corrections - Polymeric Psuedocrown Ethers. 1. Synthesis and Complexation with Transtition metal Anions
Abraham Warshawsky, Rami Kalir, Abraham Deshe, Hedva Berkovitz, and Avraham Patachornik
pp 2513 - 2513; DOI:
10.1021/ja00527a603
PDF
Additions and Corrections - Annulated Pyranosides as Chiral Synthons for Carbocyclic Systems. Enantiospecific Routes to Both (+) and (-) Chrysanthemumcarboxylic Acids from a Single Progenitor
Brian J. Fitzsimmons, and Bert Fraser-Reid
pp 2513 - 2513; DOI:
10.1021/ja00527a604
PDF
Additions and Corrections - Gas-Phase Nitrosation of Benzene. Implications for Solution Electrophilic Aromatic Substitution Reactions.
W. D. Reents, Jr., and B. S. Freiser
pp 2513 - 2513; DOI:
10.1021/ja00527a605
PDF
Book Reviews

pp 2514 - 2518; DOI:
10.1021/ja00527a606
PDF

Issue 8


Studies in nuclear magnetic resonance spectroscopy. 17. Deuteron quadrupole coupling constants in intramolecularly hydrogen bonded systems
L. M. Jackman, J. C. Trewella, and R. C. Haddon
pp 2519 - 2525; DOI:
10.1021/ja00528a001
PDF
Adiabatic J cross-polarization in liquids for signal enhancement in NMR
G. C. Chingas, A. N. Garroway, W. B. Moniz, and R. D. Bertrand
pp 2526 - 2528; DOI:
10.1021/ja00528a002
PDF
Ring inversion in 1,4,7-cyclononatriene (trishomobenzene). Force-field calculations for abnormally large bond angles
Frank A. L. Anet and Mehran Ghiaci
pp 2528 - 2533; DOI:
10.1021/ja00528a003
PDF
Torsion angles in the cystine bridge of oxytocin in aqueous solution. Measurements of circumjacent vicinal couplings between proton, carbon-13, and nitrogen-15
Alan J. Fischman, David H. Live, Herman R. Wyssbrod, William C. Agosta, and David Cowburn
pp 2533 - 2539; DOI:
10.1021/ja00528a004
PDF
Proton-transfer reactions involving alkyl ions and alkenes. Rate constants, isomerization processes, and the derivation of thermochemical data
S. G. Lias, D. M. Shold, and P. Ausloos
pp 2540 - 2548; DOI:
10.1021/ja00528a005
PDF
A vibrational study of zirconium tetraborohydride supported on aluminum oxide. 1. Interactions with deuterium, deuterium oxide, and water vapor
H. E. Evans and W. H. Weinberg
pp 2548 - 2553; DOI:
10.1021/ja00528a006
PDF
A vibrational study of zirconium tetraborohydride supported on aluminum oxide. 2. Interactions with ethylene, propylene, and acetylene
H. E. Evans and W. H. Weinberg
pp 2554 - 2558; DOI:
10.1021/ja00528a007
PDF
Variational transition state theory. Primary kinetic isotope effects for atom transfer reactions
Bruce C. Garrett and Donald G. Truhlar
pp 2559 - 2570; DOI:
10.1021/ja00528a008
PDF
Cleaving carbon-carbon bonds in cyclopropenium ions
Eluvathingal D. Jemmis and Roald Hoffmann
pp 2570 - 2575; DOI:
10.1021/ja00528a009
PDF
Cp2M2(CO)4 - quadruply bridging, doubly bridging, semibridging, or nonbridging?
Eluvathingal D. Jemmis, Allan R. Pinhas, and Roald Hoffmann
pp 2576 - 2585; DOI:
10.1021/ja00528a010
PDF
Evidence for the incursion of intermediates in the hydrolysis of tertiary, secondary, and primary substrates
Michael Jesse Blandamer, Ross Elmore Robertson, John Marshall William Scott, and Alice Vrielink
pp 2585 - 2592; DOI:
10.1021/ja00528a011
PDF
Semiconductor electrodes. 26. Spectral sensitization of semiconductors with phthalocyanine
Calvin D. Jaeger, Fu-Ren F. Fan, and Allen J. Bard
pp 2592 - 2598; DOI:
10.1021/ja00528a012
PDF
Charge-transfer absorptions of copper(II)-imidazole and copper(II)-imidazolate chromophores
Timothy G. Fawcett, Ernest E. Bernarducci, Karsten Krogh-Jespersen, and Harvey J. Schugar
pp 2598 - 2604; DOI:
10.1021/ja00528a013
PDF
Visual pigments. 11. Spectroscopy and photophysics of retinoic acids and all-trans-methyl retinoate
T. Takemura, K. Chihara, Ralph S. Becker, P. K. Das, and G. L. Hug
pp 2604 - 2609; DOI:
10.1021/ja00528a014
PDF
Vapor phase association in acetic and trifluoroacetic acids. Thermal conductivity measurements and molecular orbital calculations
D. J. Frurip, L. A. Curtiss, and M. Blander
pp 2610 - 2616; DOI:
10.1021/ja00528a015
PDF
An MO theoretical study on the stability of tetrahedrane
Herbert Kollmar
pp 2617 - 2621; DOI:
10.1021/ja00528a016
PDF
Ab initio study of bis(nitrogen dioxide)(1+) and bis(carbon dioxide)(1-) ions
Y. Yoshioka and K. D. Jordan
pp 2621 - 2626; DOI:
10.1021/ja00528a017
PDF
Photophysical and photochemical properties of chloropentaamminerhodium(2+) in nonaqueous solvents. Solvent control of the photolabilization pathways of the ligand field excited states
Michael A. Bergkamp, Richard J. Watts, and Peter C. Ford
pp 2627 - 2631; DOI:
10.1021/ja00528a018
PDF
Correlating phosphorus core binding energies, phosphorus lone pair ionization potentials, and proton affinities of tervalent phosphorus compounds
T. H. Lee, W. L. Jolly, A. A. Bakke, R. Weiss, and J. G. Verkade
pp 2631 - 2636; DOI:
10.1021/ja00528a019
PDF
High-resolution variable-temperature phosphorus-31 NMR of solid calcium phosphates
W. P. Rothwell, J. S. Waugh, and J. P. Yesinowski
pp 2637 - 2643; DOI:
10.1021/ja00528a020
PDF
Substituent effects in cluster species. 3. Structural consequences of intercage .pi. interactions in the dimer and trimer of 1,5-dicarbapentaborane(5)
E. L. Andersen, R. L. DeKock, and T. P. Fehlner
pp 2644 - 2650; DOI:
10.1021/ja00528a021
PDF
Electron spin-echo studies of radical interaction and orientation on catalytic surfaces. Hydroxymethyl radicals in A-, Y-, and X-type zeolites
Tsuneki Ichikawa and Larry Kevan
pp 2650 - 2653; DOI:
10.1021/ja00528a022
PDF
Electrochemistry of vitamin B12. 5. Cyanocobalamins
D. Lexa, J. M. Sayeant, and J. Zickler
pp 2654 - 2663; DOI:
10.1021/ja00528a023
PDF
Synthesis and spectroscopic and structural properties of bis(N-acetyl-DL-tryptophanato)copper(II) complex and its amine adducts. Effect of amines on the amino acid coordination. Crystal and molecular structure of diaquabis(N-acetyl-DL-tryptophanato)bis(pyridine)copper(II)
L. P. Battaglia, A. Bonamartini Corradi, G. Marcotrigiano, L. Menabue, and G. C. Pellacani
pp 2663 - 2669; DOI:
10.1021/ja00528a024
PDF
Metal-ion recognition by macrocyclic ligands. Thermodynamic stabilities of nickel complexes of a series of O2N2-donor macrocyclic ligands
Giorgio Anderegg, A. Ekstrom, Leonard F. Lindoy, and Roland J. Smith
pp 2670 - 2674; DOI:
10.1021/ja00528a025
PDF
Theory of hyperfine interaction in five-liganded divalent and trivalent manganese porphyrin systems
Shantilata Mishra, Jane C. Chang, and T. P. Das
pp 2674 - 2681; DOI:
10.1021/ja00528a026
PDF
Synthesis of perfluoroalkyl trifluoromethanesulfonates from perfluoroalkyl halides. Substitutive electrophilic dehalogenation with chlorine(I) and bromine(I) trifluoromethanesulfonates
Yutaka Katsuhara and Darryl D. DesMarteau
pp 2681 - 2686; DOI:
10.1021/ja00528a027
PDF
Reaction of .alpha.-arylvinyl halides with antimony pentafluoride. A proton and carbon-13 NMR spectroscopic investigation
Hans-Ullrich Siehl and Michael Hanack
pp 2686 - 2692; DOI:
10.1021/ja00528a028
PDF
Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents
P. Girard, J. L. Namy, and H. B. Kagan
pp 2693 - 2698; DOI:
10.1021/ja00528a029
PDF
Reactivity of alkyne tungsten and molybdenum complexes. Heterolytic carbon-hydrogen bond activation in coordinated alkynes
Patricia L. Watson and Robert G. Bergman
pp 2698 - 2703; DOI:
10.1021/ja00528a030
PDF
Crystal structure of a beauvericin-barium picrate complex
B. Braden, J. A. Hamilton, M. N. Sabesan, and L. K. Steinrauf
pp 2704 - 2709; DOI:
10.1021/ja00528a031
PDF
Topography of cyclodextrin inclusion complexes. 12. Structural chemistry of linear .alpha.-cyclodextrin-polyiodide complexes. X-ray crystal structures of (.alpha.-cyclodextrin)2.LiI3.I2.8H2O and (.alpha.-cyclodextrin)2.Cd0.5).I5.27H2O. Models for the blue amylose-iodine complex
M. Noltemeyer and W. Saenger
pp 2710 - 2722; DOI:
10.1021/ja00528a032
PDF
Preferred kinetic migration of methyl and preferred thermodynamic migration of phenyl in conversion of cis-acetylbenzoyltetracarbonylrhenate(I) to cis-benzoylmethyltetracarbonylrhenate(I) and cis-acetylphenyltetracarbonylrhenate(I)
Charles P. Casey and Daniel M. Scheck
pp 2723 - 2728; DOI:
10.1021/ja00528a033
PDF
Mechanism of reductive elimination of acetophenone from Me4+[cis-(CO)4Mn(COMe)(COPh)]-
Charles P. Casey and Daniel M. Scheck
pp 2728 - 2731; DOI:
10.1021/ja00528a034
PDF
Autoxidation of 2-tert-butyl-2,3-diazabicyclo[2.2.1]heptane. Stereospecific loss of hydrogen from N-3 and C-5, and N-3 and C-6
Stephen F. Nelsen and William P. Parmelee
pp 2732 - 2737; DOI:
10.1021/ja00528a035
PDF
Optical rotatory dispersion studies. 128. Octant contributions of methyl groups in 4-tert-butylcyclohexanones
Joseph P. Konopelski, P. Sundararaman, Guenter Barth, and Carl Djerassi
pp 2737 - 2745; DOI:
10.1021/ja00528a036
PDF
Role of through space 2p-3d overlap in the alkylation of (.omega.-N,N-dimethylaminoalkyl)diphenylphosphines and in the alkaline decomposition of related quaternary phosphonium salts
William E. McEwen, Joanne H. Smith, and Edward J. Woo
pp 2746 - 2751; DOI:
10.1021/ja00528a037
PDF
Unimolecular reactions of isolated organic ions. The importance of ion-dipole interactions
Richard D. Bowen and Dudley H. Williams
pp 2752 - 2756; DOI:
10.1021/ja00528a038
PDF
Further evidence for single electron transfer during the alkylation of the benzophenone anil dianion
James G. Smith and Douglas C. Irwin
pp 2757 - 2759; DOI:
10.1021/ja00528a039
PDF
Effect of solvation on .beta. values for formyl, acetyl, and pivaloyl transfer between sulfur and oxygen nucleophiles
Eric R. Pohl, Dorothy Wu, and D. J. Hupe
pp 2759 - 2763; DOI:
10.1021/ja00528a040
PDF
Secondary deuterium isotope effects on formyl transfer reactions between sulfur and oxygen nucleophiles
Eric R. Pohl and D. J. Hupe
pp 2763 - 2768; DOI:
10.1021/ja00528a041
PDF
Chiral secondary amides. 2. Molecular packing and chiral recognition
S. Weinstein, L. Leiserowitz, and E. Gil-Av
pp 2768 - 2772; DOI:
10.1021/ja00528a042
PDF
Structure, optical resolution, and conformational stability of perchlorotriphenylamine
Kathryn S. Hayes, Mark Nagumo, John F. Blount, and Kurt Mislow
pp 2773 - 2776; DOI:
10.1021/ja00528a043
PDF
Separation and identification of residual diastereomers in a maximally labeled triarylamine
Robert Glaser, John F. Blount, and Kurt Mislow
pp 2777 - 2786; DOI:
10.1021/ja00528a044
PDF
Photochemical kinetics of salicylidenaniline
P. F. Barbara, P. M. Rentzepis, and L. E. Brus
pp 2786 - 2791; DOI:
10.1021/ja00528a045
PDF
Photolysis of the endoperoxide of heterocoerdianthrone. A concerted, adiabatic cycloreversion originating from an upper excited singlet state
R. Schmidt, W. Drews, and H. D. Brauer
pp 2791 - 2797; DOI:
10.1021/ja00528a046
PDF
Thermal isomerization of allyl-substituted cyclopropenes. An example of a nonsynchronous cope rearrangement
Albert Padwa and Thomas J. Blacklock
pp 2797 - 2806; DOI:
10.1021/ja00528a047
PDF
Chemistry of exciplexes. 9. Viscosity effect on intramolecular exciplex formation in saturated hydrocarbons
Nein-Chu C. Yang, Soon Bin Neoh, Takeaki Naito, Lay-Keow Ng, Donald A. Chernoff, and Daniel B. McDonald
pp 2806 - 2810; DOI:
10.1021/ja00528a048
PDF
Nucleophilic addition to activated olefins. 3. Reactions of piperidine and morpholine with benzylidenemalononitrile in 50% dimethyl sulfoxide-50% water. Intrinsic barriers in nucleophilic additions
Claude F. Bernasconi, John P. Fox, and Simonetta Fornarini
pp 2810 - 2816; DOI:
10.1021/ja00528a049
PDF
Pyrazolo[4,3-d]pyrimidine nucleosides. 9. Studies on the isomeric N-methylformycins
Arthur F. Lewis and Leroy B. Townsend
pp 2817 - 2822; DOI:
10.1021/ja00528a050
PDF
Structure of the free-base "capped" porphyrin, 5,10,15,20-[pyrromellitoyl(tetrakis-o-oxyethoxyphenyl)]porphyrin
Geoffrey B. Jameson and James A. Ibers
pp 2823 - 2831; DOI:
10.1021/ja00528a051
PDF
Kinetics and mechanism of reduction of horse heart cytochrome c by hexaammineruthenium(II) ion. Reactivities of the electronic isomers of cytochrome c
Adeleye Adegite and M. I. Okpanachi
pp 2832 - 2836; DOI:
10.1021/ja00528a052
PDF
Reaction of singlet oxygen with .alpha.,.beta.-unsaturated ketones and lactones
Harry E. Ensley, Richard V. C. Carr, Robert S. Martin, and Tillman E. Pierce
pp 2836 - 2838; DOI:
10.1021/ja00528a053
PDF
Total synthesis of dl-tazettine
Samuel Danishefsky, Joel Morris, George Mullen, and Ronald Gammill
pp 2838 - 2840; DOI:
10.1021/ja00528a054
PDF
A 1,3-O- to -C-alkyl shift catalyzed by palladium
Barry M. Trost, Thomas A. Runge, and Louis N. Jungheim
pp 2840 - 2841; DOI:
10.1021/ja00528a055
PDF
A new diene synthesis via organopalladium chemistry
Barry M. Trost and Joseph M. Fortunak
pp 2841 - 2843; DOI:
10.1021/ja00528a056
PDF
Electron affinity of HO2 and HOx radicals
Sidney W. Benson and Prakash S. Nangia
pp 2843 - 2844; DOI:
10.1021/ja00528a057
PDF
Hemoprotein models: NMR of imidazole chelated protohemin cyanide complexes
Teddy G. Traylor and Albin P. Berzinis
pp 2844 - 2846; DOI:
10.1021/ja00528a058
PDF
Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms
C. D. Burkholder, W. E. Jones, J. S. Wasson, and M. T. H. Liu
pp 2847 - 2848; DOI:
10.1021/ja00528a059
PDF
Poly(dimethylphosphazene), (Me2PN)n
Patty Wisian-Neilson and Robert H. Neilson
pp 2848 - 2849; DOI:
10.1021/ja00528a060
PDF
Preparation, disproportionation, and reactions of two semi-met forms of hemerythrin
Lucia M. Babcock, Zdravko Bradic, Patricia C. Harrington, Ralph G. Wilkins, and Gerald S. Yoneda
pp 2849 - 2850; DOI:
10.1021/ja00528a061
PDF
1-Benzyl-1,4-dihydronicotinamide as a reagent for replacing aliphatic nitro groups by hydrogen: an electron-transfer chain reaction
Noboru Ono, Rui Tamura, and Aritsune Kaji
pp 2851 - 2852; DOI:
10.1021/ja00528a062
PDF
A major leaving group effect on chemical events after the group has left: reactions of acetone enolate ion with halobenzenes and related substrates provoked by solvated electrons
Raymond R. Bard, J. F. Bunnett, Xavier Creary, and Michael J. Tremelling
pp 2852 - 2854; DOI:
10.1021/ja00528a063
PDF
An electron diffraction study of 1,1-dimethylsilaethylene
Peter G. Mahaffy, Robb Gutowsky, and Lawrence K. Montgomery
pp 2854 - 2856; DOI:
10.1021/ja00528a064
PDF
Production of dixenon cation by reversible oxidation of xenon
Lawrence Stein and Wayne W. Henderson
pp 2856 - 2857; DOI:
10.1021/ja00528a065
PDF
Transition metal catalyzed reactions of alkynes and boron hydrides: synthesis of 2-(cis-2-butenyl)pentaborane(9) and its conversion into monocarbon carboranes
Robert Wilczynski and Larry G. Sneddon
pp 2857 - 2858; DOI:
10.1021/ja00528a066
PDF
Preparation of a "stabilized formyl" complex from carbon monoxide and hydrogen and the crystal structure of a derivative in which the carbon-oxygen bond has been cleaved
Patricia Belmonte, Richard R. Schrock, Melvyn Rowen Churchill, and Wiley J. Youngs
pp 2858 - 2860; DOI:
10.1021/ja00528a067
PDF
EPR detection of (CF3)3CI-. A test case regarding the stability of RX- radical anions
Jih Tzong Wang and Ffrancon Williams
pp 2860 - 2861; DOI:
10.1021/ja00528a068
PDF
Organo-sulfur mechanisms. 11. [1,3]-Sigmatropic shifts for 5-X-bicyclo[2.1.0]pent-2-enes. An evaluation of the pseudopericyclic model
James P. Snyder and Thomas A. Halgren
pp 2861 - 2863; DOI:
10.1021/ja00528a069
PDF
Decarboxylation reactions: reactivity of a free carboxylate anion in ethereal solvents
Masamitsu Shirai and Johannes Smid
pp 2863 - 2865; DOI:
10.1021/ja00528a070
PDF
The remarkable catalytic power of glymes in ester aminolysis carried out in nonpolar media
John Charles Hogan and Richard David Gandour
pp 2865 - 2866; DOI:
10.1021/ja00528a071
PDF
Photochemical transformations. 27. Acid-catalyzed photosolvolytic reactions and rearrangements. Evidence for heterolytic photochemical bond cleavage
Stanley J. Cristol and Rory D. Daussin
pp 2866 - 2867; DOI:
10.1021/ja00528a072
PDF
Book Reviews

pp 2868 - 2868; DOI:
10.1021/ja00528a600
PDF

Issue 9


Influence of substituents on NMR and barriers to rotation in tert-benzyllithium compounds
Gideon Fraenkel and J. Michael Geckle
pp 2869 - 2880; DOI:
10.1021/ja00529a001
PDF
The pH dependence of nitrogen-15 NMR shifts and coupling constants in aqueous imidazole and 1-methylimidazole. Comments on estimation of tautomeric equilibrium constants for aqueous histidine
M. Alei, L. O. Morgan, W. E. Wageman, and T. W. Whaley
pp 2881 - 2887; DOI:
10.1021/ja00529a002
PDF
Electronic spectra and structure of a weak .pi. complex. Vibronic structure in the charge-transfer transition of anthracene-s-trinitrobenzene
C. J. Eckhardt and H. Eckhardt
pp 2887 - 2892; DOI:
10.1021/ja00529a003
PDF
Infrared spectra of hydrogen-bonded .pi. complexes between hydrogen halides and acetylene
Stephen A. McDonald, Gary L. Johnson, Brian W. Keelan, and Lester Andrews
pp 2892 - 2896; DOI:
10.1021/ja00529a004
PDF
Kinetics of hydrogen abstraction by amino radicals from alkanes in the gas phase. A flash photolysis-laser resonance absorption study
M. Demissy and R. Lesclaux
pp 2897 - 2902; DOI:
10.1021/ja00529a005
PDF
Electrolytes. From dilute solutions to fused salts
Kenneth S. Pitzer
pp 2902 - 2906; DOI:
10.1021/ja00529a006
PDF
Rates of proton transfer between pyridine bases in the gas phase. Steric and isotope effects
Joseph M. Jasinski and John I. Brauman
pp 2906 - 2913; DOI:
10.1021/ja00529a007
PDF
Proton exchange between nucleic acid bases in nonaqueous solvents
Hideo Iwahashi and Yoshimasa Kyogoku
pp 2913 - 2917; DOI:
10.1021/ja00529a008
PDF
Spin conversion processes in solutions
E. Buhks, G. Navon, M. Bixon, and J. Jortner
pp 2918 - 2923; DOI:
10.1021/ja00529a009
PDF
Chiral discrimination in excimer formation
Chieu D. Tran and Janos H. Fendler
pp 2923 - 2928; DOI:
10.1021/ja00529a010
PDF
Unified view of Marcus electron transfer and Mulliken charge transfer theories in organometallic chemistry. Steric effects in alkylmetals as quantitative probes for outer-sphere and inner-sphere mechanisms
S. Fukuzumi, C. L. Wong, and J. K. Kochi
pp 2928 - 2939; DOI:
10.1021/ja00529a011
PDF
Isomers of closo-dicarbapentaborane(5) and their methyl and fluoro derivatives. A theoretical study
Glenn D. Graham, Dennis S. Marynick, and William N. Lipscomb
pp 2939 - 2945; DOI:
10.1021/ja00529a012
PDF
Electronegativities of the elements from simple .CHI..alpha. theory
Libero J. Bartolotti, Shridhar R. Gadre, and Robert G. Parr
pp 2945 - 2948; DOI:
10.1021/ja00529a013
PDF
Theoretical study of halobenzenium ions
Robert C. Binning and Kenneth M. Sando
pp 2948 - 2952; DOI:
10.1021/ja00529a014
PDF
Metallacyclopentanes and bisolefin complexes
Armel Stockis and Roald Hoffmann
pp 2952 - 2962; DOI:
10.1021/ja00529a015
PDF
Electronic and vibrational spectral investigation of the molecular association of the all-trans isomers of retinal, retinol, and retinoic acid
Kohji Chihara and Walter H. Waddell
pp 2963 - 2968; DOI:
10.1021/ja00529a016
PDF
Regiospecific coordination of ambidentate tetrazoles to cobalt oximes
Nicholas E. Takach, Elizabeth M. Holt, Nathaniel W. Alcock, Ronald A. Henry, and John H. Nelson
pp 2968 - 2979; DOI:
10.1021/ja00529a017
PDF
Transition metal arene chemistry. 4. Structural studies of cobalt group complexes
Michael R. Thompson, Cynthia Secaur Day, Victor W. Day, Robert I. Mink, and E. L. Muetterties
pp 2979 - 2986; DOI:
10.1021/ja00529a018
PDF
Crystal structure and properties of tetrathiafulvalenium triiodide
Robert C. Teitelbaum, Tobin J. Marks, and Carroll K. Johnson
pp 2986 - 2989; DOI:
10.1021/ja00529a019
PDF
Nitrogen-14 nuclear quadrupole resonance spectra of the coordinated amino group and of coordinated imidazole. Crystal and molecular structures of chloroglycylglycinato(imidazole)cadmium
Carol I. H. Ashby, William F. Paton, and Theodore I. Brown
pp 2990 - 2998; DOI:
10.1021/ja00529a020
PDF
Ternary complexes in solution. 35. Intramolecular hydrophobic ligand-ligand interactions in mixed ligand complexes containing an aliphatic amino acid
Beda E. Fischer and Helmut Sigel
pp 2998 - 3008; DOI:
10.1021/ja00529a021
PDF
Molecular structure of (.eta.5-C5H5)2Ti(OC2H5)Cl and [(.eta.5-C5H5)Cl2Ti]2O2C2(CH3)4. A structural basis for deoxygenation using titanium
John C. Huffman, Kenneth G. Moloy, John A. Marsella, and Kenneth G. Caulton
pp 3009 - 3014; DOI:
10.1021/ja00529a022
PDF
Preparation and structural characterization of polypeptide complexes of dimolybdenum(II). 1. A tetrakis(glycylglycine) complex
Avi Bino and F. Albert Cotton
pp 3014 - 3017; DOI:
10.1021/ja00529a023
PDF
Preparation and characterization of the anionic complex potassium dicyano(meso-tetraphenylporphinato)iron(III) bis(acetone)
W. Robert Scheidt, Kenneth J. Haller, and Keiichiro Hatano
pp 3017 - 3021; DOI:
10.1021/ja00529a024
PDF
Studies of the photoreactions of dodecacarbonyltriosmium with chlorocarbons and with triphenylphosphine in solution
David R. Tyler, Mark Altobelli, and Harry B. Gray
pp 3022 - 3024; DOI:
10.1021/ja00529a025
PDF
Eleven-vertex rhodium, iridium, and ruthenium phosphinometallocarborane complexes formed from sodium undecahydro-5,6-dicarba-nido-decaborate(1-)
C. W. Jung and M. F. Hawthorne
pp 3024 - 3032; DOI:
10.1021/ja00529a026
PDF
Influence of steric and electronic effects on the binding of arenediazonium cations to 18-crown-6 in methanol at 25.degree.C
R. M. Izatt, J. D. Lamb, C. S. Swain, J. J. Christensen, and Barry L. Haymore
pp 3032 - 3034; DOI:
10.1021/ja00529a027
PDF
Reduction of .alpha.-keto acids by low-valent metal ions. 2. Reaction of aqueous vanadous ion with pyruvic and phenylglyoxylic acids
J. Konstantatos, E. Vrachnou-Astra, N. Katsaros, and D. Katakis
pp 3035 - 3040; DOI:
10.1021/ja00529a028
PDF
The mechanism of asymmetric homogeneous hydrogenation. Rhodium(I) complexes of dehydroamino acids containing asymmetric ligands related to bis(1,2-diphenylphosphino)ethane
John M. Brown and Penny A. Chaloner
pp 3040 - 3048; DOI:
10.1021/ja00529a029
PDF
Tautomerism of orotic acid dianion. Effect of calcium and magnesium cations on the tautomeric constant and on tautomerization dynamics
Guy Dodin and Jacques Emile Dubois
pp 3049 - 3056; DOI:
10.1021/ja00529a030
PDF
Dependence of aryl ether acylation upon Lewis acid stoichiometry
Thomas F. Buckley and Henry Rapoport
pp 3056 - 3062; DOI:
10.1021/ja00529a031
PDF
General-acid-catalyzed imidazolidine ring opening. Hydrolysis of symmetrical and unsymmetrical 1,3-imidazolidines of p-dimethylaminocinnamaldehyde
Thomas H. Fife and August M. Pellino
pp 3062 - 3071; DOI:
10.1021/ja00529a032
PDF
Mechanism of cleavage of carbamate anions
Sheila P. Ewing, Daniel Lockshon, and William P. Jencks
pp 3072 - 3084; DOI:
10.1021/ja00529a033
PDF
Kinetics and mechanism of the thiolytic removal of the dithiasuccinoyl (Dts) amino protecting group
George Barany and R. B. Merrifield
pp 3084 - 3095; DOI:
10.1021/ja00529a034
PDF
.alpha.-Ketoketene dithioacetal chemistry. 1. Alternate modes of lithium aluminum hydride reduction. Regio- and stereospecific vs. reduction-alkylation-fragmentation
Ronald B. Gammill, Paul M. Gold, and Stephen A. Mizsak
pp 3095 - 3100; DOI:
10.1021/ja00529a035
PDF
Electron transfer induced isomerization of cis-4,4'-diphenylstilbene into its trans form
C. K. Chien, H. C. Wang, M. Szwarc, A. J. Bard, and K. Itaya
pp 3100 - 3104; DOI:
10.1021/ja00529a036
PDF
Thermochemistry and kinetics of ozonation reactions
Prakash S. Nangia and Sidney W. Benson
pp 3105 - 3115; DOI:
10.1021/ja00529a037
PDF
Gas-phase acid-induced nucleophilic displacement reactions. Stereochemistry of inter- and intramolecular substitutions at saturated carbon
Maurizio Speranza and Giancarlo Angelini
pp 3115 - 3120; DOI:
10.1021/ja00529a038
PDF
Gas-phase acylation reactions. Substrate and positional selectivity of free acetylium ions toward methylbenzenes
Maurizio Speranza and Cinzia Sparapani
pp 3120 - 3124; DOI:
10.1021/ja00529a039
PDF
Electron photodetachment from mercaptyl anions (RS-). Electron affinities of mercaptyl radicals and the sulfur-hydrogen bond strength in mercaptans
Bruce K. Janousek, Kenneth J. Reed, and John I. Brauman
pp 3125 - 3129; DOI:
10.1021/ja00529a040
PDF
Theory of photophysical properties of symmetric chlorophyll hydrated dimers
Karl F. Freed
pp 3130 - 3135; DOI:
10.1021/ja00529a041
PDF
Phosphorus-31 and carbon-13 NMR spectra of 2-norbornyl phosphorus compounds. Karplus equations for 3JPC in several phosphorus(III) and phosphorus(IV) derivatives
Louis D. Quin, Michael J. Gallagher, Glen T. Cunkle, and Donald B. Chesnut
pp 3136 - 3143; DOI:
10.1021/ja00529a042
PDF
Conformational states of myo-inositol hexakis(phosphate) in aqueous solution. A carbon-13 NMR, phosphorus-31 NMR, and Raman spectroscopic investigation
Lester R. Isbrandt and Richard P. Oertel
pp 3144 - 3148; DOI:
10.1021/ja00529a043
PDF
Template synthesis of macromolecules. Synthesis and chemistry of functionalized macroporous poly(divinylbenzene)
Kenneth J. Shea, Evan A. Thompson, Sue D. Pandey, and Philip S. Beauchamp
pp 3149 - 3155; DOI:
10.1021/ja00529a044
PDF
Diastereomeric transition states. Relative energies of the chair and boat reaction pathways in the Cope rearrangement
Kenneth J. Shea and Richard B. Phillips
pp 3156 - 3162; DOI:
10.1021/ja00529a045
PDF
Diels-Alder reactivity of polycyclic aromatic hydrocarbons. 1. Acenes and benzologs
D. Biermann and W. Schmidt
pp 3163 - 3173; DOI:
10.1021/ja00529a046
PDF
Diels-Alder reactivity of polycyclic aromatic hydrocarbons. 2. Phenes and starphenes
D. Biermann and W. Schmidt
pp 3173 - 3181; DOI:
10.1021/ja00529a047
PDF
Short-lived intermediates. 8. Excited states, regioselectivity, and stereospecificity in the photochemistry of (R,S:S,R)- and (R,R:S,S)-1,2-dimethylbutyl trifluoroacetate
James E. Gano and David Hou-Tar Chien
pp 3182 - 3188; DOI:
10.1021/ja00529a048
PDF
Photochemical and photophysical studies of organized assemblies. Interaction of oils, long-chain alcohols, and surfactants forming microemulsions
Mats Almgren, Franz Grieser, and J. K. Thomas
pp 3188 - 3193; DOI:
10.1021/ja00529a049
PDF
Photochemistry of .alpha.'-substituted .beta.,.gamma.-cyclopropyl cyclic ketones. Influence of geometric constraints and substituent effects on competitive Norrish type I photoreactions
Roger K. Murray and Thomas M. Ford
pp 3194 - 3198; DOI:
10.1021/ja00529a050
PDF
Chemi- and bioluminescence of firefly luciferin
Emil H. White, Mark G. Steinmetz, Jeffrey D. Miano, Peter D. Wildes, and Robert Morland
pp 3199 - 3208; DOI:
10.1021/ja00529a051
PDF
Conformational studies on humulene by means of empirical force field calculations. Role of stable conformers of humulene in biosynthetic and chemical reactions
Haruhisa Shirahama, Eiji Osawa, and Takeshi Matsumoto
pp 3208 - 3213; DOI:
10.1021/ja00529a052
PDF
A novel "induced-fit" phenomenon. Evidence for conformational changes closely associated with efficient hydrolysis of acyl trypsin
Hitoshi Nakayama, Kazutaka Tanizawa, and Yuichi Kanaoka
pp 3214 - 3218; DOI:
10.1021/ja00529a053
PDF
Cytochrome aa3 electron-transfer reactions. Kinetics of hexaammineruthenium(II) reduction of the beef heart enzyme
Robert A. Scott and Harry B. Gray
pp 3219 - 3224; DOI:
10.1021/ja00529a054
PDF
Models for the active site of oxygen-binding hemoproteins. Dioxygen binding properties and the structures of (2-methylimidazole)-meso-tetra(.alpha.,.alpha.,.alpha.,.alpha.-o-pivalamidophenyl)porphyrinatoiron(II)-ethanol and its dioxygen adduct
Geoffrey B. Jameson, Frank S. Molinaro, James A. Ibers, James P. Collman, John I. Brauman, Eric Rose, and Kenneth S. Suslick
pp 3224 - 3237; DOI:
10.1021/ja00529a055
PDF
Resonance Raman spectroscopy in the picosecond time scale: the carboxyhemoglobin photointermediate
J. Terner, T. G. Spiro, M. Nagumo, M. F. Nicol, and M. A. El-Sayed
pp 3238 - 3239; DOI:
10.1021/ja00529a056
PDF
Can cyclopropyne really be made?
Paul Saxe and Henry F. Schaefer
pp 3239 - 3240; DOI:
10.1021/ja00529a057
PDF
1-Azaallyllithium reagents (metalated Schiff bases). Configurational equilibration and stereospecific nitrogen protonation to metastable sec-enamines
Rudolf Knorr and Peter Loew
pp 3241 - 3242; DOI:
10.1021/ja00529a058
PDF
Synthesis and characterization of new iron-palladium and iron-platinum carbonyl anionic clusters
Giuliano Longoni, Mario Manassero, and Mirella Sansoni
pp 3242 - 3244; DOI:
10.1021/ja00529a059
PDF
Models for nicotinamide coenzymes. Isotope effect discrepancies in the reaction of dihydronicotinamides with trifluoroacetophenone are due to adduct formation
David M. Chipman, Ruth Yaniv, and Paul Van Eikeren
pp 3244 - 3246; DOI:
10.1021/ja00529a060
PDF
New membrane carrier for selective transport of metal ions
Kazuhiro Maruyama, Hiroshi Tsukube, and Takeo Araki
pp 3246 - 3247; DOI:
10.1021/ja00529a061
PDF
Trialkylsilyl triflates. 5. A stereoselective aldol-type condensation of enol silyl ethers and acetals catalyzed by trimethylsilyl trifluoromethanesulfonate
S. Murata, M. Suzuki, and R. Noyori
pp 3248 - 3249; DOI:
10.1021/ja00529a062
PDF
Carbon-13 NMR spectra of cellulose polymorphs
R. H. Atalla, J. C. Gast, D. W. Sindorf, V. J. Bartuska, and G. E. Maciel
pp 3249 - 3251; DOI:
10.1021/ja00529a063
PDF
High resolution, magic angle sampling spinning carbon-13 NMR of solid cellulose I
William L. Earl and D. L. VanderHart
pp 3251 - 3252; DOI:
10.1021/ja00529a064
PDF
Detection of "tension" and electronic asymmetry in imidazole-appended iron porphyrins by NMR spectroscopy
Harold Goff
pp 3252 - 3254; DOI:
10.1021/ja00529a065
PDF
Models of the cytochromes b. 1. Effect of substituents, axial ligand plane orientation, and possible axial ligand bond strain on the pyrrole proton shifts of a series of low-spin monosubstituted tetraphenylporphinatoiron(III)-bisimidazole complexes
F. Ann Walker
pp 3254 - 3256; DOI:
10.1021/ja00529a066
PDF
Tricyclo[6.1.1.03,9]deca-2,8(10)-diene, the Dewar isomer of [4]metacyclophane
L. A. M. Turkenburg, J. W. Van Straten, W. H. De Wolf, and F. Bickelhaupt
pp 3256 - 3257; DOI:
10.1021/ja00529a067
PDF
Aromatic protonation. 5. Diprotonated 1,6-methano[10]annulene. NMR evidence for a cyclopropyldicarbinyl dication moiety
Koop Lammertsma and Hans Cerfontain
pp 3257 - 3259; DOI:
10.1021/ja00529a068
PDF
Lack of tunneling in the excited-state double proton transfer of 7-azaindole dimer?
Hanna Bulska and Alina Chodkowska
pp 3259 - 3261; DOI:
10.1021/ja00529a069
PDF
Photochemical preparation of a [3.1]metacyclophane and [3.2]metaparacyclophane through internal charge-transfer sensitization
Cheng-I Lin, Prithipal Singh, Michael Maddox, and Edwin F. Ullman
pp 3261 - 3262; DOI:
10.1021/ja00529a070
PDF
The structure of amidyl radicals. An investigation by variable-temperature electron paramagnetic resonance spectroscopy
Jean Lessard, D. Griller, and K. U. Ingold
pp 3262 - 3264; DOI:
10.1021/ja00529a071
PDF
Nitrogen-centered free radicals. 10. Electron spin resonance evidence for a .pi. ground electronic configuration for sulfonamidyl radicals
Wayne C. Danen and Roland W. Gellert
pp 3264 - 3265; DOI:
10.1021/ja00529a072
PDF
Stereoselective syntheses via a photochemical template effect
Julien Damen and D. C. Neckers
pp 3265 - 3267; DOI:
10.1021/ja00529a073
PDF
Organofluorosilicates in organic synthesis. 9. Stereochemistry at carbon in cleavage of the carbon-silicon bond in exo- and endo-2-norbornylpentafluorosilicates by various brominating agents
Kohei Tamao, Junichi Yoshida, Masao Murata, and Makoto Kumada
pp 3267 - 3269; DOI:
10.1021/ja00529a074
PDF
Organofluorosilicates in organic synthesis. 10. Alkylation of tetracyanoethylene with organopentafluorosilicates: implication of one-electron-transfer mechanism
Junichi Yoshida, Kohei Tamao, Makoto Kumada, and Takashi Kawamura
pp 3269 - 3270; DOI:
10.1021/ja00529a075
PDF
Titanium-mediated methylene-transfer reactions. Direct conversion of esters into vinyl ethers
S. H. Pine, R. Zahler, D. A. Evans, and R. H. Grubbs
pp 3270 - 3272; DOI:
10.1021/ja00529a076
PDF
Can chemical reactivity patterns on chemically modified electrode surfaces be anticipated from solution reactivity? A study of ruthenium nitro complexes
Hector D. Abruna, J. L. Walsh, T. J. Meyer, and Royce W. Murray
pp 3272 - 3274; DOI:
10.1021/ja00529a077
PDF
Heteropoly periodates: structure of [Co43+I37+O24H12]3- ion and principles pertinent to a separate potentially important category of heteropoly complexes
Louis C. W. Baker, Lukasz Lebioda, Jacek Grochowski, and H. G. Mukherjee
pp 3274 - 3276; DOI:
10.1021/ja00529a078
PDF
Bi- and polynuclear antiferromagnetic metal complexes (copper,nickel) with salicylaldimines and acetate-type ligands. New modes of acetate bridging
Ray J. Butcher, John W. Overman, and Ekk Sinn
pp 3276 - 3278; DOI:
10.1021/ja00529a079
PDF
One-electron oxidation of benzyltrialkylstannanes. 1. Cation radical fragmentation by dual modes
David F. Eaton
pp 3278 - 3280; DOI:
10.1021/ja00529a080
PDF
One-electron oxidation of benzyltrialkylstannanes. 2. Excited-state quenching of 9,10-dicyanoanthracene
David F. Eaton
pp 3280 - 3281; DOI:
10.1021/ja00529a081
PDF
Double-bond participation in cyclopent-3-enyl tosylate
Joseph B. Lambert, Rodney B. Finzel, and Catherine A. Belec
pp 3281 - 3283; DOI:
10.1021/ja00529a082
PDF
Synthesis and structure of totally synthetic coboglobin models
James C. Stevens, Patricia J. Jackson, Wayne P. Schammel, Gary G. Christoph, and Daryle H. Busch
pp 3283 - 3285; DOI:
10.1021/ja00529a083
PDF
Totally synthetic coboglobin models with oxygen binding capabilities equivalent to those of coboglobin
James C. Stevens and Daryle H. Busch
pp 3285 - 3287; DOI:
10.1021/ja00529a084
PDF
Synthesis and absolute configuration of optically active trans-1,2-disubstituted cycloalkenes
James A. Marshall, Tim R. Konicek, and Katherine E. Flynn
pp 3287 - 3288; DOI:
10.1021/ja00529a085
PDF
Carbon-13 chemical shifts of alkyne ligands as variable electron donors in monomeric molybdenum and tungsten complexes
Joseph L. Templeton and Bennett C. Ward
pp 3288 - 3290; DOI:
10.1021/ja00529a086
PDF
The .mu.-hydrobis[tetracarbonyl(methyldiphenylphosphine)molybdenum](2-) anion: an example of phosphine enhancement of metal-metal interaction
Marcetta Y. Darensbourg, J. L. Atwood, W. E. Hunter, and R. R. Burch
pp 3290 - 3292; DOI:
10.1021/ja00529a087
PDF
Intermolecular reduction of coordinated ligands by transition organometallic hydride reagents
T. Bodnar, S. J. LaCroce, and A. R. Cutler
pp 3292 - 3294; DOI:
10.1021/ja00529a088
PDF
General methods for alkaloid synthesis via intramolecular [4 + 2] cycloaddition reactions of enamides. A new approach to the synthesis of Aspidosperma alkaloids
Stephen F. Martin, Sunil R. Desai, Gerald W. Philips, and Anna C. Miller
pp 3294 - 3296; DOI:
10.1021/ja00529a089
PDF
Direct calculation of equilibrium constants for isotopic exchange reactions by ab initio molecular orbital theory
Robert F. Hout, Max Wolfsberg, and Warren J. Hehre
pp 3296 - 3298; DOI:
10.1021/ja00529a090
PDF
Palladium-catalyzed cross-coupling reaction of homoallylic or homopropargylic organozincs with alkenyl halides as a new selective route to 1,5-dienes and 1,5-enynes
Eiichi Negishi, Louis F. Valente, and Makoto Kobayashi
pp 3298 - 3299; DOI:
10.1021/ja00529a091
PDF
Unprecedented regiospecificity and stereospecificity in reactions of Ph3C+PF6- with rhenium alkyls of the formula (.eta.-C5H5)Re(NO)(PPh3)(CH2R)
William A. Kiel, Gong-Yu Lin, and J. A. Gladysz
pp 3299 - 3301; DOI:
10.1021/ja00529a092
PDF
Metal atom to cluster to bulk transformations. Electron spin resonance studies of silver atoms in rare gas matrices at 12 K. Quantum size effect
Geoffrey A. Ozin
pp 3301 - 3303; DOI:
10.1021/ja00529a093
PDF
syn,endo-Tetracyclo[6.2.1.13,6.02,7]dodec-2-ylium cations. Kinetic and chemical consequences of fusing norbornyl segments across common C2,C3 segments
Leo A. Paquette, Katsuo Ohkata, and Richard V. C. Carr
pp 3303 - 3305; DOI:
10.1021/ja00529a094
PDF
Book Reviews

pp 3305 - 3308; DOI:
10.1021/ja00529a600
PDF

Issue 10


Structure and properties of liquid ammonia
William L. Jorgensen and Mustafa Ibrahim
pp 3309 - 3315; DOI:
10.1021/ja00530a001
PDF
Structures and isotopic fractionation factors of complexes, A1HA2-
Maurice M. Kreevoy and Tai Ming Liang
pp 3315 - 3322; DOI:
10.1021/ja00530a002
PDF
A resonance Raman/iodine Moessbauer investigation of the starch-iodine structure. Aqueous solution and iodine vapor preparations
Robert C. Teitelbaum, Stanley L. Ruby, and Tobin J. Marks
pp 3322 - 3328; DOI:
10.1021/ja00530a003
PDF
Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entree to heats of solvation of aliphatic carbonium ions
Edward M. Arnett and Norbert J. Pienta
pp 3329 - 3334; DOI:
10.1021/ja00530a004
PDF
Heats of formation of gaseous free radicals via ion cyclotron double resonance spectroscopy
Douglas J. DeFrees, Robert T. McIver, and Warren J. Hehre
pp 3334 - 3338; DOI:
10.1021/ja00530a005
PDF
Study of complexation of polydentate amido ethers with lithium ions by nuclear magnetic resonance spectroscopy. 1. Solvent effects
Uriel Olsher, Gabriel A. Elgavish, and Joseph Jagur-Grodzinski
pp 3338 - 3345; DOI:
10.1021/ja00530a006
PDF
Dynamic behavior and aggregation of propyllithium from carbon-13 and lithium-6 NMR at high field
Gideon Fraenkel, Mark Henrichs, James M. Hewitt, Biing Ming Su, and Michael J. Geckle
pp 3345 - 3350; DOI:
10.1021/ja00530a007
PDF
Phosphorus-31 nuclear magnetic resonance studies of polymer-anchored rhodium(I) complexes
Aart J. Naaktgeboren, Roeland J. M. Nolte, and Wiendelt Drenth
pp 3350 - 3354; DOI:
10.1021/ja00530a008
PDF
Nuclear spin-spin coupling via nonbonded interactions. 3. Importance of bridgehead interactions on vicinal carbon-13-proton and carbon-13-carbon-13 coupling constants in bicycloalkanes
M. Barfield, S. E. Brown, E. D. Canada, N. D. Ledford, J. L. Marshall, S. R. Walter, and E. Yakali
pp 3355 - 3359; DOI:
10.1021/ja00530a009
PDF
Collisional activation and metastable ion characteristics. 73. High-resolution tandem mass spectrometer (MS/MS) of increased sensitivity and mass range
Fred W. McLafferty, Peter J. Todd, Donald C. McGilvery, and Michael A. Baldwin
pp 3360 - 3363; DOI:
10.1021/ja00530a010
PDF
Secondary hydrogen isotope effect in the unimolecular decomposition of 2-methylpropane radical cations
Phillip T. Mead, Kevin F. Donchi, John C. Traeger, John R. Christie, and Peter J. Derrick
pp 3364 - 3369; DOI:
10.1021/ja00530a011
PDF
A theoretical approach to the Birch reduction. Structures and stabilities of the radical anions of substituted benzenes
Arthur J. Birch, Alan L. Hinde, and Leo Radom
pp 3370 - 3376; DOI:
10.1021/ja00530a012
PDF
Are bonds bent? To what extent do bond orbitals follow nuclear motions?
Daniel M. Chipman, William E. Palke, and Bernard Kirtman
pp 3377 - 3383; DOI:
10.1021/ja00530a013
PDF
A poly-p-nitrostyrene on platinum electrode. Polymer charging kinetics and electrocatalysis of organic dihalide reductions
John B. Kerr, Larry L. Miller, and Michael R. Van de Mark
pp 3383 - 3390; DOI:
10.1021/ja00530a014
PDF
Use of chemically derivatized n-type silicon photoelectrodes in aqueous media. Photooxidation of iodide, hexacyanoiron(II), and hexaammineruthenium(II) at ferrocene-derivatized photoanodes
Andrew B. Bocarsly, Erick G. Walton, and Mark S. Wrighton
pp 3390 - 3398; DOI:
10.1021/ja00530a015
PDF
Effects of salt concentration and anion on the rate of carrier-facilitated transport of metal cations through bulk liquid membranes containing crown ethers
J. D. Lamb, J. J. Christensen, S. R. Izatt, K. Bedke, M. S. Astin, and R. M. Izatt
pp 3399 - 3403; DOI:
10.1021/ja00530a016
PDF
Europium ion coordination with .gamma.-carboxyglutamic acid containing ligand systems
Martha M. Sarasua, Mary E. Scott, Joseph A. Helpern, Paul B. W. Ten Kortenaar, Norman T. Boggs, Lee G. Pedersen, Karl A. Koehler, and Richard G. Hiskey
pp 3404 - 3412; DOI:
10.1021/ja00530a017
PDF
Interaction of lanthanide(III) ions with bovine prothrombin fragment. 1. A luminescence and nuclear magnetic resonance study
Mary E. Scott, Martha M. Sarasua, Henry C. Marsh, David L. Harris, Richard G. Hiskey, and Karl A. Koehler
pp 3413 - 3419; DOI:
10.1021/ja00530a018
PDF
Paramagnetic carbon monoxide on magnesium oxide
R. M. Morris, R. A. Kaba, T. G. Groshens, K. J. Klabunde, R. J. Baltisberger, N. F. Woolsey, and V. I. Stenberg
pp 3419 - 3424; DOI:
10.1021/ja00530a019
PDF
Photoinsertion of alkynes into a ferraborane. Preparation and characterization of a novel tetracarbon carborane
Thomas P. Fehlner
pp 3424 - 3430; DOI:
10.1021/ja00530a020
PDF
Electron-diffraction investigations of the molecular structures of cis- and trans-1,2-dimethyldiborane
Lise Hedberg, Kenneth Hedberg, David A. Kohler, David M. Ritter, and Verner Schomaker
pp 3430 - 3434; DOI:
10.1021/ja00530a021
PDF
Conductive molecular crystals. Structural, electrical, and magnetic properties of partially oxidized octamethyltetrabenzporphyrinatonickel(II)
Terry E. Phillips, Raymond P. Scaringe, Brian M. Hoffman, and James A. Ibers
pp 3435 - 3444; DOI:
10.1021/ja00530a022
PDF
Formation, crystal structure, and reactions of catena-(.mu.-SPh)[(.mu.-SPh)6Zn4(CH3OH)(SPh)], a model for zinc thiolate metalloenzymes
Ian G. Dance
pp 3445 - 3451; DOI:
10.1021/ja00530a023
PDF
Synthesis, characterization, and crystal structures of [(Ph3P)2N]+3{Na[Mo3(CO)6(NO)3(.mu.2-OCH3)3(.mu.3-O)]2}3-, an unusual organometallic triple ion, and [Me4N]+[Mo3(CO)6(NO)3(.mu.2-OCH3)3(.mu.3-OCH3)]-
Stephen W. Kirtley, Jeffrey P. Chanton, Richard A. Love, Donald L. Tipton, Thomas N. Sorrell, and Robert Bau
pp 3451 - 3460; DOI:
10.1021/ja00530a024
PDF
Crystal structure of bis(9-methylhypoxanthine)silver(I) perchlorate monohydrate, a model complex for the silver-poly(I) system
Francine Belanger-Gariepy and Andre L. Beauchamp
pp 3461 - 3464; DOI:
10.1021/ja00530a025
PDF
Sensitivity of the chromium-chromium quadrupole bond to axial interactions in dichromium(II) compounds
F. Albert Cotton, William H. Ilsley, and Wolfgang Kaim
pp 3464 - 3474; DOI:
10.1021/ja00530a026
PDF
Lewis basicity of a chlorine atom bound to an aliphatic carbon atom as sensed by a quadruple chromium-chromium bond. Structures of M2[(2,6-xylyl)NC(CH3)O]4.2CH2Cl2, M = chromium, molybdenum
F. Albert Cotton, William H. Ilsley, and Wolfgang Kaim
pp 3475 - 3479; DOI:
10.1021/ja00530a027
PDF
Infrared matrix isolation study of magnesium metal atom reactions. Spectra of an unsolvated Grignard species
Bruce S. Ault
pp 3480 - 3484; DOI:
10.1021/ja00530a028
PDF
Kinetics and mechanisms of substitution reactions on decacarbonylmanganeserhenium
Dave Sonnenberger and Jim D. Atwood
pp 3484 - 3489; DOI:
10.1021/ja00530a029
PDF
The mechanism of hydrogen migration in cyclohexadienylmanganese tricarbonyl
W. Lamanna and M. Brookhart
pp 3490 - 3494; DOI:
10.1021/ja00530a030
PDF
Electrophilic reaction of the hydroxyl radical with phenol. Determination of the distribution of isomeric dihydroxycyclohexadienyl radicals
N. V. Raghavan and S. Steenken
pp 3495 - 3499; DOI:
10.1021/ja00530a031
PDF
Proton-transfer and electron-transfer processes in reaction of p-nitrotoluene with bases. A spectrophotometric study
E. Buncel and B. C. Menon
pp 3499 - 3507; DOI:
10.1021/ja00530a032
PDF
Aromatic substitution. 45. Transfer nitration of aromatics with N-nitropyridinium and quinolinium ions
George A. Olah, Subhash C. Narang, Judith A. Olah, Ronald L. Pearson, and Chris A. Cupas
pp 3507 - 3510; DOI:
10.1021/ja00530a033
PDF
Substrate selectivity and orientation in aromatic Substitution by molecular fluorine
F. Cacace, P. Giacomello, and A. P. Wolf
pp 3511 - 3515; DOI:
10.1021/ja00530a034
PDF
Chemiluminescence in the reaction of a sulfurane with alkyl hydroperoxides
Paul D. Bartlett, Tetsuo Aida, Hsien-Kun Chu, and Tai-Shan Fang
pp 3515 - 3524; DOI:
10.1021/ja00530a035
PDF
Conformational effects in the fluorescence and photochemistry of [2.n](9,10)anthracenophanes (n = 4, 5)
Albert Dunand, James Ferguson, Miroslav Puza, and Glen B. Robertson
pp 3524 - 3530; DOI:
10.1021/ja00530a036
PDF
Carbanion photochemistry. 2. Kinetic control of product formation in reactions of radicals with carbanions
Laren M. Tolbert
pp 3531 - 3534; DOI:
10.1021/ja00530a037
PDF
Chemistry of enol silyl ethers. 5. A novel cycloaromatization reaction. Regiocontrolled synthesis of substituted methyl salicylates
Tak-Hang Chan and Peter Brownbridge
pp 3534 - 3538; DOI:
10.1021/ja00530a038
PDF
The bicycle rearrangement. 5. Relationship to the di-.pi.-methane rearrangement and control by bifunnel distortion. Mechanistic and exploratory organic photochemistry
Howard E. Zimmerman and Ronda E. Factor
pp 3538 - 3548; DOI:
10.1021/ja00530a039
PDF
Sulfur as a regiochemical control element. Synthesis of 2-alkoxy(acyloxy)-3-alkyl(aryl)thiobuta-1,3-dienes
Barry M. Trost, William C. Vladuchick, and Alex J. Bridges
pp 3548 - 3554; DOI:
10.1021/ja00530a040
PDF
Sulfur as a regiochemical control element. Cycloadditions of 2-alkoxy(acyloxy)-3-alkyl(aryl)thiobuta-1,3-dienes
Barry M. Trost, William C. Vladuchick, and Alex J. Bridges
pp 3554 - 3572; DOI:
10.1021/ja00530a041
PDF
Reaction of olefins with palladium trifluoroacetate
Barry M. Trost and Patrick J. Metzner
pp 3572 - 3577; DOI:
10.1021/ja00530a042
PDF
Metalation of 1,3-dithiolanes. Mercaptan synthesis and carbonyl transposition
Stephen R. Wilson, Gregory M. Georgiadis, Hiralal N. Khatri, and John E. Bartmess
pp 3577 - 3583; DOI:
10.1021/ja00530a043
PDF
Palladium-assisted cyclization-insertion reactions. Synthesis of functionalized heterocycles
Louis S. Hegedus, G. F. Allen, and D. J. Olsen
pp 3583 - 3587; DOI:
10.1021/ja00530a044
PDF
Ring-chain tautomerism in 1,3-diaza and 1,3-oxaza heterocycles
Joseph B. Lambert and Michal W. Majchrzak
pp 3588 - 3591; DOI:
10.1021/ja00530a045
PDF
The timing of the proton-transfer process in carbonyl additions and related reactions. General-acid-catalyzed hydrolysis of imines and N-acylimines of benzophenone
J. M. Sayer and Patrick Conlon
pp 3592 - 3600; DOI:
10.1021/ja00530a046
PDF
Enantiomeric enrichment in the hydrolysis of oxazolones catalyzed by cyclodextrins or proteolytic enzymes
V. Daffe and J. Fastrez
pp 3601 - 3605; DOI:
10.1021/ja00530a047
PDF
23672 RP, a new macrolide antibiotic from Streptomyces chryseus. Mass spectrometry study and x-ray structure determination
Bernadette Arnoux, Claudine Pascard, Laurent Raynaud, and Jean Lunel
pp 3605 - 3608; DOI:
10.1021/ja00530a048
PDF
Iron-ligand stretching band in the resonance Raman spectra of ferrous iron porphyrin derivatives. Importance as a probe band for quaternary structure of hemoglobin
Hiroshi Hori and Teizo Kitagawa
pp 3608 - 3613; DOI:
10.1021/ja00530a049
PDF
Substrate specificity of farnesylpyrophosphate synthetase. Application to asymmetric synthesis
Tanetoshi Koyama, Akio Saito, Kyozo Ogura, and Shuichi Seto
pp 3614 - 3618; DOI:
10.1021/ja00530a050
PDF
Tunneling effects in the hydrogen atom transfer reaction of tetrasubstituted cyclopropenes
Albert Padwa and Chuen S. Chou
pp 3619 - 3620; DOI:
10.1021/ja00530a051
PDF
.alpha. Deprotonation of .beta.-lactones - an example of a forbidden .beta. elimination
Johann Mulzer and Thomas Kerkmann
pp 3620 - 3622; DOI:
10.1021/ja00530a052
PDF
Osmochromes (osmium analogs of hemochromes): proof of superoxide and hydroperoxide generation from dioxygen and a metalloporphyrin lacking a free coordination site
Jochen Billecke, Wolfgang Kokisch, and J. W. Buchler
pp 3622 - 3624; DOI:
10.1021/ja00530a053
PDF
A nonoctahedral dioxo molybdenum complex with a coordinated partial disulfide bond
Edward I. Stiefel, Kenneth F. Miller, Alice E. Bruce, James L. Corbin, Jeremy M. Berg, and Keith O. Hodgson
pp 3624 - 3626; DOI:
10.1021/ja00530a054
PDF
Synthesis, structure, and reactivity of mercurial derivatives of an organoruthenium cluster
Raed Fahmy, Kevin King, Edward Rosenberg, Antonio Tiripicchio, and Marisa Tiripicchio Camellini
pp 3626 - 3628; DOI:
10.1021/ja00530a055
PDF
General acid catalyzed dissociation of metal cryptates
B. G. Cox and H. Schneider
pp 3628 - 3630; DOI:
10.1021/ja00530a056
PDF
3.eta.-Homoallylcobalt complexes in the intramolecular rearrangements of but-3-enylcobaloximes
Martin P. Atkins, Bernard T. Golding, Adrian Bury, Michael D. Johnson, and Phillip J. Sellars
pp 3630 - 3632; DOI:
10.1021/ja00530a057
PDF
Synthetic studies on pyrrolizidine alkaloids. 1. (.+-.)-Heliotridine and (.+-.)-retronecine via intramolecular dienophile transfer
Gary E. Keck and David G. Nickell
pp 3632 - 3634; DOI:
10.1021/ja00530a058
PDF
Photochemical annelations. 6. Four-carbon photochemical annelation of alkenes with 2,2,6-trimethyl-1,3-dioxolenone
S. W. Baldwin and J. M. Wilkinson
pp 3634 - 3635; DOI:
10.1021/ja00530a059
PDF
NMR of individual sites in protein crystals. Magnetic ordering effects
Eric Oldfield and T. Michael Rothgeb
pp 3635 - 3637; DOI:
10.1021/ja00530a060
PDF
Molecular A frames. Synthesis from binuclear rhodium(0) precursors and catalytic activity in the water gas shift reaction and alkyne hydrogenation
Clifford P. Kubiak and Richard Eisenberg
pp 3637 - 3639; DOI:
10.1021/ja00530a061
PDF
Microwave spectrum, dipole moment, and structure of spiro[2.4]hepta-4,6-diene. Evidence for significant cyclopropyl conjugation
Stuart W. Staley, Allison E. Howard, Marlin D. Harmony, S. N. Mathur, Mano Kattija-Ari, Jong-In Choe, and Gerhard Lind
pp 3639 - 3640; DOI:
10.1021/ja00530a062
PDF
Synthesis of 1,2:3,4-diepoxides by catalyzed rearrangement of 1,4-endoperoxides
Jack D. Boyd, Christopher S. Foote, and David K. Imagawa
pp 3641 - 3642; DOI:
10.1021/ja00530a063
PDF
Synthesis and reactions of porphine-type metal complexes. 8. Carbon-carbon bond formation catalyzed by vitamin B12 and a vitamin B12 model compound. Electrosynthesis of bicyclic ketones by 1,4 addition
Rolf Scheffold, Meera Dike, Suneel Dike, Thomas Herold, and Lorenz Walder
pp 3642 - 3644; DOI:
10.1021/ja00530a064
PDF
Formation of 1,2-dioxetanes and probable trapping of an intermediate in the reactions of some enol ethers with singlet oxygen
E. W. H. Asveld and Richard M. Kellogg
pp 3644 - 3646; DOI:
10.1021/ja00530a065
PDF
Photoinduced cyclization of mono- and dianions of N-acyl-o-chloranilines. A general oxindole synthesis
James F. Wolfe, Mark C. Sleevi, and R. Richard Goehring
pp 3646 - 3647; DOI:
10.1021/ja00530a066
PDF
Unsymmetrical cleavage of boranes by bis(trimethlyphosphine)-diborane(4). Formation of a triboron cation
Mitsuaki Kameda and Goji Kodama
pp 3647 - 3649; DOI:
10.1021/ja00530a067
PDF
Carbon-carbon bond formation in the reaction of calcium atoms with ethers
W. E. Billups, Mark M. Konarski, Robert H. Hauge, and John L. Margrave
pp 3649 - 3650; DOI:
10.1021/ja00530a068
PDF
Laser-induced metal ion luminescence: interlanthanide ion energy transfer distance measurements in the calcium-binding proteins, parvalbumin, and thermolysin. Metalloprotein models address a photophysical problem
William DeW. Horrocks, Moo-Jhong Rhee, A. Peter Snyder, and Daniel R. Sudnick
pp 3650 - 3652; DOI:
10.1021/ja00530a069
PDF
Approaches to homogenous reduction of carbon monoxide. 2. Reactions of bis(.eta.5-cyclopentadienyl)trihydridoniobium with metal carbonyls: selective reduction of carbon monoxide to ethane
Kwai Sam Wong and Jay A. Labinger
pp 3652 - 3653; DOI:
10.1021/ja00530a070
PDF
Evidence for an intermediate in nucleophilic substitution of a thiamin analog. Change from first- to second-order kinetics in sulfite ion
John A. Zoltewicz, Georg Uray, and Glenn M. Kauffman
pp 3653 - 3654; DOI:
10.1021/ja00530a071
PDF
Total synthesis of (.+-.)-trichodermol
W. Clark Still and Mei-Yuan Tsai
pp 3654 - 3655; DOI:
10.1021/ja00530a072
PDF
Electronic spectra of model oxy, carboxy P450, and carboxy heme complexes
Gilda H. Loew and Marie Madeleine Rohmer
pp 3655 - 3657; DOI:
10.1021/ja00530a073
PDF
Electronic spectrum of model cytochrome P450 complex with postulated carbene metabolite of halothane
Gilda Loew and Amiram Goldblum
pp 3657 - 3659; DOI:
10.1021/ja00530a074
PDF
A reversible field induced phase transition in semiconducting films of silver and copper TNAP radical-ion salts
Richard S. Potember, Theodore O. Poehler, Angela Rappa, Dwaine O. Cowan, and Aaron N. Bloch
pp 3659 - 3660; DOI:
10.1021/ja00530a075
PDF
Competitive oxidation processes in the reaction between (dicyclopentadienyl)zirconium bis(phosphine) complexes and alkyl halides
Gregory M. Williams, Kerrie I. Gell, and Jeffrey Schwartz
pp 3660 - 3662; DOI:
10.1021/ja00530a076
PDF
Additions and Corrections - Statistical Phase Space Theory of Polyatomic Systems. Application to the Unimolecular Reactions C6H5CN·+→C6H4·+ + HCN and C4H6·+→C3H3+ + ·CH3
Walter J. Chesnavich, and Michael T. Bowers
pp 3662 - 3662; DOI:
10.1021/ja00530a600
PDF
Additions and Corrections - Catalytic Decarbonylation of Aldehydes
D. H. Doughty, and L. H. Pignolet
pp 3662 - 3663; DOI:
10.1021/ja00530a601
PDF
Additions and Corrections - Sensitivity Enhancement in Natural Abundance Proton-Coupled 15N NMR Spectra Using the Selective Population Transfer Method
Hans J. Jakobsen, and Wallace S. Brey
pp 3663 - 3663; DOI:
10.1021/ja00530a602
PDF
Additions and Corrections - Methyl-Substituted Allyl Cations. A Comparison of Experimental Stability, Rotational Barrier, and Solvolysis Data with ab Initio Calculations
Herbert Mayr, Wolfgang Förner, and Paul von Ragué Schleyer
pp 3663 - 3663; DOI:
10.1021/ja00530a603
PDF
Additions and Corrections - Free Energy Relationships for Electron-Transfer Processes
Franco Scandola
pp 3663 - 3663; DOI:
10.1021/ja00530a604
PDF
Additions and Corrections - Conformational Characteristics of Poly(methyl vinyl ketone)s and of Simple Model Ketones
Ulrich W. Suter
pp 3663 - 3663; DOI:
10.1021/ja00530a605
PDF
Additions and Corrections - Structure and Reactivity in Intramolecular Catalysis. Catalysis of Sulfonamide Hydrolysis by the Neighboring Carboxyl Group
Teun Graafland, Anno Wagenaar, Anthony J. Kirby, and Jan B. F. N. Engberts
pp 3663 - 3663; DOI:
10.1021/ja00530a606
PDF
Additions and Corrections - A New Empirical Method to Calculate Average Molecular Polarizabilities
Kenneth J. Miller, and John A. Savchik
pp 3663 - 3663; DOI:
10.1021/ja00530a607
PDF
Additions and Corrections - Intramolecular Electrostatic and General Acid Catalysis in the Hydrolysis of O,S-Thioacetals
Thomas H. Fife, and Theodore J. Przystas
pp 3663 - 3663; DOI:
10.1021/ja00530a608
PDF
Additions and Corrections - Photolysis of Alkyl Azides. Evidence for a Nonnitrene Mechanism
Evan P. Kyba, and Rudolph A. Abramovitch
pp 3663 - 3663; DOI:
10.1021/ja00530a609
PDF
Additions and Corrections - The Chemistry of Bis(fulvalene)divanadium
James C. Smart, and Barry L. Pinsky
pp 3663 - 3663; DOI:
10.1021/ja00530a610
PDF
Additions and Corrections - Stereospecific Total Synthesis of a "Slow Reacting Substance" of Anaphylaxis Leukotriene C-1
E. J. Corey, David A. Clark, Giichi Goto, Anthony Marfat, Charles Mioskowski, Bengt Samuelsson, and Sven Hammarstrom
pp 3663 - 3663; DOI:
10.1021/ja00530a611
PDF
Book Reviews

pp 3664 - 3670; DOI:
10.1021/ja00530a612
PDF

Issue 11


The concept of Fermi level pinning at semiconductor/liquid junctions. Consequences for energy conversion efficiency and selection of useful solution redox couples in solar devices
Allen J. Bard, Andrew B. Bocarsly, Fu Ren F. Fan, Erick G. Walton, and Mark S. Wrighton
pp 3671 - 3677; DOI:
10.1021/ja00531a001
PDF
Semiconductor electrodes. 24. Behavior of photoelectrochemical cells based on p-type gallium arsenide in aqueous solutions
Fu Ren F. Fan and Allen J. Bard
pp 3677 - 3683; DOI:
10.1021/ja00531a002
PDF
Photoreduction at illuminated p-type semiconducting silicon photoelectrodes. Evidence for Fermi level pinning
Andrew B. Bocarsly, Dana C. Bookbinder, Raymond N. Dominey, Nathan S. Lewis, and Mark S. Wrighton
pp 3683 - 3688; DOI:
10.1021/ja00531a003
PDF
Photoinduced processes in copper(II)-crown ether surfactant micelles
R. Humphry-Baker, Y. Moroi, M. Graetzel, Ezio Pelizzetti, and Pietro Tundo
pp 3689 - 3692; DOI:
10.1021/ja00531a004
PDF
Circularly polarized luminescence studies of the ternary complexes formed between terbium(III), pyridine-2,6-dicarboxylic acid, and amino acids
Harry G. Brittain
pp 3693 - 3698; DOI:
10.1021/ja00531a005
PDF
Conformational analysis. 39. Carbon-13 NMR spectra of saturated heterocycles. 9. Piperidine and N-methylpiperidine
Ernest L. Eliel, Duraisamy Kandasamy, Chen-yu Yen, and Karl D. Hargrave
pp 3698 - 3707; DOI:
10.1021/ja00531a006
PDF
Influence of substituents at the 5 position on the structure of uridine
Ernst Egert, Hans Joerg Lindner, Wolfgang Hillen, and Michael C. Boehm
pp 3707 - 3713; DOI:
10.1021/ja00531a007
PDF
Origin of the differential acidity of diastereotopic protons in sulfonium salts
Samuel Lindsay Graham and Clayton H. Heathcock
pp 3713 - 3718; DOI:
10.1021/ja00531a008
PDF
Transition state vibrational analysis for the methyl isocyanide rearrangement, CH3NC .fwdarw. CH3CN
Paul Saxe, Yukio Yamaguchi, Peter Pulay, and Henry F. Schaefer
pp 3718 - 3723; DOI:
10.1021/ja00531a009
PDF
Internal rotations in aliphatic molecules: n-butane and 2,2,3,3-tetrafluorobutane
Steve Scheiner
pp 3723 - 3728; DOI:
10.1021/ja00531a010
PDF
Diffusion in rigid bilayer membranes. Use of combined multiple pulse and multiple pulse gradient techniques in nuclear magnetic resonance
M. Silva Crawford, B. C. Gerstein, An-Li Kuo, and C. G. Wade
pp 3728 - 3732; DOI:
10.1021/ja00531a011
PDF
Thermochemistry and unimolecular reactions of ionized acetic acid and its enol in the gas phase
John L. Holmes and F. P. Lossing
pp 3732 - 3735; DOI:
10.1021/ja00531a012
PDF
Unimolecular equilibration of isomeric cation radicals. Mechanism of decomposition of ionized methyl isobutyrate in the gas phase
Philip H. Hemberger, Jan C. Kleingeld, Karsten Levsen, Nili Mainzer, Asher Mandelbaum, Nico M. M. Nibbering, Helmut Schwarz, Raymund Weber, Adrian Weisz, and Chrysostomos Wesdemiotis
pp 3736 - 3745; DOI:
10.1021/ja00531a013
PDF
A kinetic investigation of the insertion of ketones into the dioxygen adduct dioxobis(triphenylphosphine)platinum
Renato Ugo, Giovanni Maria Zanderighi, Achille Fusi, and Daniela Carreri
pp 3745 - 3751; DOI:
10.1021/ja00531a014
PDF
A kinetics study of the oxidation of iron(II) by nitric acid
Irving R. Epstein, Kenneth Kustin, and Linda Joyce Warshaw
pp 3751 - 3758; DOI:
10.1021/ja00531a015
PDF
Oxidative addition of aryl carboxylates to nickel(0) complexes involving cleavage of the acyl-oxygen bond
Takakazu Yamamoto, Junichi Ishizu, Teiji Kohara, Sanshiro Komiya, and Akio Yamamoto
pp 3758 - 3764; DOI:
10.1021/ja00531a016
PDF
The 147-nm photolysis of disilane
G. G. A. Perkins and F. W. Lampe
pp 3764 - 3769; DOI:
10.1021/ja00531a017
PDF
Metal-silicon bonded compounds. 12. Crystal and molecular structure of hexameric trimethylsilyllithium, [LiSiMe3]6
William H. Ilsley, Theodore F. Schaaf, Milton D. Glick, and John P. Oliver
pp 3769 - 3774; DOI:
10.1021/ja00531a018
PDF
Allylation of quinones with allyltin reagents
Yoshinori Naruta
pp 3774 - 3783; DOI:
10.1021/ja00531a019
PDF
Phenylselenoetherification. A highly efficient cyclization process for the synthesis of oxygen- and sulfur-heterocycles
K. C. Nicolaou, R. L. Magolda, W. J. Sipio, W. E. Barnette, Z. Lysenko, and M. M. Joullie
pp 3784 - 3793; DOI:
10.1021/ja00531a020
PDF
Gas-phase chemistry of copper(1+) with alkyl chlorides
Roger W. Jones and Ralph H. Staley
pp 3794 - 3798; DOI:
10.1021/ja00531a021
PDF
Three-electron oxidations. 17. The chromium(VI) and chromium(V) steps in the chromic acid cooxidation of 2-hydroxy-2-methylbutyric acid and 2-propanol
Surendra N. Mahapatro, Miroslav Krumpolc, and Jan Rocek
pp 3799 - 3806; DOI:
10.1021/ja00531a022
PDF
Determination of the lifetimes of unstable ion radicals by homogeneous redox catalysis of electrochemical reactions. Application to the reduction of aromatic halides
C. P. Andrieux, C. Blocman, J. M. Dumas-Bouchiat, F. M'Halla, and J. M. Saveant
pp 3806 - 3813; DOI:
10.1021/ja00531a023
PDF
N-tert-butoxy-N-tert-alkylaminyls. A new class of persistent radicals
Helmut Woynar and K. U. Ingold
pp 3813 - 3815; DOI:
10.1021/ja00531a024
PDF
Transient species in photochemistry of enones. The orthogonal triplet state revealed by laser photolysis
Roland Bonneau
pp 3816 - 3822; DOI:
10.1021/ja00531a025
PDF
Structural effects on the intramolecular electron transfer induced decomposition of a series of 1,2-dioxetanes derived from 9-alkylidene-10-methylacridans
Chris Lee and Lawrence A. Singer
pp 3823 - 3829; DOI:
10.1021/ja00531a026
PDF
Solvolysis in 2,2,2-trifluoroethanol-water and 2,2,2-trifluoroethanol-ethanol mixtures. Selectivity of the intermediates and N values
Joseph Kaspi and Zvi Rappoport
pp 3829 - 3837; DOI:
10.1021/ja00531a027
PDF
Vinylic cations from solvolysis. 29. Solvolysis of 9-(.alpha.-bromoarylidene)anthrones as a probe to the reactivity-selectivity relationship in solvolysis reactions
Zvi Rappoport, Yitzhak Apeloig, and Jeremy Greenblatt
pp 3837 - 3848; DOI:
10.1021/ja00531a028
PDF
Scope and mechanism of the reaction of olefins with anhydrides and zinc chloride to give .beta.,.gamma.-unsaturated ketones
Peter Beak and Kenneth R. Berger
pp 3848 - 3856; DOI:
10.1021/ja00531a029
PDF
Mechanism of anodic cleavage of benzyl ethers
Jean W. Boyd, Paul W. Schmalzl, and Larry L. Miller
pp 3856 - 3862; DOI:
10.1021/ja00531a030
PDF
Synthesis and thermal decomposition of cis-3,4,5,6-tetrahydropyridazine-3,4-d2. Relative rates of rotation, cleavage, and closure for tetramethylene
Peter B. Dervan and Donald S. Santilli
pp 3863 - 3870; DOI:
10.1021/ja00531a031
PDF
Regioselectivity in cycloadditions of singlet 2-methylenecyclopenta-1,3-diyl species
Roger K. Siemionko and Jerome A. Berson
pp 3870 - 3882; DOI:
10.1021/ja00531a032
PDF
Preparation of trialkyltriazenes. A comparison of the nitrogen-nitrogen bond rotation in trialkyltriazenes and aryldialkyltriazenes by variable temperature carbon-13 NMR
David H. Sieh, David J. Wilbur, and Christopher J. Michejda
pp 3883 - 3887; DOI:
10.1021/ja00531a033
PDF
Fatty acids containing photoactivable carbene precursors. Synthesis and photochemical properties of 3,3-bis(1,1-difluorohexyl)diazirine and 3-(1,1-difluorooctyl)-3H-diazirine
Bernhard Erni and H. Gobind Khorana
pp 3888 - 3896; DOI:
10.1021/ja00531a034
PDF
Tautomerism of formycin. Mechanism of interconversion
Guy Dodin, Olivier Bensaude, and Jacques Emile Dubois
pp 3897 - 3899; DOI:
10.1021/ja00531a035
PDF
The pseudophase model of micellar catalysis. Addition of cyanide ion to N-alkylpyridinium ions
Clifford A. Bunton, Laurence S. Romsted, and Chirasarit Thamavit
pp 3900 - 3903; DOI:
10.1021/ja00531a036
PDF
A stereospecific total synthesis of (.+-.)-methylenomycin A and its epimer, (.+-.)-epimethylenomycin A
Robert M. Scarborough, Bruce H. Toder, and Amos B. Smith
pp 3904 - 3913; DOI:
10.1021/ja00531a037
PDF
Reduction of the syn-anti glycosyl conformational barrier in 2'-deoxyadenosine upon binding to ethidium bromide. Evidence from ultrasonic relaxation measurements
Frank Jordan, Sadakatsu Nishikawa, and Paul Hemmes
pp 3913 - 3917; DOI:
10.1021/ja00531a038
PDF
Protonic reorganization and substrate structure in catalysis by serine proteases
James P. Elrod, John L. Hogg, Daniel M. Quinn, K. S. Venkatasubban, and Richard L. Schowen
pp 3917 - 3922; DOI:
10.1021/ja00531a039
PDF
Does substrate rather than protein provide the catalyst for .alpha.-proton abstraction in aldolase?
R. A. Periana, Rossana Motiu-DeGrood, Yvonne Chiang, and D. J. Hupe
pp 3923 - 3927; DOI:
10.1021/ja00531a040
PDF
Model studies on the mechanism of biotin-dependent carboxylations. 2. Site of protonation vs. carbon dioxide transfer
Melanie J. Cravey and Harold Kohn
pp 3928 - 3939; DOI:
10.1021/ja00531a041
PDF
Reactions of water-soluble metalloporphyrins with the serum protein, hemopexin
Esther Gibbs, William R. Skowronek, William T. Morgan, U. Muller-Eberhard, and Robert F. Pasternack
pp 3939 - 3944; DOI:
10.1021/ja00531a042
PDF
Isotopic perturbation of degenerate conformational equilibriums
Frank A. L. Anet, V. J. Basus, A. P. W. Hewett, and Martin Saunders
pp 3945 - 3946; DOI:
10.1021/ja00531a043
PDF
Interaction of an iron macrocyclic complex with apohemoglobin and apomyoglobin
V. Gottfried, S. Weiss, and Z. Dori
pp 3946 - 3948; DOI:
10.1021/ja00531a044
PDF
Photoinduced reactions. 115. A novel photoaddition of 6-cyanouracils to alkenes and alkynes involving migration of a cyano group
Isao Saito, Koji Shimozono, and Teruo Matsuura
pp 3948 - 3950; DOI:
10.1021/ja00531a045
PDF
Two-laser multiphoton dissociation of iodobenzene cation
Robert C. Dunbar, John D. Hays, Jeffrey P. Honovich, and Naomi B. Lev
pp 3950 - 3951; DOI:
10.1021/ja00531a046
PDF
Exceptional reactivity of the bicyclo[2.2.1]heptene double bond
Rolf Huisgen, Pieter H. J. Ooms, Margarita Mingin, and Norman L. Allinger
pp 3951 - 3953; DOI:
10.1021/ja00531a047
PDF
Spectroscopic studies on cobalt(II) metallothionein: evidence for pseudotetrahedral metal coordination
Milan Vasak
pp 3953 - 3955; DOI:
10.1021/ja00531a048
PDF
Synthesis and structural study of the first phosphorus(V)-phosphorus(V) compound
Jack E. Richman, Roberta O. Day, and Robert R. Holmes
pp 3955 - 3955; DOI:
10.1021/ja00531a049
PDF
A novel synthesis of methyl .alpha.-L-garosaminide which illustrates a stereocontrolled approach to the cis-hydroxyamino moiety of amino sugars
Henry W. Pauls and Bert Fraser-Reid
pp 3956 - 3957; DOI:
10.1021/ja00531a050
PDF
Mesomeric stabilization of carbonium ions by .alpha.-cyano groups. A theoretical evaluation of inductive vs. resonance effects of the cyano moiety
David A. Dixon, Patricia A. Charlier, and Paul G. Gassman
pp 3957 - 3959; DOI:
10.1021/ja00531a051
PDF
Role of HMPT and TMEDA in control of enolate stereochemistry for reactions of lithium amides with 3-pentanone
Zacharia A. Fataftah, Ihor E. Kopka, and Michael W. Rathke
pp 3959 - 3960; DOI:
10.1021/ja00531a052
PDF
Catalytic mechanisms of acyl transfer reactions in dipolar aprotic media. 1. Desolvated carboxylate ion as acyl acceptor
Joseph Hajdu and Georgianna M. Smith
pp 3960 - 3962; DOI:
10.1021/ja00531a053
PDF
Total synthesis of streptonigrin
Fatima Z. Basha, Satoshi Hibino, Deukjoon Kim, Walter E. Pye, Tai-Teh Wu, and Steven M. Weinreb
pp 3962 - 3964; DOI:
10.1021/ja00531a054
PDF
Total synthesis of pseudoguaianolides: (.+-.)-aromaticin and (.+-.)-aromatin
Peter T. Lansbury, David G. Hangauer, and Joseph P. Vacca
pp 3964 - 3965; DOI:
10.1021/ja00531a055
PDF
X-ray structural analysis of H3[Rh4(bridge)8Cl][CoCl4]4.nH2O. The photoactive species in the production of hydrogen from aqueous solutions
Kent R. Mann, Michael J. DiPierro, and Thomas P. Gill
pp 3965 - 3967; DOI:
10.1021/ja00531a056
PDF
Selective enhancement of bimolecular reaction rates by over three orders of magnitude using low intensity CW infrared laser radiation
D. S. Bomse and J. L. Beauchamp
pp 3967 - 3969; DOI:
10.1021/ja00531a057
PDF
Resolution of chiral phosphamides
Nicholas Bodor, Kenneth Knutson, and Tadao Sato
pp 3969 - 3971; DOI:
10.1021/ja00531a058
PDF
Reactions of (chlorocarbonyl)phenylketene. Formation of a new class of heterocyclic zwitterion
Kevin T. Potts, Shuji Kanemasa, and Gury Zvilichovsky
pp 3971 - 3972; DOI:
10.1021/ja00531a059
PDF
A stereocontrolled synthetic entry to the primary prostaglandins from butadiene. Oxy anionic substituent effects on [1,5]-hydrogen sigmatropy
Leo A. Paquette, Gary D. Crouse, and Ashok K. Sharma
pp 3972 - 3974; DOI:
10.1021/ja00531a060
PDF
Asymmetric total synthesis of brevianamide E
Tetsuji Kametani, Naoaki Kanaya, and Masataka Ihara
pp 3974 - 3975; DOI:
10.1021/ja00531a061
PDF
Motional collapse of methyl group vibrational bands
Richard A. MacPhail, Robert G. Snyder, and Herbert L. Strauss
pp 3976 - 3976; DOI:
10.1021/ja00531a062
PDF
Electron transfer in nickel-catalyzed addition reactions
Fabian M. Dayrit, Daniel E. Gladkowski, and Jeffrey Schwartz
pp 3976 - 3978; DOI:
10.1021/ja00531a063
PDF
Photohydrolysis of sulfonamides via donor-acceptor ion pairs with electron-donating aromatics and its application to the selective detosylation of lysine peptides
Tatsuo Hamada, Atsushi Nishida, Yuichi Matsumoto, and Osamu Yonemitsu
pp 3978 - 3980; DOI:
10.1021/ja00531a064
PDF
Difluoromethylene chain-extension reactions. Preparation of fluorinated alkenes and alkadienes from olefin precursors
Donald J. Burton, Yoshio Inouye, and James A. Headley
pp 3980 - 3982; DOI:
10.1021/ja00531a065
PDF
The hydronium ion (H3O+), pyramidal or planar?
Martyn C. R. Symons
pp 3982 - 3982; DOI:
10.1021/ja00531a066
PDF
Stabilization of carbanions by silicon. Restricted aryl rotation in the 4-methyl-4'-trimethylsilyldiphenylmethyl anion
Shelton Bank, John S. Sturges, Dennis Heyer, and C. Hackett Bushweller
pp 3982 - 3984; DOI:
10.1021/ja00531a067
PDF
Isotopic oxygen studies on aqueous molybdenum(IV)
R. Kent Murmann and Marc E. Shelton
pp 3984 - 3985; DOI:
10.1021/ja00531a068
PDF
Book Reviews

pp 3985 - 3986; DOI:
10.1021/ja00531a600
PDF

Issue 12


Conformational analysis. 7. 1,2-Difluoroethane. An electron-diffraction investigation of the molecular structure, composition, trans-gauche energy and entropy differences, and potential hindering internal rotation
Dwayne Friesen and Kenneth Hedberg
pp 3987 - 3994; DOI:
10.1021/ja00532a001
PDF
Energy transfer in ion-molecule association reactions. Dependence of collisional stabilization efficiency on the collision gas
R. D. Cates and M. T. Bowers
pp 3994 - 3996; DOI:
10.1021/ja00532a002
PDF
Control of energy deposition by impact parameter in polyatomic ion collisions
A. R. Hubik, P. H. Hemberger, J. A. Laramee, and R. G. Cooks
pp 3997 - 4000; DOI:
10.1021/ja00532a003
PDF
Effect of the methyl group rotation on the rate of intramolecular proton exchange in .alpha.-methyl-.beta.-hydroxyacrolein
J. H. Busch, E. M. Fluder, and Jose R. De la Vega
pp 4000 - 4004; DOI:
10.1021/ja00532a004
PDF
A predictor of reactivity in allowed photodimerizations and photocycloadditions
Richard A. Caldwell
pp 4004 - 4007; DOI:
10.1021/ja00532a005
PDF
Influence of starting conformations on intramolecular exciplex formation in .omega.-phenyl-.alpha.-N,N-dimethylaminoalkanes
M. Van der Auweraer, A. Gilbert, and F. C. De Schryver
pp 4007 - 4017; DOI:
10.1021/ja00532a006
PDF
Thermodynamic and kinetic aspects of the intermolecular exciplex formation between 2-methylnaphthalene and aliphatic amines
F. Meeus, M. Van der Auweraer, and F. C. De Schryver
pp 4017 - 4024; DOI:
10.1021/ja00532a007
PDF
Stepwise bond dissociation energies in sulfur hexafluoride
T. Kiang and R. N. Zare
pp 4024 - 4029; DOI:
10.1021/ja00532a008
PDF
Covalent attachment of arenes to tin oxide (SnO2)-semiconductor electrodes
Marye Anne Fox, Frederic J. Nobs, and Tamara A. Voynick
pp 4029 - 4036; DOI:
10.1021/ja00532a009
PDF
Chemically modified electrodes in dye-sensitized photogalvanic cells
Marye Anne Fox, Frederic J. Nobs, and Tamara A. Voynick
pp 4036 - 4039; DOI:
10.1021/ja00532a010
PDF
An approach to the mapping of internal motions in proteins. Analysis of carbon-13 NMR relaxation in the bovine pancreatic trypsin inhibitor
Anthony A. Ribeiro, Roy King, Charles Restivo, and Oleg Jardetzky
pp 4040 - 4051; DOI:
10.1021/ja00532a011
PDF
Ab initio, quantum chemical analysis of noncovalent interactions between peptides as modeled by dimers and a trimer of formamide
Ernest L. Mehler
pp 4051 - 4056; DOI:
10.1021/ja00532a012
PDF
Thermochemistry of trans-diimide and 1,1-diazene. Ab initio studies
Carla J. Casewit and William A. Goddard
pp 4057 - 4062; DOI:
10.1021/ja00532a013
PDF
A palladium-catalyzed reaction of a .pi.-allyl ligand with a nucleophile. An MO study about a feature of the reaction and a ligand effect on the reactivity
Shigeyoshi Sakaki, Masahiro Nishikawa, and Akira Ohyoshi
pp 4062 - 4069; DOI:
10.1021/ja00532a014
PDF
Nitrosomethane and its nitrone and oxime isomers. A theoretical study of 1,2- and 1,3-intramolecular hydrogen shifts
Paul D. Adeney, Willem J. Bouma, Leo Radom, and William R. Rodwell
pp 4069 - 4074; DOI:
10.1021/ja00532a015
PDF
A theoretical approach to the Birch reduction. Structures and stabilities of cyclohexadienyl radicals
Arthur J. Birch, Alan L. Hinde, and Leo Radom
pp 4074 - 4080; DOI:
10.1021/ja00532a016
PDF
Structure and singlet-triplet separation in simple germylenes GeH2, GeF2, and Ge(CH3)2
Jean Claude Barthelat, Bruno Saint Roch, Georges Trinquier, and Jacques Satge
pp 4080 - 4085; DOI:
10.1021/ja00532a017
PDF
Spectroscopic studies of photochemically important transition metal excited states. 2. The 1T1g, 3T1g, and 5T2g excited states of hexaamminecobalt(III)
Randall B. Wilson and Edward I. Solomon
pp 4085 - 4095; DOI:
10.1021/ja00532a018
PDF
The electronic spectrum of tris(2,2'-bipyridine)ruthenium(2+)
Franz Felix, James Ferguson, Hans U. Guedel, and Andreas Ludi
pp 4096 - 4102; DOI:
10.1021/ja00532a019
PDF
The electronic spectrum of tris(2,2'-bipyridine)iron(2+) and tris (2,2'-bipyridine)osmium(2+)
Silvio Decurtins, Franz Felix, James Ferguson, Hans U. Guedel, and Andreas Ludi
pp 4102 - 4106; DOI:
10.1021/ja00532a020
PDF
Molecular complexes of cyclic polyethers. 6. Structure of and binding interactions in a host-guest complex of a macrocyclic hexaether with tert-butylammonium perchlorate. Survey of crystallographic data
Israel Goldberg
pp 4106 - 4113; DOI:
10.1021/ja00532a021
PDF
Preparation and molecular structure of TaH[P(C6H5)2]2[(CH3)2PC2H4P(CH3)2]2, a metal hydride of the type MHL2(bidentate phosphine)2n+ having a pentagonal-bipyramidal structure
P. J. Domaille, Bruce M. Foxman, T. J. McNeese, and S. S. Wreford
pp 4114 - 4120; DOI:
10.1021/ja00532a022
PDF
The solvent as hydrogen-atom donor in organic electrochemical reactions. Reduction of aromatic halides
F. M'Halla, J. Pinson, and J. M. Saveant
pp 4120 - 4127; DOI:
10.1021/ja00532a023
PDF
Electrolytic reduction of 1,4-dihalonorbornanes at mercury electrodes in dimethylformamide. Evidence for [2.2.1]propellane as an intermediate
William F. Carroll and Dennis G. Peters
pp 4127 - 4134; DOI:
10.1021/ja00532a024
PDF
Completion of Koerner's proof that the hydrogens of benzene are homotopic. An application of group theory
J. Michael McBride
pp 4134 - 4137; DOI:
10.1021/ja00532a025
PDF
Effect of .alpha.-cyano groups on neighboring group participation in carbonium ion reactions
Paul G. Gassman and John J. Talley
pp 4138 - 4143; DOI:
10.1021/ja00532a026
PDF
Gas-phase chemistry of titanium(1+) with halomethanes, alkyl chlorides, chloroethylenes, and chlorobenzene
Jack S. Uppal and Ralph H. Staley
pp 4144 - 4149; DOI:
10.1021/ja00532a027
PDF
Solution thermodynamic studies. 5. A thermodynamic study of solvent effects on the relative stability of diastereoisomers. The trans-1,2-dibromo-4-tert-butylcyclohexane, trans-2,3-dibromodecalin, and 1-bromo-4-tert-butylcyclohexane systems
J. J. Moura Ramos, L. Dumont, M. L. Stien, and J. Reisse
pp 4150 - 4154; DOI:
10.1021/ja00532a028
PDF
Kinetics and mechanism for pyridine N-oxide carboxaldehyde phenylhydrazone formation
Valkiria Okano, Marilene P. Bastos, and Luciano Do Amaral
pp 4155 - 4159; DOI:
10.1021/ja00532a029
PDF
Photochemical and thermal rearrangements of protonated 2,3-homotropones
Ronald F. Childs and Carol V. Rogerson
pp 4159 - 4166; DOI:
10.1021/ja00532a030
PDF
Charge-transfer quenching of triplet .alpha.-trifluoroacetophenones
Peter J. Wagner and Henry M. H. Lam
pp 4167 - 4172; DOI:
10.1021/ja00532a031
PDF
Proton, carbon-13, and fluorine-19 nuclear polarizations in the photochemistry of .alpha.,.alpha.,.alpha.-trifluoroacetophenone
Peter J. Wagner and Michael J. Thomas
pp 4173 - 4182; DOI:
10.1021/ja00532a032
PDF
Synthesis and characterization of "tailed picket fence" porphyrins
James P. Collman, John I. Brauman, Kenneth M. Doxsee, Thomas R. Halbert, Edward Bunnenberg, Robert E. Linder, Gerd N. LaMar, John Del Gaudio, George Lang, and K. Spartalian
pp 4182 - 4192; DOI:
10.1021/ja00532a033
PDF
Synthesis of lactones by the palladium-catalyzed carbonylation of halo alcohols
A. Cowell and J. K. Stille
pp 4193 - 4198; DOI:
10.1021/ja00532a034
PDF
Anomalous equilibrium and kinetic .alpha.-deuterium secondary isotope effects accompanying hydride transfer from reduced nicotinamide adenine dinucleotide
Linda C. Kurz and Carl Frieden
pp 4198 - 4203; DOI:
10.1021/ja00532a035
PDF
Structure of natural antibiotic CP-47,444
W. D. Celmer, G. N. Chmurny, C E. Moppett, R. S. Ware, P. C. Watts, and E. B. Whipple
pp 4203 - 4209; DOI:
10.1021/ja00532a036
PDF
Structural studies of the hemocyanin active site. 1. Extended x-ray absorption fine structure (EXAFS) analysis
J. M. Brown, L. Powers, B. Kincaid, J. A. Larrabee, and T. G. Spiro
pp 4210 - 4216; DOI:
10.1021/ja00532a037
PDF
Structural studies of the hemocyanin active site. 2. Resonance Raman spectroscopy
James A. Larrabee and Thomas G. Spiro
pp 4217 - 4223; DOI:
10.1021/ja00532a038
PDF
Crystal structure of ferrichrome and a comparison with the structure of ferrichrome A
Dick Van der Helm, J. R. Baker, D. L. Eng-Wilmot, M. B. Hossain, and R. A. Loghry
pp 4224 - 4231; DOI:
10.1021/ja00532a039
PDF
Covalent linkage of glucose oxidase on modified glassy carbon electrodes. Kinetic phenomena
C. Bourdillon, J. P. Bourgeois, and D. Thomas
pp 4231 - 4235; DOI:
10.1021/ja00532a040
PDF
A novel intramolecular hydrogen bond in the crystal structure of 5-hydroxymethyl-2'-deoxyuridine, an antiviral and antineoplastic nucleoside. Conformational analysis of the deoxyribose ring
George I. Birnbaum, Roxanne Deslauriers, Tai Shun Lin, George T. Shiau, and William H. Prusoff
pp 4236 - 4241; DOI:
10.1021/ja00532a041
PDF
Mechanism-based enzyme inactivation using an allyl sulfoxide-allyl sulfenate ester rearrangement
Michael Johnston, Ronald Raines, Christopher Walsh, and Raymond A. Firestone
pp 4241 - 4250; DOI:
10.1021/ja00532a042
PDF
Phosphinomethyl complexes of zirconium(IV): synthesis, reduction, and complexation to a second transition metal
Neil E. Schore and Hakon Hope
pp 4251 - 4253; DOI:
10.1021/ja00532a043
PDF
Stable single-compartment vesicles with zwitterionic amphiphile involving an amino acid residue
Yukito Murakami, Akio Nakano, and Kiyoshi Fukuya
pp 4253 - 4254; DOI:
10.1021/ja00532a044
PDF
Raman phonon spectroscopy of solid-state reactions: thermal rearrangement of methyl p-dimethylaminobenzenesulfonate in solid state
Kaddi Dwarakanath and Paras N. Prasad
pp 4254 - 4256; DOI:
10.1021/ja00532a045
PDF
Hydrolysis of two acyl activated esters in water-rich 2-butoxyethanol-water mixtures. Effects of hydrophobic interactions on enthalpies, entropies, and heat capacities of activation
Herman A. J. Holterman and Jan B. F. N. Engberts
pp 4256 - 4257; DOI:
10.1021/ja00532a046
PDF
Formation of vitamin D3 in synthetic lipid multibilayers. A model for epidermal photosynthesis
Robert M. Moriarty, Robert N. Schwartz, Chyi Lee, and Veronica Curtis
pp 4257 - 4259; DOI:
10.1021/ja00532a047
PDF
Longitudinal restrictions of the binding site of opsin as measured with retinal isomers and analogs
Hiroyuki Matsumoto, R. S. H. Liu, Charles J. Simmons, and Karl Seff
pp 4259 - 4262; DOI:
10.1021/ja00532a048
PDF
Total synthesis of dl-quadrone
Samuel Danishefsky, Kenward Vaughan, Robert C. Gadwood, and Kazuo Tsuzuki
pp 4262 - 4263; DOI:
10.1021/ja00532a049
PDF
Asymmetric induction in the reaction of osmium tetroxide with olefins
Steven G. Hentges and K. Barry Sharpless
pp 4263 - 4265; DOI:
10.1021/ja00532a050
PDF
Intramolecular [3 + 2] cycloaddition reactions in the indole series "The nitrile oxide route to the ergot alkaloids". 1. Chanoclavine I
Alan P. Kozikowski and Hitoshi Ishida
pp 4265 - 4267; DOI:
10.1021/ja00532a051
PDF
Binding of 5-fluoro-L-tryptophan to human serum albumin
J. T. Gerig and J. C. Klinkenborg
pp 4267 - 4268; DOI:
10.1021/ja00532a052
PDF
Reactions of superoxide with iron porphyrins in aprotic solvents. A high spin ferric porphyrin peroxo complex
Elizabeth McCandlish, Andrew R. Miksztal, Mario Nappa, Alice Q. Sprenger, Joan S. Valentine, John D. Stong, and Thomas G. Spiro
pp 4268 - 4271; DOI:
10.1021/ja00532a053
PDF
Zwitterionic adducts between a strongly electrophilic ketone and tertiary amines
Marcia L. Manion Schilling, Heinz D. Roth, and William C. Herndon
pp 4271 - 4272; DOI:
10.1021/ja00532a054
PDF
Experimental evidence for nonsquare cyclobutadiene as a chemically significant intermediate in solution
David W. Whitman and Barry K. Carpenter
pp 4272 - 4274; DOI:
10.1021/ja00532a055
PDF
Total synthesis of (.+-.)-dihydrospiniferin-1: a furanosesquiterpene with a 1,6-methano[10]annulene carbon skeleton
James A. Marshall and Raymond E. Conrow
pp 4274 - 4275; DOI:
10.1021/ja00532a056
PDF
Electron-transfer photooxygenation. 4. Photooxygenation of trans-stilbene sensitized by methylene blue
Lewis E. Manring, J. Eriksen, and C. S. Foote
pp 4275 - 4277; DOI:
10.1021/ja00532a057
PDF
A new, convenient, and efficient route to dimolybdenum(II) compounds from molybdenum oxide (MoO3)
Avi Bino and Dan Gibson
pp 4277 - 4278; DOI:
10.1021/ja00532a058
PDF
Synthesis of the slow reacting substance of anaphylaxis leukotriene C-1 from arachidonic acid
E. J. Corey, Alan E. Barton, and David A. Clark
pp 4278 - 4279; DOI:
10.1021/ja00532a059
PDF
Electronic structure of 2-Fe ferredoxin models by X.alpha. valence bond theory
Joe G. Norman, P. Barry Ryan, and Louis Noodleman
pp 4279 - 4282; DOI:
10.1021/ja00532a060
PDF
Synthesis of (.+-.)-antirhine from (.+-.)-norcamphor
Seiichi Takano, Mikoto Takahashi, and Kunio Ogasawara
pp 4282 - 4283; DOI:
10.1021/ja00532a061
PDF
2,5-Di-N-chlorothioimino-3,4-dicyanothiophene: a novel monomer of unusual molecular and solid-state structure
F. Wudl and E. T. Zellers
pp 4283 - 4284; DOI:
10.1021/ja00532a062
PDF
Book Reviews

pp 4284 - 4286; DOI:
10.1021/ja00532a600
PDF

Issue 13


Structural analysis of molecular solutions based on quasi-component distribution functions. Application to [H2CO]aq at 25.degree.C
P. K. Mehrotra and David L. Beveridge
pp 4287 - 4294; DOI:
10.1021/ja00533a001
PDF
A model equation for the analysis of noncovalent intermolecular interactions
John E. Douglas and Peter A. Kollman
pp 4295 - 4302; DOI:
10.1021/ja00533a002
PDF
Nuclear spin polarization effects in radical ion pair reactions. Recombination in the singlet and triplet state
Heinz D. Roth and Marcia L. Manion Schilling
pp 4303 - 4310; DOI:
10.1021/ja00533a003
PDF
Chemical oscillation during the uncatalyzed reaction of aromatic compounds with bromates. 4. Stationary and moving structures in uncatalyzed oscillatory chemical reactions
Miklos Orban
pp 4311 - 4314; DOI:
10.1021/ja00533a004
PDF
Photoelectron spectra of the cyclophanes
Branka Kovac, Manijeh Mohraz, Edgar Heilbronner, Virgil Boekelheide, and Henning Hopf
pp 4314 - 4324; DOI:
10.1021/ja00533a005
PDF
Electronic structure of the transition-metal nitrates titanium tetranitrate, vanadyl trinitrate, cobalt trinitrate, and copper dinitrate. Studied by low-energy photoelectron spectroscopy and ab initio molecular orbital and scattered wave-X.alpha. calculations
C. D. Garner, Roger W. Hawksworth, Ian H. Hillier, Alistair A. MacDowell, and Martyn F. Guest
pp 4325 - 4333; DOI:
10.1021/ja00533a006
PDF
Theoretical studies on the physical properties and bonding of the 5d metal hexafluorides using the multiple scattering X.alpha. technique
J. E. Bloor and R. E. Sherrod
pp 4333 - 4340; DOI:
10.1021/ja00533a007
PDF
X-ray photoelectron spectroscopic studies on monomeric and dimeric iron porphyrins
K. M. Kadish, L. A. Bottomley, J. G. Brace, and N. Winograd
pp 4341 - 4344; DOI:
10.1021/ja00533a008
PDF
Mechanism of autoxidation of iron(II) porphyrins. Detection of a peroxo-bridged iron(III) porphyrin dimer and the mechanism of its thermal decomposition to the oxo-bridged iron(III) porphyrin dimer
Der-Hang Chin, Gerd N. La Mar, and Alan L. Balch
pp 4344 - 4350; DOI:
10.1021/ja00533a009
PDF
Electron exchange kinetics of [Fe4S4(SR)4]2-/[Fe4S4(SR)4]3- and [Fe4Se4(SR)4]2-/[Fe4Se4(SR)4]3- systems. Estimates of the intrinsic self-exchange rate constant of 4-Fe sites in oxidized and reduced ferredoxins
John G. Reynolds, Catherine L. Coyle, and R. H. Holm
pp 4350 - 4355; DOI:
10.1021/ja00533a010
PDF
Hydroboration reactions with 6-thia-nido-decaborane(11)
B. J. Meneghelli, M. Bower, N. Canter, and R. W. Rudolph
pp 4355 - 4360; DOI:
10.1021/ja00533a011
PDF
Distances of electron transfer to and from metalloprotein redox sites in reactions with inorganic complexes
A. Grant Mauk, Robert A. Scott, and Harry B. Gray
pp 4360 - 4363; DOI:
10.1021/ja00533a012
PDF
Cobalt metallacycles. 8. Preparative and kinetic studies on the reactivity of cobaltacyclopentadienes with phosphites
Katsutoshi Yasufuku, Akihiko Hamada, Katsuyuki Aoki, and Hiroshi Yamazaki
pp 4363 - 4372; DOI:
10.1021/ja00533a013
PDF
Large-ring and cyclometalated rhodium complexes from some medium-chain .alpha.,.omega.-diphosphines
Christopher Crocker, R. John Errington, Richard Markham, Christopher J. Moulton, Kevin J. Odell, and Bernard L. Shaw
pp 4373 - 4379; DOI:
10.1021/ja00533a014
PDF
Crystal structures of some cyclic phosphonium salts and their relation to the stereochemical course of base hydrolysis
Judith C. Gallucci and Robert R. Holmes
pp 4379 - 4386; DOI:
10.1021/ja00533a015
PDF
Crystal structure and absolute configuration of (1R,3S)-(-)-trans-1-benzyl-3-methyl-1-phenylphospholanium iodide. Steric course of base hydrolysis
Roberta O. Day, Steinar Husebye, Joan A. Deiters, and Robert R. Holmes
pp 4387 - 4391; DOI:
10.1021/ja00533a016
PDF
Transition-state effects in the divalent metal ion catalysis of acetal hydrolysis
Theodore J. Przystas and Thomas H. Fife
pp 4391 - 4396; DOI:
10.1021/ja00533a017
PDF
Regio- and stereoselective 1,2 Wagner-Meerwein shifts during trifluoroacetic acid catalyzed isomerization of unsymmetrically substituted tricyclo[3.2.0.02,4]heptanes
Rene Gree, Hokoon Park, and Leo A. Paquette
pp 4397 - 4403; DOI:
10.1021/ja00533a018
PDF
Catalysis of .alpha.-hydrogen exchange. 20. Stereoselective bifunctional catalysis of dedeuteration of cyclopentanone-2,2,5,5-d4 by (1R,2S,3R,4R)-3-dimethylaminomethyl-1,7,7-trimethyl-2-norbornanamine
Jack Hine, Wu-Shyong Li, and James P. Zeigler
pp 4403 - 4409; DOI:
10.1021/ja00533a019
PDF
Stereospecific synthesis of optically active benzobicyclic ring systems coordinated to tricarbonylchromium with predetermined absolute configurations
Andre Meyer and Otmar Hofer
pp 4410 - 4414; DOI:
10.1021/ja00533a020
PDF
An investigation into the electrochemical oxidation of some aromatic amines in the room-temperature molten salt system aluminum chloride-butylpyridinium chloride
J. Robinson and R. A. Osteryoung
pp 4415 - 4420; DOI:
10.1021/ja00533a021
PDF
Radical ions. 36. Structural changes accompanying the one-electron oxidation of hydrazine and its silyl derivatives
H. Bock, W. Kaim, H. Noeth, and A. Semkow
pp 4421 - 4428; DOI:
10.1021/ja00533a022
PDF
Radical ions. 37. Ionization and one-electron oxidation of electron-rich silylalkyl olefins
H. Bock and W. Kaim
pp 4429 - 4438; DOI:
10.1021/ja00533a023
PDF
Organic tellurium and selenium chemistry. Reduction of tellurides, selenides, and selenoacetals with triphenyltin hydride
Derrick L. J. Clive, Gim J. Chittattu, Vittorio Farina, William A. Kiel, Steven M. Menchen, Charles G. Russell, Alok Singh, Chi Kwong Wong, and Neville J. Curtis
pp 4438 - 4447; DOI:
10.1021/ja00533a024
PDF
Mechanism of the reaction of thiols with selenite
John L. Kice, Thomas W. S. Lee, and Shu-Teh Pan
pp 4448 - 4455; DOI:
10.1021/ja00533a025
PDF
Photochemistry of cis-fused bicyclo[4.n.0]-2,4-dienes. Ground state conformational control
William G. Dauben and Michael S. Kellogg
pp 4456 - 4463; DOI:
10.1021/ja00533a026
PDF
Monomeric methyl metaphosphate: reactions with carbonyl groups
Arnold C. Satterthwait and F. H. Westheimer
pp 4464 - 4472; DOI:
10.1021/ja00533a027
PDF
Dioxygen transfer from 4a-hydroperoxyflavin anion. 2. Oxygen transfer to the 10 position of 9-hydroxyphenanthrene anions and to 3,5-di-tert-butylcatechol anion
Shigeaki Muto and Thomas C. Bruice
pp 4472 - 4480; DOI:
10.1021/ja00533a028
PDF
Does superoxide ion oxidize catechol, .alpha.-tocopherol, and ascorbic acid by direct electron transfer?
Edward J. Nanni, Martin D. Stallings, and Donald T. Sawyer
pp 4481 - 4485; DOI:
10.1021/ja00533a029
PDF
Stable carbocations. 225. Proton and carbon-13 NMR spectroscopic study of 9-fluorenyl cations
George A. Olah, G. K. Surya Prakash, Gao Liang, Philip W. Westerman, Klaus Kunde, Jayaraman Chandrasekhar, and Paul V. R. Schleyer
pp 4485 - 4492; DOI:
10.1021/ja00533a030
PDF
Electronic control of ferroporphyrin ligand-binding kinetics
Marlene A. Stanford, James C. Swartz, Terry E. Phillips, and Brian M. Hoffman
pp 4492 - 4499; DOI:
10.1021/ja00533a031
PDF
Structure of arogenate (pretyrosine), an amino acid intermediate of aromatic biosynthesis
Lolita O. Zamir, Roy A. Jensen, B. H. Arison, A. W. Douglas, G. Albers-Schoenberg, and John R. Bowen
pp 4499 - 4504; DOI:
10.1021/ja00533a032
PDF
Quantitative evaluation of steric effects in SN2 ring closure reactions
DeLos F. DeTar and Narender P. Luthra
pp 4505 - 4512; DOI:
10.1021/ja00533a033
PDF
Ab initio mechanistic study of radical reactions. Relative reactivity of olefinic and acetylenic bonds in addition reactions
Shigeru Nagase and C. William Kern
pp 4513 - 4515; DOI:
10.1021/ja00533a034
PDF
Multiple metal-carbon bonds. 16. Tungsten-oxo alkylidene complexes as olefins metathesis catalysts and the crystal structure of W(O)(CHCMe3(PEt3)Cl2
Jeffrey H. Wengrovius, Richard R. Schrock, Melvyn Rowen Churchill, Joseph R. Missert, and Wiley J. Youngs
pp 4515 - 4516; DOI:
10.1021/ja00533a035
PDF
Intermolecular reactions of 4,4-dimethylcyclohex-2-enylidene
Gregory R. Chambers and Maitland Jones
pp 4516 - 4518; DOI:
10.1021/ja00533a036
PDF
Reaction between superoxide ion and the superoxide coordinated in a cobalt(III) complex
P. Natarajan and N. V. Raghavan
pp 4518 - 4519; DOI:
10.1021/ja00533a037
PDF
Palladium(II)-promoted cyclizations of olefinic silyl enol ethers. Preparations of .sigma.-(1-substituted 3-oxocyclopentyl)methylpalladium(II) complexes and their oxidative rearrangements
Yoshihiko Ito, Hirokazu Aoyama, and Takeo Saegusa
pp 4519 - 4521; DOI:
10.1021/ja00533a038
PDF
Structure and bonding in a phosphenium ion-metal complex, CH3NCH2CH2N(CH3)PMo(.eta.5-C5H5)(CO)2. An example of a molybdenum-phosphorus multiple bond
L. D. Hutchins, R. T. Paine, and C. F. Campana
pp 4521 - 4523; DOI:
10.1021/ja00533a039
PDF
Hydroxyphosphorane intermediates in substitution reactions at phosphorus in acyclic phosphonofluoridates: evidence from nuclear magnetic resonance
Itshak Granoth, Yoffi Segall, Daniel Waysbort, Ezra Shirin, and Haim Leader
pp 4523 - 4525; DOI:
10.1021/ja00533a040
PDF
Stereoselectivity in electron-transfer reactions
Daniel A. Geselowitz and Henry Taube
pp 4525 - 4526; DOI:
10.1021/ja00533a041
PDF
Formation of sulfinyl oxide and singlet oxygen in the reaction of thianthrene cation radical and superoxide ion
Wataru Ando, Yoshio Kabe, Shohei Kobayashi, Choichi Takyu, Akio Yamagishi, and Humio Inaba
pp 4526 - 4528; DOI:
10.1021/ja00533a042
PDF
Aromatic protonation. 6. The rearranged ion of monoprotonated 1,6-methano[10]annulene. Evidence for the presence of a cyclopropylcarbinyl cation moiety
Koop Lammertsma and Hans Cerfontain
pp 4528 - 4529; DOI:
10.1021/ja00533a043
PDF
Formation of methane and ethane by reduction of carbon monoxide coordinated through both carbon and oxygen on Mg[CpFe(CO)2]2.4THF
Andrew Wong, Martha Harris, and Jim D. Atwood
pp 4529 - 4531; DOI:
10.1021/ja00533a044
PDF
Oxygen chiral phosphodiesters. 1. Synthesis and configurational analysis of cyclic [18O]-2'-deoxyadenosine 3',5'-monophosphate
John A. Gerlt and Jeffrey A. Coderre
pp 4531 - 4533; DOI:
10.1021/ja00533a045
PDF
Stereospecific synthesis of cyclic adenosine 3',5'-(SP)-[18O]phosphate
Janina Baraniak, Krystyna Lesiak, Marek Sochacki, and Wojciech J. Stec
pp 4533 - 4534; DOI:
10.1021/ja00533a046
PDF
A method for the preparation of unesterified acyl phosphates via stannyl phosphate intermediates
Kazuo Yamaguchi, Takashi Kamimura, and Tsujiaki Hata
pp 4534 - 4536; DOI:
10.1021/ja00533a047
PDF
Reaction mechanism of hydroboration. Ab initio MO study on the C2H4 + BH3 reaction
Shigeru Nagase, N. K. Ray, and Keiji Morokuma
pp 4536 - 4537; DOI:
10.1021/ja00533a048
PDF
Peptide synthesis using unprotected amino acids and novel imidoyl halide reagents
A. F. Hegarty and D. G. McCarthy
pp 4537 - 4538; DOI:
10.1021/ja00533a049
PDF
Monomeric molybdenum oxo complexes with tetradentate aromatic aminothiols. Model redox systems for molybdenum enzymes
J. T. Spence, M. Minelli, and P. Kroneck
pp 4538 - 4541; DOI:
10.1021/ja00533a050
PDF
Metal clusters. 25. A uniquely bonded C-H group and reactivity of a low-coordinate carbidic carbon atom
M. Tachikawa and E. L. Muetterties
pp 4541 - 4542; DOI:
10.1021/ja00533a051
PDF
Fischer-Tropsch chemistry: structure of a seminal .eta.2-CH cluster derivative, HFe4(.eta.2-CH)(CO)12
Mark A. Beno, Jack M. Williams, M. Tachikawa, and E. L. Muetterties
pp 4542 - 4544; DOI:
10.1021/ja00533a052
PDF
Applications of bridgehead alkenes to organic synthesis. Regio- and stereochemical control in the Diels-Alder route to polyfunctional cyclohexenes and cyclohexanes
Kenneth J. Shea, Philip S. Beauchamp, and Ronald S. Lind
pp 4544 - 4546; DOI:
10.1021/ja00533a053
PDF
Investigation of crystalline naphthazarin B by carbon-13 NMR spectroscopy using "magic angle" spinning techniques and by x-ray diffraction: evidence for a dynamic disordered structure
Wen-I. Shiau, Eileen N. Duesler, Iain C. Paul, David Y. Curtin, William G. Blann, and Colin A. Fyfe
pp 4546 - 4548; DOI:
10.1021/ja00533a054
PDF
A new procedure for the stereoselective synthesis of (Z)-2-alkenylsilanes and -tins and their application to erythro-selective synthesis of .beta.-alkyl alcohol derivatives
Hidetaka Yatagai, Yoshinori Yamamoto, and Kazuhiro Maruyama
pp 4548 - 4550; DOI:
10.1021/ja00533a055
PDF
.beta.'-Lithiation of .alpha.,.beta.-unsaturated secondary amides
Peter Beak and Dale J. Kempf
pp 4550 - 4551; DOI:
10.1021/ja00533a056
PDF
Antitumor agents. Synthesis of novel cis-palladium complexes and their action on supercoiled DNA
George R. Newkome, Masayoshi Onishi, Wallace E. Puckett, and Walter A. Deutsch
pp 4551 - 4552; DOI:
10.1021/ja00533a057
PDF
Additions and Corrections - Photophysical Investigation of Chiral Recognition in Crown Ethers
Pietro Tundo, and Janos H. Fendler
pp 4553 - 4553; DOI:
10.1021/ja00533a600
PDF
Book Reviews

pp 4553 - 4554; DOI:
10.1021/ja00533a601
PDF

Issue 14


Bridged and unbridged M2L10 complexes
Sason Shaik, Roald Hoffmann, C. Richard Fisel, and Richard H. Summerville
pp 4555 - 4572; DOI:
10.1021/ja00534a001
PDF
Effects of basis set and configuration interaction on the electronic structure of methyllithium, with comments on the nature of the carbon-lithium bond
Glenn D. Graham, Dennis S. Marynick, and William N. Lipscomb
pp 4572 - 4578; DOI:
10.1021/ja00534a002
PDF
Molecular orbital and spectroscopic studies of triple bonds between transition-metal atoms. 1. The d3-d3 Mo2L6 compounds (L = OR, NR2, CH2R)
Bruce E. Bursten, F. Albert Cotton, Jennifer C. Green, Elaine A. Seddon, and George G. Stanley
pp 4579 - 4588; DOI:
10.1021/ja00534a003
PDF
Heavy metal-nucleotide interactions. 14. Raman difference spectrophotometric studies of competitive reactions in mixtures of four nucleotides with electrophiles. Factors governing selectivity in the binding reactions
Mary R. Moller, Michael A. Bruck, Timothy O'Connor, Frank J. Armatis, Edward A. Knolinski, Nikolaus Kottmair, and R. Stuart Tobias
pp 4589 - 4598; DOI:
10.1021/ja00534a004
PDF
CIDNP-detected nuclear resonance of transient radicals in pulse radiolysis
A. D. Trifunac and W. T. Evanochko
pp 4598 - 4601; DOI:
10.1021/ja00534a005
PDF
Griffith model bonding in dioxygen complexes of manganese porphyrins
Louise Karle Hanson and Brian M. Hoffman
pp 4602 - 4609; DOI:
10.1021/ja00534a006
PDF
Oxygen-18 isotope effect in carbon-13 nuclear magnetic resonance spectroscopy. 2. The effect of structure
John M. Risley and Robert L. Van Etten
pp 4609 - 4614; DOI:
10.1021/ja00534a007
PDF
Classification of molecular symmetry by framework groups
J. A. Pople
pp 4615 - 4622; DOI:
10.1021/ja00534a008
PDF
Interpretation of temperature-dependent ESR spectra of peroxy polyethylene radicals in urea-polyethylene complexes
Shulamith Schlick and Larry Kevan
pp 4622 - 4626; DOI:
10.1021/ja00534a009
PDF
Ultraviolet photoelectron studies of the ground-state electronic structure and gas-phase tautomerism of purine and adenine
J. Lin, C. Yu, S. Peng, I. Akiyama, K. Li, Li Kao Lee, and P. R. LeBreton
pp 4627 - 4631; DOI:
10.1021/ja00534a010
PDF
A theoretical investigation on the model Wittig reaction PH3CH2 + CH2O .fwdarw. PH3O + C2H4
R. Hoeller and H. Lischka
pp 4632 - 4635; DOI:
10.1021/ja00534a011
PDF
Electron transfer in the quenching of triplet methylene blue by complexes of iron(II)
Takeshi Ohno and Norman N. Lichtin
pp 4636 - 4643; DOI:
10.1021/ja00534a012
PDF
Chemical oscillations and instabilities. 39. A generalized mechanism for bromate-driven oscillators controlled by bromide
Richard M. Noyes
pp 4644 - 4649; DOI:
10.1021/ja00534a013
PDF
Diffusional charge transport through ultrathin films of radiofrequency plasma polymerized vinylferrocene at low temperature
P. Daum, J. R. Lenhard, D. Rolison, and Royce W. Murray
pp 4649 - 4653; DOI:
10.1021/ja00534a014
PDF
Microemulsion systems studied by positron annihilation techniques
Ali Boussaha, Belkacem Djermouni, Luz Alicia Fucugauchi, and Hans J. Ache
pp 4654 - 4658; DOI:
10.1021/ja00534a015
PDF
Solid-state dehydration of (o-hydroxyaryl)diphenylmethanols. Crystal and molecular structures of [1-(2-hydroxyphenyl)]diphenylmethanol and of [1-(2-hydroxynaphthyl)]diphenylmethanol
Terry W. Lewis, Eileen N. Duesler, Ruth B. Kress, David Y. Curtin, and Iain C. Paul
pp 4659 - 4664; DOI:
10.1021/ja00534a016
PDF
An investigation of ionic hydration effects in perfluorosulfonate ionomers by Fourier transform infrared spectroscopy
S. R. Lowry and K. A. Mauritz
pp 4665 - 4667; DOI:
10.1021/ja00534a017
PDF
Allenic anions. Structure and inversion barrier of H2CCCH-
John K. Wilmshurst and Clifford E. Dykstra
pp 4668 - 4672; DOI:
10.1021/ja00534a018
PDF
Isotope exchange reactions of hydroxy(1-) or hydroxy-d(1-) ions with hydrogen and water
M. Meot-Ner Mautner, J. R. Lloyd, E. P. Hunter, W. A. Agosta, and F. H. Field
pp 4672 - 4676; DOI:
10.1021/ja00534a019
PDF
Photoelectrochemical behavior of n-gallium arsenide electrodes in ambient-temperature molten-salt electrolytes
P. Singh, K. Rajeshwar, J. DuBow, and R. Job
pp 4676 - 4681; DOI:
10.1021/ja00534a020
PDF
The high-spin (5T2) .dblharw. low-spin (1A1) transition in solid bis(1,10-phenanthroline-2-carbaldehyde phenylhydrazone) iron(II) diperchlorate. Simultaneous change of molecular spin state and crystallographic structure
E. Koenig, G. Ritter, W. Irler, and H. A. Goodwin
pp 4681 - 4687; DOI:
10.1021/ja00534a021
PDF
Phase-transfer-catalyzed nucleophilic reactions of hydroxide ions at metal-bound carbon monoxide centers
Donald J. Darensbourg, Brenda J. Baldwin, and Joseph A. Froelich
pp 4688 - 4694; DOI:
10.1021/ja00534a022
PDF
Synthesis and electronic and redox properties of "double-cubane" cluster complexes containing molybdenum iron sulfide (MoFe3S4) and tungsten iron sulfide (WFe3S4) cores
Thomas E. Wolff, Philip P. Power, Richard B. Frankel, and R. H. Holm
pp 4694 - 4703; DOI:
10.1021/ja00534a023
PDF
Accurate redetermination of crystal structure of dehydrated zeolite A. Absence of near zero coordination of sodium. Refinement of silicon,aluminum-ordered superstructure
Joseph J. Pluth and Joseph V. Smith
pp 4704 - 4708; DOI:
10.1021/ja00534a024
PDF
Structure of the 7-phenylnorbornyl carbanion. A pyramidal organolithium and planar organopotassium
P. Robert Peoples and John B. Grutzner
pp 4709 - 4715; DOI:
10.1021/ja00534a025
PDF
Isolation of an unusual deprotonated form of o-aminobenzylidene: an intermediate in the template condensation of o-aminobenzaldehyde with platinum(II)
Mark D. Timken, Robert I. Sheldon, William G. Rohly, and Kristin Bowman Mertes
pp 4716 - 4720; DOI:
10.1021/ja00534a026
PDF
An inelastic electron-tunneling spectroscopic study of ruthenium carbonyl (Ru3(CO)12) adsorbed on an aluminum oxide surface
W. M. Bowser and W. H. Weinberg
pp 4720 - 4724; DOI:
10.1021/ja00534a027
PDF
Acid hydrolysis of ethyl glycinate complex of pentaammineruthenium(III)
Andrew Yeh and Henry Taube
pp 4725 - 4729; DOI:
10.1021/ja00534a028
PDF
Allylic alkylation. Palladium-catalyzed substitutions of allylic carboxylates. Stereo- and regiochemistry
Barry M. Trost and Thomas R. Verhoeven
pp 4730 - 4743; DOI:
10.1021/ja00534a029
PDF
Cyclization catalyzed by palladium(0). Initial studies and macrolide formation
Barry M. Trost and Thomas R. Verhoeven
pp 4743 - 4763; DOI:
10.1021/ja00534a030
PDF
Mechanism of the ozonolysis of ethylene in the liquid phase
Gerald D. Fong and Robert L. Kuczkowski
pp 4763 - 4768; DOI:
10.1021/ja00534a031
PDF
Aromatic substitution in the gas phase. A comparative study of the alkylation of benzene and toluene with C3H7+ ions from the protonation of cyclopropane and propene
Marina Attina, Fulvio Cacace, and Pierluigi Giacomello
pp 4768 - 4772; DOI:
10.1021/ja00534a032
PDF
"1,4" Alkyl migrations in Fischer indole cyclizations
Bernard Miller and Edward R. Matjeka
pp 4772 - 4780; DOI:
10.1021/ja00534a033
PDF
Carbon isotope effects in proton abstraction from 2-nitropropane-2-14C by pyridines. The contribution of tunneling
Joe C. Wilson, Inger Kaellsson, and William H. Saunders
pp 4780 - 4784; DOI:
10.1021/ja00534a034
PDF
Optical rotary dispersion studies. 129. Conformational isotope effects and octant contributions of methyl-d3 and methyl (carbon-13) groups in cyclohexanone
Shy-Fuh Lee, Mark Edgar, Chwang Siek Pak, Guenter Barth, and Carl Djerassi
pp 4784 - 4790; DOI:
10.1021/ja00534a035
PDF
Heterogeneous rates of electron transfer. Application of cyclic voltammetric techniques to irreversible electrochemical processes
R. J. Klingler and J. K. Kochi
pp 4790 - 4798; DOI:
10.1021/ja00534a036
PDF
Intramolecular electron transfer in the anion radicals of nitrobenzyl halides
P. Neta and D. Behar
pp 4798 - 4802; DOI:
10.1021/ja00534a037
PDF
Fluorescer-enhanced chemiluminescence of a cyclic peroxalate via electron exchange
Waldemar Adam, Carmen Cadilla, Omar Cueto, and Luis O. Rodriguez
pp 4802 - 4805; DOI:
10.1021/ja00534a038
PDF
Bicyclic azoalkanes via urazoles derived from cycloaddition of N-phenyl-1,2,4-triazoline-3,5-dione with strained bicycloalkenes
Waldemar Adam, Ottorino De Lucchi, and Ihsan Erden
pp 4806 - 4809; DOI:
10.1021/ja00534a039
PDF
Modified crown ether catalysts. 3. Structural parameters affecting phase transfer catalysis by crown ethers and a comparison of the effectiveness of crown ethers to that of other phase transfer catalysts
P. E. Stott, J. S. Bradshaw, and W. W. Parish
pp 4810 - 4815; DOI:
10.1021/ja00534a040
PDF
Formation and hydrolysis of lactones of phenolic acids
Michael Caswell and Gaston L. Schmir
pp 4815 - 4821; DOI:
10.1021/ja00534a041
PDF
Chromopeptides from phytochrome. The structure and linkage of the PR form of the phytochrome chromophore
J. Clark Lagarias and Henry Rapoport
pp 4821 - 4828; DOI:
10.1021/ja00534a042
PDF
Kinetics of thiamine cleavage by bisulfite ion
Daniel R. Doerge and Lloyd L. Ingraham
pp 4828 - 4830; DOI:
10.1021/ja00534a043
PDF
C3H5+ isomers: evidence for the existence of long-lived allyl and 2-propenyl cations in the gas phase
Michael T. Bowers, Liu Shuying, Petranella Kemper, Rod Stradling, Hugh Webb, Donald H. Aue, James R. Gilbert, and Keith R. Jennings
pp 4830 - 4832; DOI:
10.1021/ja00534a044
PDF
A tricopper(II) complex containing a triply bridging carbonate group
Gary Kolks, Stephen J. Lippard, and Joseph V. Waszczak
pp 4832 - 4833; DOI:
10.1021/ja00534a045
PDF
Proton NMR characterization of heme rotational disorder in reconstituted horseradish peroxidase
Gerd N. La Mar, Jeffrey S. De Ropp, Kevin M. Smith, and Kevin C. Langry
pp 4833 - 4835; DOI:
10.1021/ja00534a046
PDF
Structure of bis(phthalocyaninato)neodymium(III)
K. Kasuga, M. Tsutsui, R. C. Petterson, K. Tatsumi, N. Van Opdenbosch, G. Pepe, and E. F. Meyer
pp 4835 - 4836; DOI:
10.1021/ja00534a047
PDF
The importance of solvation on the gas-phase proton-transfer reaction between cyclopentadienyl anion and alcohols
Richard N. McDonald, A. Kasem Chowdhury, and D. W. Setser
pp 4836 - 4838; DOI:
10.1021/ja00534a048
PDF
Synthesis of a dibenzophosphonin
Eric D. Middlemas and Louis D. Quin
pp 4838 - 4839; DOI:
10.1021/ja00534a049
PDF
Cobalt mediated cyclizations of linear achiral diyenes. A one step construction of complexed chiral polycycles
Ethan D. Sternberg and K. Peter C. Vollhardt
pp 4839 - 4841; DOI:
10.1021/ja00534a050
PDF
Stereochemistry of the thermal and photochemical rearrangement of 7,7-dimethylbicyclo[4.1.1]octa-2,4-diene to 8,8-dimethylbicyclo[5.1.0]octa-2,4-diene
Weston Thatcher Borden, Jon Gun Lee, and Stanley D. Young
pp 4841 - 4843; DOI:
10.1021/ja00534a051
PDF
Magnetic field and magnetic isotope effects on cage reactions in micellar solutions
Nicholas J. Turro, Ming-Fea Chow, Chao-Jen Chung, Gregory C. Weed, and Bernhard Kraeutler
pp 4843 - 4845; DOI:
10.1021/ja00534a052
PDF
.alpha.-Fluorination of carbonyl compounds with trifluoromethyl hypofluorite
W. J. Middleton and E. M. Bingham
pp 4845 - 4846; DOI:
10.1021/ja00534a053
PDF
Proton and nitrogen-14 electron-nuclear double resonance of oxovanadium(IV) porphyrin in solid solution
H. Van Willigen, C. F. Mulks, A. Bouhaouss, M. Ferhat, and A. H. Roufosse
pp 4846 - 4848; DOI:
10.1021/ja00534a054
PDF
Thermal and photochemical smiles rearrangements of .beta.-(nitrophenoxy)ethylamines
Gene G. Wubbels, Ann M. Halverson, and Joe D. Oxman
pp 4848 - 4849; DOI:
10.1021/ja00534a055
PDF
Natural abundance carbon-13-carbon-13 coupling observed via double-quantum coherence
Ad Bax, Ray Freeman, and Stewart P. Kempsell
pp 4849 - 4851; DOI:
10.1021/ja00534a056
PDF
Electrochemistry of vitamin B12. 6. Diaquocobinamide
Doris Lexa, Jean Michel Saveant, and Josiane Zickler
pp 4851 - 4852; DOI:
10.1021/ja00534a057
PDF
Allosteric effects. Remote control of ion transport selectivity
J. Rebek and R. V. Wattley
pp 4853 - 4854; DOI:
10.1021/ja00534a058
PDF

Issue 15


Solvent-dependent conformational distributions of some dipeptides
Vincent Madison and Kenneth D. Kopple
pp 4855 - 4863; DOI:
10.1021/ja00535a001
PDF
The laser induced fluorescence spectrum of the sym-trichlorotrifluorobenzene radical cation in the gas phase
T. J. Sears, Terry A. Miller, and V. E. Bondybey
pp 4864 - 4866; DOI:
10.1021/ja00535a002
PDF
Phosphorescence and delayed fluorescence of 1-chloronaphthalene in micellar solutions
Nicholas J. Turro and Masayuki Aikawa
pp 4866 - 4870; DOI:
10.1021/ja00535a003
PDF
Negative ion states of 1,3-cycloalkadienes
Judith C. Giordan, Michael R. McMillan, John H. Moore, and Stuart W. Staley
pp 4870 - 4872; DOI:
10.1021/ja00535a004
PDF
Electron spectroscopic investigations of the influence of initial- and final-state effects on electronegativity
E. J. Aitken, M. K. Bahl, K. D. Bomben, J. K. Gimzewski, G. S. Nolan, and T. D. Thomas
pp 4873 - 4879; DOI:
10.1021/ja00535a005
PDF
Liquid crystalline phases of the sodium decylsulfate/decanol/water system. Nematic-nematic and cholesteric-cholesteric phase transitions
L. J. Yu and A. Saupe
pp 4879 - 4883; DOI:
10.1021/ja00535a006
PDF
Self-inverse and nonself-inverse degenerate isomerizations
James G. Nourse
pp 4883 - 4889; DOI:
10.1021/ja00535a007
PDF
Structural studies of silicates by solid-state high-resolution silicon-29 NMR
E. Lippmaa, M. Maegi, A. Samoson, G. Engelhardt, and A. R. Grimmer
pp 4889 - 4893; DOI:
10.1021/ja00535a008
PDF
Electron paramagnetic resonance detection of carotenoid triplet states
Harry A. Frank, John D. Bolt, Silvia M. de B. Costa, and Kenneth Sauer
pp 4893 - 4898; DOI:
10.1021/ja00535a009
PDF
A thermodynamic derivation of the cross-relations for rates of electron-transfer reactions
M. A. Ratner and R. D. Levine
pp 4898 - 4900; DOI:
10.1021/ja00535a010
PDF
Matrix photoionization and radiolysis of boron trihalides. Infrared and ultraviolet spectra of boron trichloride(1+) and boron tribromide(1+) and infrared spectra of boron dichloride and boron dibromide
J. Houston Miller and Lester Andrews
pp 4900 - 4906; DOI:
10.1021/ja00535a011
PDF
Ab initio calculations and carbon-13 NMR study on the methoxymethyl cation
D. Farcasiu and J. A. Horsley
pp 4906 - 4911; DOI:
10.1021/ja00535a012
PDF
Reaction of molecular oxygen with pyridinehemochromes in aqueous solution
Jack Emert, William Pietro, and Runold Ambrose
pp 4912 - 4916; DOI:
10.1021/ja00535a013
PDF
Reaction of superoxide radicals with copper(II)-histidine complexes
Judith Weinstein and Benon H. J. Bielski
pp 4916 - 4919; DOI:
10.1021/ja00535a014
PDF
Reactions of superoxide anion with copper(II) salicylate complexes
Chi-Lin O'Young and Stephen J. Lippard
pp 4920 - 4924; DOI:
10.1021/ja00535a015
PDF
Characterization of reversible reactions of isocyanides with molybdenum dithiolate complexes
Douglas J. Miller and M. Rakowski DuBois
pp 4925 - 4928; DOI:
10.1021/ja00535a016
PDF
Low-temperature crystal and molecular structure of tetracarbonyl[2-bromoheptahydrotriborato(1-)]manganese, (CO)4MnB3H7Br, and a proton NMR study of the kinetics of its intramolecular hydrogen exchange in solution
Michael W. Chen, Joseph C. Calabrese, Donald F. Gaines, and David F. Hillenbrand
pp 4928 - 4933; DOI:
10.1021/ja00535a017
PDF
Mechanisms of 1,1-reductive elimination from palladium
Arlene Gillie and J. K. Stille
pp 4933 - 4941; DOI:
10.1021/ja00535a018
PDF
Hydrogen-transfer reactions catalyzed by low-valent, tertiary phosphine complexes of zirconium. Molecular structure of hydrido(.eta.5-cyclooctadienyl)bis[1,2-bis(dimethylphosphino)ethane]zirconium
M. B. Fischer, E. J. James, T. J. McNeese, S. C. Nyburg, B. Posin, W. Wong-Ng, and S. S. Wreford
pp 4941 - 4947; DOI:
10.1021/ja00535a019
PDF
Reversible metal-to-metal methyl transfer in .eta.5-cyclopentadienyl(triphenylphosphine)dimethylcobalt(III)
Henry E. Bryndza, Eric R. Evitt, and Robert G. Bergman
pp 4948 - 4951; DOI:
10.1021/ja00535a020
PDF
Tautomeric catecholate-semiquinone interconversion via metal-ligand electron transfer. Structural, spectral, and magnetic properties of (3,5-di-tert-butylcatecholato)(3,5-di-tert-butylsemiquinone)(bipyridyl)cobalt(III), a complex containing mixed-valence organic ligands
Robert M. Buchanan and Cortlandt G. Pierpont
pp 4951 - 4957; DOI:
10.1021/ja00535a021
PDF
F-Ethylamine and F-ethylimine
Ramesh C. Kumar and Jean'ne M. Shreeve
pp 4958 - 4959; DOI:
10.1021/ja00535a022
PDF
.pi.-Arene complexes of nickel(II). Synthesis (from metal atoms) of (.pi.-arene)bis(pentafluorophenyl)nickel(II). Properties, .pi.-arene lability, and chemistry
Robert G. Gastinger, Bruce B. Anderson, and Kenneth J. Klabunde
pp 4959 - 4966; DOI:
10.1021/ja00535a023
PDF
Electron donor and acceptor induced fluorescence quenching and charge carrier photogeneration in X-metal-free phthalocyanine
Rafik O. Loutfy and E. Roland Menzel
pp 4967 - 4970; DOI:
10.1021/ja00535a024
PDF
.alpha.-Lithiosilanes. 4. Silaethylene cycloadditions with conjugated dienes
Paul Ronald Jones, Thomas F. O. Lim, and Richard A. Pierce
pp 4970 - 4973; DOI:
10.1021/ja00535a025
PDF
Palladium-assisted alkylation of olefins
Louis S. Hegedus, Robert E. Williams, Michael A. McGuire, and Tamio Hayashi
pp 4973 - 4979; DOI:
10.1021/ja00535a026
PDF
Palladium-assisted carboacylation of olefins
Louis S. Hegedus and W. H. Darlington
pp 4980 - 4983; DOI:
10.1021/ja00535a027
PDF
Bimanes. 5. Synthesis and properties of syn- and anti-1,5-diazabicyclo[3.3.0]octadienediones (9,10-dioxabimanes)
Edward M. Kosower and Barak Pazhenchevsky
pp 4983 - 4993; DOI:
10.1021/ja00535a028
PDF
Spin trapping. Kinetics of the reaction of superoxide and hydroxyl radicals with nitrones
Eli Finkelstein, Gerald M. Rosen, and Elmer J. Rauckman
pp 4994 - 4999; DOI:
10.1021/ja00535a029
PDF
Oxidation of hydroquinone silyl ethers to quinones
Ray F. Stewart and Larry L. Miller
pp 4999 - 5004; DOI:
10.1021/ja00535a030
PDF
Silicon in Synthesis. 10. The (Trimethylsilyl)allyl Anion: A .beta.-Acyl Anion Equivalent for the Conversion of Aldehydes and Ketones into .gamma.-Lactones
Ed Ehlinger, and Phillip Magnus
pp 5004 - 5011; DOI:
10.1021/ja00535a600
PDF
Gas-phase reactions of anions with substituted silanes
C. H. DePuy, Veronica M. Bierbaum, L. A. Flippin, Joseph J. Grabowski, Gary K. King, Robert J. Schmitt, and S. A. Sullivan
pp 5012 - 5015; DOI:
10.1021/ja00535a031
PDF
Bond fixation in annulenes. 8. Assessment of the ring inversion and bond shifting barriers in 1,2,3-trimethylcyclooctatetraene. Resolution, absolute configuration, and circular dichroic behavior of an [8]annulene hydrocarbon
Leo A. Paquette and John M. Gardlik
pp 5016 - 5025; DOI:
10.1021/ja00535a032
PDF
Bond fixation in annulenes. 9. Equalization of ring inversion and bond shifting energetics in 1,2,3,4-tetramethylcyclooctatetraene. Asymmetric synthesis direct resolution, and absolute configuration of the optically active hydrocarbon
Leo A. Paquette, John M. Gardlik, Larry K. Johnson, and Kevin J. McCullough
pp 5026 - 5032; DOI:
10.1021/ja00535a033
PDF
Bond fixation in annulenes. 10. Utilization of buttressing effects for comparing ring inversion and .pi. bond shifting transition state geometries in cyclooctatetraenes
Leo A. Paquette and John M. Gardlik
pp 5033 - 5035; DOI:
10.1021/ja00535a034
PDF
Reactions of 4a-peroxides and 4a-pseudobases of N10- and N5-phenethylflavins
Masaki Iwata, Thomas C. Bruice, H. L. Carrell, and Jenny P. Glusker
pp 5036 - 5044; DOI:
10.1021/ja00535a035
PDF
Diazo coupling reactions with a functional micellar reagent. Circumvention of Hartley's rules
Robert A. Moss and Chaim Rav-Acha
pp 5045 - 5047; DOI:
10.1021/ja00535a036
PDF
Polyanthraquinocyclopropanes, dianthraquinocyclopropanone, and dianthraquinoethylene. Synthesis and properties
Judith L. Benham, Robert West, and John A. T. Norman
pp 5047 - 5053; DOI:
10.1021/ja00535a037
PDF
Oxidation and reduction properties of anthraquinocyclopropanes and anthraquinocyclopropenes
Judith L. Benham and Robert West
pp 5054 - 5058; DOI:
10.1021/ja00535a038
PDF
Chemiluminescent thermolysis of .alpha.-peroxylactones
Nicholas J. Turro and Ming-Fea Chow
pp 5058 - 5064; DOI:
10.1021/ja00535a039
PDF
Methylketene. Ion chemistry and proton affinity
Mary Alison Armitage, Michael Joseph Higgins, Errol George Lewars, and Raymond Evans March
pp 5064 - 5068; DOI:
10.1021/ja00535a040
PDF
Crystal and molecular structure of 1,4,7-trithiacyclononane
Richard S. Glass, George S. Wilson, and William N. Setzer
pp 5068 - 5069; DOI:
10.1021/ja00535a041
PDF
Molecular, electronic, and crystal structure of naphtho[1,8-cd:4,5-c'd']bis[1,2,6]selenadiazine
Alfred Gieren, Viktor Lamm, Robert C. Haddon, and Martin L. Kaplan
pp 5070 - 5073; DOI:
10.1021/ja00535a042
PDF
Structures of some bicyclic and tricyclic phosphoranes in solution
Donald B. Denney, Dorothy Z. Denney, Philip J. Hammond, Chialang Huang, and Kuo-Shu Tseng
pp 5073 - 5077; DOI:
10.1021/ja00535a043
PDF
Stereoelectronic effects in the reactions of epimeric 2-aryloxy-2-oxy-1,3,2-dioxaphosphorinanes and oxazaphosphorinanes
David G. Gorenstein, Robert Rowell, and John Findlay
pp 5077 - 5081; DOI:
10.1021/ja00535a044
PDF
A carbon-13 nuclear magnetic resonance spectroscopic investigation of the Kiliani reaction
Richard M. Blazer and Thomas W. Whaley
pp 5082 - 5085; DOI:
10.1021/ja00535a045
PDF
Intramolecular Diels-Alder route to angularly substituted perhydrophenanthrenes. Synthesis of (.+-.)-fichtelite
Douglass F. Taber and Samir A. Saleh
pp 5085 - 5088; DOI:
10.1021/ja00535a046
PDF
The asbestinins, a novel class of diterpenes from the gorgonian Briareum asbestinum
Donald B. Stierle, Brad Carte, D. John Faulkner, Bruce Tagle, and Jon Clardy
pp 5088 - 5092; DOI:
10.1021/ja00535a047
PDF
Activation of coordinated carbon monoxide toward alkyl and aryl migration (carbon monoxide insertion) by molecular Lewis acids and x-ray structure of the reactive intermediate
Susan Beda Butts, Steven H. Strauss, Elizabeth M. Holt, Rebecca E. Stimson, Nathaniel W. Alcock, and Duward F. Shriver
pp 5093 - 5100; DOI:
10.1021/ja00535a048
PDF
Synthesis and structure of the first binuclear methylene-bridged cobalt complex, bis(.eta.5-pentamethylcyclopentadienyl)-.mu.-methylene-.mu.-carbonyl-dicobalt: a surprising role for the lithium enolate of acetaldehyde
Thomas R. Halbert, Michael E. Leonowicz, and Daniel J. Maydonovitch
pp 5101 - 5102; DOI:
10.1021/ja00535a049
PDF
Mo2S42+ core: new syntheses, new complexes, and electrochemical diversity
Kenneth F. Miller, Alice E. Bruce, James L. Corbin, Scot Wherland, and Edward I. Stiefel
pp 5102 - 5104; DOI:
10.1021/ja00535a050
PDF
A quintet-state triplet-triplet radical pair
H. Murai, M. Torres, and O. P. Strausz
pp 5104 - 5106; DOI:
10.1021/ja00535a051
PDF
Intense satellites in the N 1s x-ray photoelectron spectra of certain metalloporphyrins
S. Muralidharan and R. G. Hayes
pp 5106 - 5107; DOI:
10.1021/ja00535a052
PDF
Dogger Bank itch. The allergen is (2-hydroxyethyl)dimethylsulfoxonium ion
Joergen S. Carle and Carsten Christophersen
pp 5107 - 5108; DOI:
10.1021/ja00535a053
PDF
Continuous-wave carbon dioxide laser-induced decomposition of phosgene in boron trichloride: a thermal reaction
Clyde Riley and Loretta Maclean
pp 5108 - 5109; DOI:
10.1021/ja00535a054
PDF
Electric-field orientation of poly(.alpha.-L-glutamic acid) in various conformations as studied by reversing-pulse electric birefringence
Kiwamu Yamaoka, Tsuyoshi Ichibakase, Kazuyoshi Ueda, and Koichiro Matsuda
pp 5109 - 5110; DOI:
10.1021/ja00535a055
PDF
Azulene-naphthalene rearrangement. Involvement of 1-phenylbuten-3-ynes and 4-phenyl-1,3-butadienylidene
Juergen Becker, Curt Wentrup, Ellen Katz, and Klaus Peter Zeller
pp 5110 - 5112; DOI:
10.1021/ja00535a056
PDF
Surface-induced alkyl migration reactions in metal carbonyls
F. Correa, R. Nakamura, R. E. Stimson, R. L. Burwell, and D. F. Shriver
pp 5112 - 5114; DOI:
10.1021/ja00535a057
PDF
Mechanism of metathesis and epoxidation in chromium and molybdenum complexes containing methyl-oxo bonds
Anthony K. Rappe and William A. Goddard
pp 5114 - 5115; DOI:
10.1021/ja00535a058
PDF
Resolution of underivatized amino acids by reversed-phase chromatography
E. Gil-Av, A. Tishbee, and P. E. Hare
pp 5115 - 5117; DOI:
10.1021/ja00535a059
PDF
Hypovalent radicals. 7. Gas-phase generation of phenylnitrene anion radical and its reaction with phenyl azide
Richard N. McDonald and A. Kasem Chowdhury
pp 5118 - 5119; DOI:
10.1021/ja00535a060
PDF
Applications of light-induced electron-transfer and hydrogen-abstraction processes: photoelectrochemical production of hydrogen from reducing radicals
K. Chandrasekaran and David G. Whitten
pp 5119 - 5120; DOI:
10.1021/ja00535a061
PDF
Propargylsilane and (trimethylsilyl)alkyne terminator groups. Formation of an exocyclic allene in the acetolysis of 8-(trimethylsilyl)-6-octyn-2-yl tosylate
Aris D. Despo, Sai Keung Chiu, Timothy Flood, and Paul E. Peterson
pp 5120 - 5122; DOI:
10.1021/ja00535a062
PDF
Propargylsilane function as a terminator of biomimetic polyene cyclizations leading to steroids
Rudolf Schmid, Peter L. Huesmann, and William S. Johnson
pp 5122 - 5123; DOI:
10.1021/ja00535a063
PDF
Thermodynamically uphill reduction of a surface-confined N,N'-dialkyl-4,4'-bipyridinium derivative on illuminated p-type silicon surfaces
Dana C. Bookbinder and Mark S. Wrighton
pp 5123 - 5125; DOI:
10.1021/ja00535a064
PDF
Dimerization of bridgehead olefins formed from tricyclic cyclopropylidenes
Philip Warner, Suae-Chen Chang, Douglas R. Powell, and Robert A. Jacobson
pp 5125 - 5127; DOI:
10.1021/ja00535a065
PDF
Organic photochemistry: the laser vs. the lamp. The behavior of diphenylcarbene generated at high light intensities
Nicholas J. Turro, Masayuki Aikawa, Jared A. Butcher, and Gary W. Griffin
pp 5127 - 5128; DOI:
10.1021/ja00535a066
PDF
Direct lanthanide-induced-shift NMR determination of conformer populations in substituted cyclohexanones
Raymond J. Abraham, Derek J. Chadwick, Lee Griffiths, and Fernando Sancassan
pp 5128 - 5130; DOI:
10.1021/ja00535a067
PDF
Book Reviews

pp 5130 - 5136; DOI:
10.1021/ja00535a601
PDF

Issue 16


Semiconductor electrodes. 30. Spectral sensitization of the semiconductors titanium oxide (n-TiO2) and tungsten oxide (n-WO3) with metal phthalocyanines
Alain Giraudeau, Fu-Ren F. Fan, and Allen J. Bard
pp 5137 - 5142; DOI:
10.1021/ja00536a001
PDF
Semiconductor electrodes. 31. Photoelectrochemistry and photovoltaic systems with n- and p-type tungsten selenide (WSe2) in aqueous solution
Fu-Ren F. Fan, Henry S. White, Bob L. Wheeler, and Allen J. Bard
pp 5142 - 5148; DOI:
10.1021/ja00536a002
PDF
Anisotropic reorientation of nicotine in solution. A carbon-13 spin-lattice relaxation time study of molecular conformation
T. Phil Pitner, Jerry F. Whidby, and William B. Edwards
pp 5149 - 5150; DOI:
10.1021/ja00536a003
PDF
Proton affinities and photoelectron spectra of three-membered-ring heterocycles
Donald H. Aue, Hugh M. Webb, William R. Davidson, Mariano Vidal, Michael T. Bowers, Harold Goldwhite, Lawrence E. Vertal, John E. Douglas, Peter A. Kollman, and George L. Kenyon
pp 5151 - 5157; DOI:
10.1021/ja00536a004
PDF
Analysis of the rotational strength by means of configuration analysis based on the localized molecular orbitals
Kazuo Akagi, Tokio Yamabe, Hiroshi Kato, Akira Imamura, and Kenichi Fukui
pp 5157 - 5165; DOI:
10.1021/ja00536a005
PDF
Metastable decompositions of C5H10O+. ions with the oxygen on the middle carbon: a test for energy randomization
David J. McAdoo, William Farr, and Charles E. Hudson
pp 5165 - 5169; DOI:
10.1021/ja00536a006
PDF
The quinones of azulene. A theoretical prognosis
Lawrence T. Scott, Melvin D. Rozeboom, K. N. Houk, T. Fukunaga, Hans Joerg Lindner, and Klaus Hafner
pp 5169 - 5176; DOI:
10.1021/ja00536a007
PDF
Free energy of formation of sulfur trioxide in aqueous solution. Methods for determining the energy level of an unobservable intermediate
J. Peter Guthrie
pp 5177 - 5180; DOI:
10.1021/ja00536a008
PDF
A spectroscopic study of ion association. Lithium picrate in 2-butanone
W. R. Gilkerson and Angela McCaskill Roberts
pp 5181 - 5183; DOI:
10.1021/ja00536a009
PDF
Spin-dipolar contributions to the nuclear spin-spin coupling constants of molecules
Wellington S. Lee and Jerome M. Schulman
pp 5184 - 5187; DOI:
10.1021/ja00536a010
PDF
EPR studies of the molecular motion of nitroxide radicals in poly(vinyl alcohol) gels
Tokuko Watanabe, Tetsuro Yahagi, and Shizuo Fujiwara
pp 5187 - 5191; DOI:
10.1021/ja00536a011
PDF
Molecular orbital theory of the hydrogen bond. 22. 4-Monosubstituted pyridines as proton acceptors
Janet E. Del Bene
pp 5191 - 5195; DOI:
10.1021/ja00536a012
PDF
Pauling "3-electron bonds", "increased-valence", and 6-electron 4-center bonding
Richard D. Harcourt
pp 5195 - 5201; DOI:
10.1021/ja00536a013
PDF
Chemistry of organosilicon compounds. 131. Substituent effects by deuterium and alkyl groups and carbon-13 hyperfine coupling constants of cyclopentadienyl radicals as studied by electron spin resonance
Mitsuo Kira, Mieko Watanabe, and Hideki Sakurai
pp 5202 - 5207; DOI:
10.1021/ja00536a014
PDF
Bleomycin-iron complexes. Electron spin resonance study, ligand effect, and implication for action mechanism
Yukio Sugiura
pp 5208 - 5215; DOI:
10.1021/ja00536a015
PDF
Monomeric cobalt(II)-oxygen adducts of bleomycin antibiotics in aqueous solution. A new ligand type for oxygen binding and effect of axial Lewis base
Yukio Sugiura
pp 5216 - 5221; DOI:
10.1021/ja00536a016
PDF
Determination of circumstances under which the correlation of core binding energy and gas-phase basicity or proton affinity breaks down
R. S. Brown and A. Tse
pp 5222 - 5226; DOI:
10.1021/ja00536a017
PDF
Effect of polymer attachment on the equilibrium acidity of an organotransition metal hydride and an organic carboxylic acid. Synthesis and properties of a polymer-supported metal anion
Jane E. Frommer and Robert G. Bergman
pp 5227 - 5234; DOI:
10.1021/ja00536a018
PDF
Anomalous spin Hamiltonian parameters of pseudotetrahedral copper(II) complexes. ESR spectra of copper(II)-doped dichlorobis(triphenylphosphine oxide)zinc(II)
Alessandro Bencini, Dante Gatteschi, and Claudia Zanchini
pp 5234 - 5237; DOI:
10.1021/ja00536a019
PDF
Reactions of dinitrogen oxide (nitrous oxide) with dicyclopentadienyltitanium complexes including a reaction in which carbon monoxide is oxidized
Frank Bottomley, Ivan J. B. Lin, and Masao Mukaida
pp 5238 - 5242; DOI:
10.1021/ja00536a020
PDF
.gamma.-Radiation-oxidation of polycyclic aromatic hydrocarbons: involvement of singlet oxygen
Roger L. Clough
pp 5242 - 5245; DOI:
10.1021/ja00536a021
PDF
Cooligomerizations of 3-substituted 1,5-hexadiynes with bis(trimethylsilyl)acetylene catalyzed by cobalt. A general synthesis of tricyclic ring systems from acyclic precursors
Raymond L. Funk and K. Peter C. Vollhardt
pp 5245 - 5253; DOI:
10.1021/ja00536a022
PDF
Transition-metal-catalyzed alkyne cyclizations. A cobalt-mediated total synthesis of dl-estrone
Raymond L. Funk and K. Peter C. Vollhardt
pp 5253 - 5261; DOI:
10.1021/ja00536a023
PDF
Generation of arenium ions by a self-protonation reaction in an aprotic molten salt medium
A. C. Buchanan, A. S. Dworkin, and G. P. Smith
pp 5262 - 5265; DOI:
10.1021/ja00536a024
PDF
Redox-photosensitized reactions. 5. Redox-photosensitized ring cleavage of 1,1a,2,2a-tetrahydro-7H-cyclobut[a]indene derivatives: mechanism and structure-reactivity relationship
Tetsuro Majima, Chyongjin Pac, and Hiroshi Sakurai
pp 5265 - 5273; DOI:
10.1021/ja00536a025
PDF
Novel intramolecular [4 + 2] cycloaddition reactions of enamines and enamides with unactivated dienes
Stephen F. Martin, Chih-Yun Tu, and Ta-Shue Chou
pp 5274 - 5279; DOI:
10.1021/ja00536a026
PDF
Electron-transfer-initiated reactions of organic peroxides. Reaction of phthaloyl peroxide with olefins and other electron donors
Joseph J. Zupancic, Keith A. Horn, and Gary B. Schuster
pp 5279 - 5285; DOI:
10.1021/ja00536a027
PDF
Energetic restrictions on the allowed range of catalyst pKas for general-acid- or general-base-catalyzed reactions of carbonyl compounds
J. Peter Guthrie
pp 5286 - 5293; DOI:
10.1021/ja00536a028
PDF
Nanosecond time-resolved fluorescence of phototautomeric lumichrome
Jung Do Choi, Robert D. Fugate, and Pill-Soon Song
pp 5293 - 5297; DOI:
10.1021/ja00536a029
PDF
Organic photochemistry with 6.7-eV photons: photoisomerization of tricyclo[3.2.1.02,4]oct-6-ene (endo and exo) and tricyclo[3.2.2.02,4]non-6-ene (endo and exo)
R. Srinivasan, Jose A. Ors, Karen H. Brown, Thomas Baum, Lloyd S. White, and Angelo R. Rossi
pp 5297 - 5302; DOI:
10.1021/ja00536a030
PDF
Potential surfaces for (NH)32+ [triaziridenyl dication]
Weston Thatcher Borden, Ernest R. Davidson, and David Feller
pp 5302 - 5311; DOI:
10.1021/ja00536a031
PDF
The region of mechanistic transition in acid-catalyzed epoxide ring opening. A mechanistic switch mediated by salt in aqueous media
Y. Pocker and B. P. Ronald
pp 5311 - 5316; DOI:
10.1021/ja00536a032
PDF
Relationship between the gas-phase entropies of molecules and their entropies of solvation in water and 1-octanol
David H. Wertz
pp 5316 - 5322; DOI:
10.1021/ja00536a033
PDF
Kinetic energy release and position of transition state during intramolecular aromatic substitution in ionized 1-phenyl-1-(2-pyridyl)ethylenes
Ralf Schubert and Hans Friedrich Gruetzmacher
pp 5323 - 5328; DOI:
10.1021/ja00536a034
PDF
Nucleophilic addition to olefins. 4. Structure-reactivity relationships in the reactions of amines with substituted benzylidene Meldrum's acids. Evidence for intramolecular proton transfer to carbon
Claude F. Bernasconi and Simonetta Fornarini
pp 5329 - 5336; DOI:
10.1021/ja00536a035
PDF
Highly stereoselective total syntheses of (+)-pachydictyol A and (-)-dictyolene, novel marine diterpenes from brown seaweeds of the family dictyotaceae
Andrew E. Greene
pp 5337 - 5343; DOI:
10.1021/ja00536a036
PDF
Long-distance intramolecular electron transfer in a macrocyclic crown ether, a thermoneutral, nonadiabatic process
Stephen Mazur, Vyas M. Dixit, and Fabian Gerson
pp 5343 - 5350; DOI:
10.1021/ja00536a037
PDF
Active-site interactions in fluorine-19 labeled [methionine-192]-.alpha.-chymotrypsin
Bryan H. Landis and Lawrence J. Berliner
pp 5350 - 5354; DOI:
10.1021/ja00536a038
PDF
Structural models for the rate-altering effects of alkylated [methionine-192]-.alpha.-chymotrypsins
Bryan H. Landis and Lawrence J. Berliner
pp 5354 - 5358; DOI:
10.1021/ja00536a039
PDF
Protonic reorganization in catalysis by serine proteases: acylation by small substrates
Daniel M. Quinn, James P. Elrod, Robert Ardis, Paul Friesen, and Richard L. Schowen
pp 5358 - 5365; DOI:
10.1021/ja00536a040
PDF
Protonic reorganization and substrate structure in catalysis by amidohydrolases
Daniel M. Quinn, K. S. Venkatasubban, Masahiro Kise, and Richard L. Schowen
pp 5365 - 5369; DOI:
10.1021/ja00536a041
PDF
Stereochemistry of allenic compounds. 3. Geometrical deformations of the propadiene unit in cyclic allenes
Jean Louis Luche, Jean Claude Damiano, and Claudine Cohen-Addad
pp 5370 - 5374; DOI:
10.1021/ja00536a042
PDF
Chemistry of anthocyanin pigments. 6. Kinetic and thermodynamic study of hydrogen sulfite addition to cyanin. Formation of a highly stable Meisenheimer-type adduct derived from a 2-phenylbenzopyrylium salt
Raymond Brouillard and Jean Michel El Hage Chahine
pp 5375 - 5378; DOI:
10.1021/ja00536a043
PDF
Chemical and spectroscopic comparison of the binuclear copper active site of mollusc and arthropod hemocyanins
Richard S. Himmelwright, Nancy C. Eickman, Cynthia D. LuBien, and Edward I. Solomon
pp 5378 - 5388; DOI:
10.1021/ja00536a044
PDF
Geometric isomerism in triplet carbenes: carbohydroxycarbene
Kwang S. Kim and Henry F. Schaefer
pp 5389 - 5390; DOI:
10.1021/ja00536a045
PDF
Assignment of the anomalous resonance Raman vibrations of bathorhodopsin
Gregory Eyring, Bostick Curry, Richard Mathies, Albert Broek, and Johan Lugtenburg
pp 5390 - 5392; DOI:
10.1021/ja00536a046
PDF
Direct measurement of the electron susceptibility anisotropy in paramagnetic complexes using high-field deuterium NMR
P. J. Domaille
pp 5392 - 5393; DOI:
10.1021/ja00536a047
PDF
Carbon monoxide activation by f-element organometallics. An unusually distorted, carbenelike dihaptoacyl and CO tetramerization
Paul J. Fagan, Juan M. Manriquez, Tobin J. Marks, Victor W. Day, Sara H. Vollmer, and Cynthia Secaur Day
pp 5393 - 5396; DOI:
10.1021/ja00536a048
PDF
Retention of configuration in displacement of carbonyl ligands from allyl(cyclopentadienyl)carbonylnitrosylmolybdenum cations
J. W. Faller and Y. Shvo
pp 5396 - 5398; DOI:
10.1021/ja00536a049
PDF
Synthesis and thermal isomerization of 2,2,3,3-tetrafluoromethylenecyclopropane
William R. Dolbier, Simon F. Sellers, Basil H. Al-Sader, and Bruce E. Smart
pp 5398 - 5399; DOI:
10.1021/ja00536a050
PDF
Detection of trialkylstannyl radicals using laser flash photolysis
J. C. Scaiano
pp 5399 - 5400; DOI:
10.1021/ja00536a051
PDF
Model approach to retinal pigments. Remarkable red shift due to proximal ammonium ion
Iwao Tabushi and Kazuhiro Shimokawa
pp 5400 - 5402; DOI:
10.1021/ja00536a052
PDF
Controlled alkaline hydrolysis of 16-bromo-17-keto steroids without ketol rearrangement and its reaction mechanism
Mitsuteru Numazawa and Yoshio Osawa
pp 5402 - 5404; DOI:
10.1021/ja00536a053
PDF
Contribution of orbital alignment to organic and enzymic reactivity
F. M. Menger and L. E. Glass
pp 5404 - 5406; DOI:
10.1021/ja00536a054
PDF
Extended unsaturated carbenes. Generation and trapping of an alkatetraenylidenecarbene, (R)2C:C:C:C:C:C:
Peter J. Stang and Mladen Ladika
pp 5406 - 5407; DOI:
10.1021/ja00536a055
PDF
ESR and IR evidence for intermediates in the di-.pi.-methane photorearrangement of a naphthobarrelene-like compound after low-temperature UV irradiation
Martin Demuth, Dieter Lemmer, and Kurt Schaffner
pp 5407 - 5409; DOI:
10.1021/ja00536a056
PDF
Effect of through-bond interaction on terminal methylene rotation in the tetramethylene diradical
Weston Thatcher Borden and Ernest R. Davidson
pp 5409 - 5410; DOI:
10.1021/ja00536a057
PDF
.alpha.-Keto dianions. New reactive intermediates
Conrad J. Kowalski, M. Lynn O'Dowd, M. Carmel Burke, and Kevin W. Fields
pp 5411 - 5412; DOI:
10.1021/ja00536a058
PDF
Reactions of germylenes with diazo compounds. New route for the formation of germanium-carbon double-bonded intermediates
P. Riviere, A. Castel, and J. Satge
pp 5413 - 5415; DOI:
10.1021/ja00536a059
PDF
Isolation of the [6 + 4].pi. cycloadduct and facile successive Cope rearrangements of the [2 + 4].pi. cycloadduct in a frontier-controlled pericyclic reaction of oxepin with cyclopentadienone
Takashi Ban, Yoshiaki Wakita, and Ken Kanematsu
pp 5415 - 5416; DOI:
10.1021/ja00536a060
PDF
Chirality at a pro-pro-prochiral phosphorus center. Stereochemical course of the 5'-nucleotidase-catalyzed reaction
Ming-Daw Tsai and Ting-Ting Chang
pp 5416 - 5418; DOI:
10.1021/ja00536a061
PDF
An unexpected G-G base pairing caused by the coordination of platinum(II) at the N(7) position of 9-ethylguanine
R. Faggiani, C. J. L. Lock, and B. Lippert
pp 5418 - 5419; DOI:
10.1021/ja00536a062
PDF
Cleavage of DNA by coordination complexes. Superoxide formation in the oxidation of 1,10-phenanthroline-cuprous complexes by oxygen - relevance to DNA-cleavage reaction
Daniel R. Graham, Laura E. Marshall, Karl A. Reich, and David S. Sigman
pp 5419 - 5421; DOI:
10.1021/ja00536a063
PDF
A model for a molecular mechanism of anticoagulant activity of 3-substituted 4-hydroxycoumarins
Richard B. Silverman
pp 5421 - 5423; DOI:
10.1021/ja00536a064
PDF
Total synthesis of l-triptonide and l-triptolide
E. E. Van Tamelen, J. P. Demers, E. G. Taylor, and K. Koller
pp 5424 - 5425; DOI:
10.1021/ja00536a065
PDF
Total synthesis of (5S,6R,7E,9E,11Z,14Z)-5-hydroxy-6-[(2R)-2-amino-2-(carboxyethyl)thio]-7,9,11,14-eicosatetraenoic acid, a potent SRS-A
Michael Rosenberger and Christian Neukom
pp 5425 - 5426; DOI:
10.1021/ja00536a066
PDF
Total synthesis of rugulovasines
J. Rebek and Y. K. Shue
pp 5426 - 5427; DOI:
10.1021/ja00536a067
PDF
Deuterium and oxygen-18 isotope effects on nucleophilic displacement by monomeric water in aprotic solvents
Joseph L. Kurz and Jasun Lee
pp 5427 - 5429; DOI:
10.1021/ja00536a068
PDF
Oxetene: synthesis and energetics of electrocyclic ring opening
Philip C. Martino and Philip B. Shevlin
pp 5429 - 5430; DOI:
10.1021/ja00536a069
PDF
1,1-Dichloro-2,5-bis(N-chlorothioimino)-3,4-dicyanoselenophene
F. Wudl and E. T. Zellers
pp 5430 - 5431; DOI:
10.1021/ja00536a070
PDF
Book Reviews

pp 5432 - 5434; DOI:
10.1021/ja00536a600
PDF

Issue 17


Electrochemical behavior of donor-tetracyanoquinodimethane electrodes in aqueous media
Calvin D. Jaeger and Allen J. Bard
pp 5435 - 5442; DOI:
10.1021/ja00537a001
PDF
Quantum-chemical studies of model cytochrome P450 hydrocarbon oxidation mechanisms. 1. A MINDO/3 study of hydroxylation and epoxidation pathways for methane and ethylene
Andrew T. Pudzianowski and Gilda H. Loew
pp 5443 - 5449; DOI:
10.1021/ja00537a002
PDF
Vibrational optical activity in para-substituted 1-methylcyclohex-1-enes
Prasad L. Polavarapu, Max Diem, and Laurence A. Nafie
pp 5449 - 5453; DOI:
10.1021/ja00537a003
PDF
Nuclear magnetic resonance relaxation studies of carbon-13 labeled uracil in transfer ribonucleic acid
W. David Hamill, W. James Horton, and David M. Grant
pp 5454 - 5458; DOI:
10.1021/ja00537a004
PDF
Thermally and photochemically initiated polymerization processes in the solid state
Jeremy K. Burdett
pp 5458 - 5462; DOI:
10.1021/ja00537a005
PDF
Properties of swollen polymer networks. Solvation and swelling of peptide-containing resins in solid-phase peptide synthesis
Virender K. Sarin, Stephen B. H. Kent, and R. B. Merrifield
pp 5463 - 5470; DOI:
10.1021/ja00537a006
PDF
Dipole-supported states. A very low lying excited state of acetaldehyde enolate anion
Ross W. Wetmore, Henry F. Schaefer, P. C. Hiberty, and John I. Brauman
pp 5470 - 5473; DOI:
10.1021/ja00537a007
PDF
The nature of hydrofluoric acid. A spectroscopic study of the proton-transfer complex H3O+.cntdot..cntdot..cntdot.F-
Paul A. Giguere and Sylvia Turrell
pp 5473 - 5477; DOI:
10.1021/ja00537a008
PDF
Luminescence quenching in the cluster network of perfluorosulfonate membrane
Plato C. Lee and Dan Meisel
pp 5477 - 5481; DOI:
10.1021/ja00537a009
PDF
Thermodynamic destabilization of N-centered radical cations by a .gamma.-keto group
Stephen F. Nelsen, Carl R. Kessel, Loretta A. Grezzo, and Daniel J. Steffek
pp 5482 - 5485; DOI:
10.1021/ja00537a010
PDF
Configuration-dependent Raman bands of phospholipid surfaces. 1. Carbonyl stretching modes at the bilayer interface
Ellen Bicknell-Brown, Kenneth G. Brown, and Willis B. Person
pp 5486 - 5491; DOI:
10.1021/ja00537a011
PDF
Singlet-triplet separation in dibromomethylene
Charles W. Bauschlicher
pp 5492 - 5493; DOI:
10.1021/ja00537a012
PDF
Photocatalytic and photoelectrochemical hydrogen production on strontium titanate single crystals
F. T. Wagner and G. A. Somorjai
pp 5494 - 5502; DOI:
10.1021/ja00537a013
PDF
Crystal structure and conformation of the cyclic trimer of a repeat pentapeptide of elastin, cyclo-(L-valyl-L-prolylglycyl-L-valylglycyl)3
William J. Cook, Howard Einspahr, Tina L. Trapane, Dan W. Urry, and Charles E. Bugg
pp 5502 - 5505; DOI:
10.1021/ja00537a014
PDF
Synthesis and spectroscopic and structural investigation on tetrakis(N-(2-ammoniaethyl)piperazinium)di-.mu.-chloro-dodecachlorotricuprate(IIbis(tetrachlorocuprate(II)), (C6H18N3)4Cu5Cl22
L. Antolini, G. Marcotrigiano, L. Menabue, and G. C. Pellacani
pp 5506 - 5510; DOI:
10.1021/ja00537a015
PDF
Oxidation-reduction reactions of complexes with macrocyclic ligands. Oxygen uptake kinetics, equilibriums and intermediates in aqueous CoII(N4) systems
Chung-Lai Wong, Jay A. Switzer, K. P. Balakrishnan, and John F. Endicott
pp 5511 - 5518; DOI:
10.1021/ja00537a016
PDF
Oxidation-reduction reactions of complexes with macrocyclic ligands. Energetics and dynamics of methyl exchange
John F. Endicott, K. P. Balakrishnan, and Chung-Lai Wong
pp 5519 - 5526; DOI:
10.1021/ja00537a017
PDF
Light-induced charge injection in functional crown ether vesicles
Keith Monserrat, Michael Graetzel, and Pierro Tundo
pp 5527 - 5529; DOI:
10.1021/ja00537a018
PDF
Entropy, enthalpy, and side arm porphyrins. 1. Thermodynamics of axial ligand competition between 3-picoline and a series of 3-pyridyl ligands covalently attached to zinc tetraphenylporphyrin
F. Ann Walker and Mabry Benson
pp 5530 - 5538; DOI:
10.1021/ja00537a019
PDF
Catalysis by multimetallics. Catalyzed homogeneous oxidation of alcohols and ketones with molecular oxygen in the presence of hexarhodium hexadecacarbonyl and dirhenium decacarbonyl
D. Max Roundhill, Mark K. Dickson, Nagaraj S. Dixit, and B. P. Sudha-Dixit
pp 5538 - 5542; DOI:
10.1021/ja00537a020
PDF
Photoelectrochemistry of tris(bipyridyl)ruthenium(II) covalently attached to n-type tin(IV) oxide
Pushpito Ghosh and Thomas G. Spiro
pp 5543 - 5549; DOI:
10.1021/ja00537a021
PDF
Synthetic molybdenum-iron-sulfur clusters. Preparation, structures, and properties of the [S2MoS2Fe(SC6H5)2]2- and [S2MoS2FeCl2]2- ions
R. H. Tieckelmann, H. C. Silvis, T. A. Kent, B. H. Huynh, J. V. Waszczak, Boon-Keng Teo, and B. A. Averill
pp 5550 - 5559; DOI:
10.1021/ja00537a022
PDF
Phosphorus-31 spin-lattice relaxation in aqueous orthophosphate solutions
Douglas C. McCain and John L. Markley
pp 5559 - 5565; DOI:
10.1021/ja00537a023
PDF
Interaction of cis-diaquodiammineplatinum dinitrate with ribose dinucleoside monophosphates
J. C. Chottard, J. P. Girault, G. Chottard, J. Y. Lallemand, and D. Mansuy
pp 5565 - 5572; DOI:
10.1021/ja00537a024
PDF
Intermolecular association of 1,N6-ethenoadenosine in aqueous solution. Vapor pressure osmometric and heat of dilution studies
Michiharu Sakurai, Satoshi Morimoto, and Yasuo Inoue
pp 5572 - 5574; DOI:
10.1021/ja00537a025
PDF
Intramolecular association of 1,N6-ethenoadenylyl-(3'.fwdarw.5')-1,N6-ethenoadenosine (.epsilon.Ap.epsilon.A). A comparison of intramolecular stacking equilibrium quotients estimated by different methods
Yasuo Inoue, Takao Kuramochi, Michiharu Sakurai, and Ichiro Tazawa
pp 5574 - 5577; DOI:
10.1021/ja00537a026
PDF
Photochemical transformations. 28. Comparisons of "ionic" intermediates produced photochemically with corresponding ground-state intermediates. Further studies in some chlorobenzobicyclooctadienyl systems
Stanley J. Cristol and Robert M. Strom
pp 5577 - 5580; DOI:
10.1021/ja00537a027
PDF
Thermorubin 1. Structure studies
Francis Johnson, Bani Chandra, Charles R. Iden, Prakash Naiksatam, Robert Kahen, Yoshi Okaya, and Shue-Yih Lin
pp 5580 - 5585; DOI:
10.1021/ja00537a028
PDF
A pyrimidine nucleoside constrained in the syn form. Structure and conformation of 6-methyl-2'-deoxyuridine
George I. Birnbaum, Frank E. Hruska, and Walter P. Niemczura
pp 5586 - 5590; DOI:
10.1021/ja00537a029
PDF
Determination of the lifetime of singlet oxygen in water-d2 using 9,10-anthracenedipropionic acid, a water-soluble probe
Barbara A. Lindig, Michael A. J. Rodgers, and A. Paul Schaap
pp 5590 - 5593; DOI:
10.1021/ja00537a030
PDF
Dynamic stereochemistry of 10-substituted 9-mesityl-9,10-dihydro-9-boraanthracene compounds
P. Finocchiaro, A. Recca, F. A. Bottino, F. Bickelhaupt, R. Van Veen, H. Schenk, and J. D. Schagen
pp 5594 - 5596; DOI:
10.1021/ja00537a031
PDF
Autoxidation of polyunsaturated lipids. Factors controlling the stereochemistry of product hydroperoxides
Ned A. Porter, Bruce A. Weber, Hugo Weenen, and Jamil A. Khan
pp 5597 - 5601; DOI:
10.1021/ja00537a032
PDF
Olefin epoxidation with .alpha.-substituted hydroperoxides
J. Rebek and R. McCready
pp 5602 - 5605; DOI:
10.1021/ja00537a033
PDF
The trialkylhydrazyl-trialkylhydrazine radical cation proton transfer. 1. Equilibrium constant
Stephen F. Nelsen, William P. Parmelee, Manfred Goebl, Karl Otmar Hiller, Dieter Veltwisch, and Klaus-Dieter Asmus
pp 5606 - 5610; DOI:
10.1021/ja00537a034
PDF
Selective dimerization of monosubstituted .alpha.-olefins by tantalacyclopentane catalysts
S. J. McLain, J. Sancho, and R. R. Schrock
pp 5610 - 5618; DOI:
10.1021/ja00537a035
PDF
Steric effects. A study of a rationally designed system
Garry Bott, Leslie D. Field, and Sever Sternhell
pp 5618 - 5626; DOI:
10.1021/ja00537a036
PDF
Photoinduced electron transfer reactions of transition-metal complexes with amines. Mechanistic studies of alternate pathways to back electron transfer
Patricia J. DeLaive, Thomas K. Foreman, Charles Giannotti, and David G. Whitten
pp 5627 - 5631; DOI:
10.1021/ja00537a037
PDF
Intramolecular proton transfer and excited-state relaxation in 2-(2-hydroxyphenyl)benzothiazole
P. F. Barbara, L. E. Brus, and P. M. Rentzepis
pp 5631 - 5635; DOI:
10.1021/ja00537a038
PDF
Ethylenediamine and aminoacetonitrile catalyzed decarboxylation of oxalacetate
Daniel L. Leussing and N. V. Raghavan
pp 5635 - 5643; DOI:
10.1021/ja00537a039
PDF
Formation and reaction of oxaziridine intermediate in the photochemical reaction of 6-cyanophenanthridine 5-oxide at low temperature
Kunihiro Tokumura, Hitomi Goto, Hironobu Kashiwabara, Chikara Kaneko, and Michiya Itoh
pp 5643 - 5647; DOI:
10.1021/ja00537a040
PDF
Photochemical transformation of small ring compounds. 114. Photochemistry of cyclopropene derivatives. 17. Competition between side-chain fragmentation and ring opening
Albert Padwa, Thomas J. Blacklock, Diana M. Cordova, and Roman Loza
pp 5648 - 5656; DOI:
10.1021/ja00537a041
PDF
Charge-transfer mechanism for quenching of the lowest 3n,.pi.* state of vapor-phase carbonyl-containing compounds by oxygen
Frank A. Cebul, Ken A. Kirk, Don W. Lupo, L. M. Pittenger, M. D. Schuh, Ifor R. Williams, and Greg C. Winston
pp 5656 - 5661; DOI:
10.1021/ja00537a042
PDF
Physical binding of tetraols derived from 7,8-dihydroxy-9,10-epoxybenzo[a]pyrene to DNA
Victor Ibanez, Nicholas E. Geacintov, Antoine G. Gagliano, Sebastian Brandimarte, and Ronald G. Harvey
pp 5661 - 5666; DOI:
10.1021/ja00537a043
PDF
Functional design of heme proteins: reaction with linear liqands
Michele C. Smith and George McLendon
pp 5666 - 5670; DOI:
10.1021/ja00537a044
PDF
Structural study of the vanadium complex in living ascidian blood cells by x-ray absorption spectroscopy
Thomas D. Tullius, William O. Gillum, Robert M. K. Carlson, and Keith O. Hodgson
pp 5670 - 5676; DOI:
10.1021/ja00537a045
PDF
A new method for 1,2-diamination of alkenes using cyclopentadienylnitrosylcobalt dimer/NO/LiAlH4
Paul N. Becker, Mary Ann White, and Robert G. Bergman
pp 5676 - 5677; DOI:
10.1021/ja00537a046
PDF
Photochemistry of a surfactant stilbene in organized media: a probe for hydrophobic sites in micelles, vesicles, and other assemblies
John C. Russell, Silvia B. Costa, Reginald P. Seiders, and David G. Whitten
pp 5678 - 5679; DOI:
10.1021/ja00537a047
PDF
ESR study of x-irradiated [HP(OCH2CH2)3N]BF4: phosphorus in a trigonal-bipyramidal configuration with the unpaired electron in apical position
J. H. H. Hamerlinck, P. Schipper, and H. M. Buck
pp 5679 - 5680; DOI:
10.1021/ja00537a048
PDF
A three-carbon condensative expansion. Application to muscone
Barry M. Trost and John E. Vincent
pp 5680 - 5683; DOI:
10.1021/ja00537a049
PDF
Kinetics of carbon monoxide binding to manganese, zinc, and cobalt hybrid hemoglobins
Neil V. Blough, Haya Zemel, Brian M. Hoffman, Ted C. K. Lee, and Quentin H. Gibson
pp 5683 - 5685; DOI:
10.1021/ja00537a050
PDF
Catalysis by aliphatic thiol of photoreduction of benzophenone by primary and secondary amines
Paul G. Stone and Saul Cohen
pp 5685 - 5686; DOI:
10.1021/ja00537a051
PDF
Ion-molecule complexes in unimolecular fragmentations of gaseous cations. Cyclization of unsaturated carbocations in the gas phase
David G. Hall and Thomas Hellman Morton
pp 5686 - 5688; DOI:
10.1021/ja00537a052
PDF
Ulicyclamide and ulithiacyclamide, two new small peptides from a marine tunicate
Chris Ireland and Paul J. Scheuer
pp 5688 - 5691; DOI:
10.1021/ja00537a053
PDF
A new oxidized derivative of cyclophosphamide obtained from ozonolysis of O-3-butenyl N,N-bis(2-chloroethyl)phosphorodiamidate
J. Van der Steen, J. G. Westra, C. Benckhuysen, and H. R. Schulten
pp 5691 - 5692; DOI:
10.1021/ja00537a054
PDF
Flow pyrolysis and direct and silicon tetrafluoride-sensitized laser-induced decomposition of tetralin. Identification of retro-[2 + 4] cleavage as the primary homogeneous thermal decomposition channel
Michael R. Berman, Paul B. Comita, C. Bradley Moore, and Robert G. Bergman
pp 5692 - 5694; DOI:
10.1021/ja00537a055
PDF
Synthesis of metallacyclopentanes containing two metals in the ring. Thermal decomposition to cyclopropane and ligand-induced conversion to stable mononuclear metallacyclopentanones
Klaus H. Theopold and Robert G. Bergman
pp 5694 - 5695; DOI:
10.1021/ja00537a056
PDF
Boronitroxides
Michel P. Crozet and Paul Tordo
pp 5696 - 5697; DOI:
10.1021/ja00537a057
PDF
Alternative pathways in the reactions of cyclopropyl halides with alkali metal naphthalenes
G. Boche, D. R. Schneider, and H. Wintermayr
pp 5697 - 5699; DOI:
10.1021/ja00537a058
PDF
An enantiodirected cyclopentenone annulation. Synthesis of a useful building block for condensed cyclopentanoid natural products
Barry M. Trost and Dennis P. Curran
pp 5699 - 5700; DOI:
10.1021/ja00537a059
PDF
Dynamics of electron transfer in amine photooxidation
K. S. Peters, S. C. Freilich, and C. G. Schaeffer
pp 5701 - 5702; DOI:
10.1021/ja00537a060
PDF

Issue 18


Complete analysis of proton NMR spectra of complex natural products using a combination of one- and two-dimensional techniques. 1-Dehydrotestosterone
Laurance D. Hall and Jeremy K. M. Sanders
pp 5703 - 5711; DOI:
10.1021/ja00538a001
PDF
Carbon-13 NMR studies on arsenic(III) and antimony(III) dihydroxydicarboxylate complexes
Dragoslav Marcovich and Robert E. Tapscott
pp 5712 - 5717; DOI:
10.1021/ja00538a002
PDF
Soft x-ray absorption spectroscopy. Electronic and morphological structure of poly(vinylidene fluoride)
R. S. Williams, D. Denley, D. A. Shirley, and J. Stoehr
pp 5717 - 5723; DOI:
10.1021/ja00538a003
PDF
Rotational motions of side chains of poly-L-lysine
Richard J. Wittebort, Attila Szabo, and Frank R. N. Gurd
pp 5723 - 5728; DOI:
10.1021/ja00538a004
PDF
An electrode modified with polymer-bound dopamine which catalyzes NADH oxidation
Chantal Degrand and Larry L. Miller
pp 5728 - 5732; DOI:
10.1021/ja00538a005
PDF
Absorption spectra and photochemical rearrangement of cycloheptatriene cation to toluene cation in solid argon
Lester Andrews and Brian W. Keelan
pp 5732 - 5736; DOI:
10.1021/ja00538a006
PDF
Reactions of fluorine with methane upon photolysis and diffusion in solid argon. Infrared spectra of hydrofluoric acid hydrogen-bonded complexes
Gary L. Johnson and Lester Andrews
pp 5736 - 5741; DOI:
10.1021/ja00538a007
PDF
Determination of the basicities of benzyl, allyl, and tert-butylpropargyl anions by anodic oxidation of organolithium compounds
Bernhard Jaun, Joshua Schwarz, and Ronald Breslow
pp 5741 - 5748; DOI:
10.1021/ja00538a008
PDF
Electronic structure of symmetric homoconjugated dienes. Circular dichroism of (1S)-2-deuterio- and 2-methylnorbornadiene and (1S)-2-deuterio- and 2-methylbicyclo[2.2.2]octadiene
David A. Lightner, Jacek K. Gawronski, and Thomas D. Bouman
pp 5749 - 5754; DOI:
10.1021/ja00538a009
PDF
Separation of contact and pseudocontact contributions to carbon-13 lanthanide induced shifts in non-axially-symmetric lanthanide ethylenediaminetetraacetate chelates
A. Dean Sherry, Ping P. Yang, and Leon O. Morgan
pp 5755 - 5759; DOI:
10.1021/ja00538a010
PDF
Electronic structure of the alkyllithium clusters, (CH3Li)n, n = 1-6, and (C2H5Li)n, n = 1-2
Glenn Graham, Steven Richtsmeier, and David A. Dixon
pp 5759 - 5766; DOI:
10.1021/ja00538a011
PDF
Circular dichroism, crystal structure, and absolute configuration of the siderophore ferric N,N',N"-triacetylfusarinine, FeC39H57N6O15
M. B. Hossain, D. L. Eng-Wilmot, R. A. Loghry, and Dick Van der Helm
pp 5766 - 5773; DOI:
10.1021/ja00538a012
PDF
Synthesis and crystal and molecular structure of [(Ph3P)2N+][S4N-] and the electronic structure of the planar acyclic anion, S4N-
T. Chivers, W. G. Laidlaw, R. T. Oakley, and M. Trsic
pp 5773 - 5781; DOI:
10.1021/ja00538a013
PDF
Closo and hyper-closo ten-vertex ruthenacarboranes containing chelating alkenylphosphine ligands
C. W. Jung, R. T. Baker, C. B. Knobler, and M. F. Hawthorne
pp 5782 - 5790; DOI:
10.1021/ja00538a014
PDF
Tris(amino)boranes: the effect of angle strain on hybridization
Jack E. Richman, N. C. Yang, and Leah L. Andersen
pp 5790 - 5792; DOI:
10.1021/ja00538a015
PDF
Kinetics of an associative ligand-exchange process: alcohol exchange with arsenate(V) triesters
Carl D. Baer, John O. Edwards, Malcolm J. Kaus, Thomas G. Richmond, and Philip H. Rieger
pp 5793 - 5798; DOI:
10.1021/ja00538a016
PDF
A semiclassical treatment of electron-exchange reactions. Application to the hexaaquoiron(II)-hexaaquoiron(III) system
Bruce S. Brunschwig, Jean Logan, Marshall D. Newton, and Norman Sutin
pp 5798 - 5809; DOI:
10.1021/ja00538a017
PDF
Phosphole [2 + 2] and [4 + 2] dimerizations around metal carbonyl moieties. Structure and chemistry of a new type of exo [4 + 2] dimers
Catherine C. Santini, Jean Fischer, Francois Mathey, and Andre Mitschler
pp 5809 - 5815; DOI:
10.1021/ja00538a018
PDF
Resonance Raman spectra of nitrosyl heme proteins and of porphyrin analogs
J. D. Stong, J. M. Burke, P. Daly, P. Wright, and T. G. Spiro
pp 5815 - 5819; DOI:
10.1021/ja00538a019
PDF
Exchange interactions in copper(II)-nickel(II) and nickel(II)-nickel(II) pairs in tetra(.mu.-benzoato-O,O')bis(quinoline)dimetal(II) complexes
Alessandro Bencini, Cristiano Benelli, Dante Gatteschi, and Claudia Zanchini
pp 5820 - 5823; DOI:
10.1021/ja00538a020
PDF
A mechanistic study of the rhodium-catalyzed cyclization of 4-hexenals. Reactions of deuterio-4-hexenals
Richard E. Campbell, Charles F. Lochow, Krishnakant P. Vora, and Roy G. Miller
pp 5824 - 5830; DOI:
10.1021/ja00538a021
PDF
Role of a peroxide intermediate in the chemiluminescence of luminol. A mechanistic study
Gabor Merenyi and Johan S. Lind
pp 5830 - 5835; DOI:
10.1021/ja00538a022
PDF
Mechanistic change in acid-catalyzed hydrolysis of silyl vinyl ethers
Marilyn H. Novice, Hani R. Seikaly, Annette D. Seiz, and Thomas T. Tidwell
pp 5835 - 5838; DOI:
10.1021/ja00538a023
PDF
Hydration of the flavylium ion
Robert A. McClelland and Sherrin Gedge
pp 5838 - 5848; DOI:
10.1021/ja00538a024
PDF
Carbanions. 20. Rearrangements in reactions of 5-chloro-4,4-diphenyl-2-pentyne, 1-chloro-5,5-dimethyl-2,2-diphenyl-3-hexyne, and 5,5-dimethyl-2,2-diphenyl-3-hexyne with alkali metals. Cation effects on migratory aptitudes of groups
Erling Grovenstein, Kuen-Wai Chiu, and Bhalchandra B. Patil
pp 5848 - 5859; DOI:
10.1021/ja00538a025
PDF
Photoresponsive crown ethers. 1. Cis-trans isomerism of azobenzene as a tool to enforce conformational changes of crown ethers and polymers
Seiji Shinkai, Takahiro Nakaji, Yoshihiro Nishida, Toshiyuki Ogawa, and Osamu Manabe
pp 5860 - 5865; DOI:
10.1021/ja00538a026
PDF
Geminal acylation-alkylation at a carbonyl carbon via regiospecifically generated metalloenamines
Stephen F. Martin, Gerald W. Phillips, Thomas A. Puckette, and John A. Colapret
pp 5866 - 5872; DOI:
10.1021/ja00538a027
PDF
Lewis acid induced conjugate addition of alkenes to .alpha.,.beta.-unsaturated ketones or aldehydes
Barry B. Snider, David J. Rodini, and Jan Van Straten
pp 5872 - 5880; DOI:
10.1021/ja00538a028
PDF
Efficient, regiospecific synthesis of anthracycline intermediates: total synthesis of daunomycin
Kathlyn A. Parker and James Kallmerten
pp 5881 - 5886; DOI:
10.1021/ja00538a029
PDF
Sesquiterpene lactones. Total synthesis of (.+-.)-eriolanin and (.+-.)-eriolangin
Paul A. Grieco, Tomei Oguri, and S. Gilman
pp 5886 - 5891; DOI:
10.1021/ja00538a030
PDF
Electronic effects on the Menshutkin reaction. A complete kinetic and thermodynamic dissection of alkyl transfer to 3- and 4-substituted pyridines
Edward M. Arnett and Ronald Reich
pp 5892 - 5902; DOI:
10.1021/ja00538a031
PDF
New binuclear lanthanide NMR shift reagents effective for aromatic compounds
T. J. Wenzel, T. C. Bettes, J. E. Sadlowski, and R. E. Sievers
pp 5903 - 5904; DOI:
10.1021/ja00538a032
PDF
Structure and dynamic behavior of transition-metal ions in aqueous solution: an EXAFS study of electron-exchange reactions
T. K. Sham, J. B. Hastings, and M. L. Perlman
pp 5904 - 5906; DOI:
10.1021/ja00538a033
PDF
Transition metal methylene complexes. 13. Proton-induced ring opening of a dimetallacyclopropane-type .mu.-methylene-rhodium compound. A straightforward novel route to halo(methyl) complexes
Wolfgang A. Herrmann, Johann Plank, Manfred L. Ziegler, and Barbara Balbach
pp 5906 - 5908; DOI:
10.1021/ja00538a034
PDF
Selective reductions of ammineruthenium(III) complexes by hydrogen sulfide
S. E. Diamond, B. S. Tovrog, and F. Mares
pp 5908 - 5909; DOI:
10.1021/ja00538a035
PDF
A binuclear nickel(II) encapsulating agent for chloride and bromide ions
W. L. Gladfelter and Harry B. Gray
pp 5909 - 5910; DOI:
10.1021/ja00538a036
PDF
Hydrophobic effect of the methylene group: enthalpy and entropy contributions
Michael H. Abraham
pp 5910 - 5912; DOI:
10.1021/ja00538a037
PDF
A new route to lipid hydroperoxides: orbital symmetry controlled ring opening of vinylcyclopropyl bromides
Ned A. Porter, David H. Roberts, and Carl B. Ziegler
pp 5912 - 5913; DOI:
10.1021/ja00538a038
PDF
Reversible conformational changes induced by light in poly(L-glutamic acid) with photochromic side chains
Osvaldo Pieroni, Julien L. Houben, Adriano Fissi, Paolo Costantino, and Francesco Ciardelli
pp 5913 - 5915; DOI:
10.1021/ja00538a039
PDF
Chiral recognition by small biological molecules. Resolution of helicenes on silica gel coated with riboflavin
Young Hwan Kim, Arye Tishbee, and Emanuel Gil-Av
pp 5915 - 5917; DOI:
10.1021/ja00538a040
PDF
Sterically promoted benzocyclobutenol formation from 2,4,6-triisopropylbenzophenone photolysis
Yoshikatsu Ito, Yasutoshi Umehara, Toyoto Hijiya, Yutaka Yamada, and Teruo Matsuura
pp 5917 - 5919; DOI:
10.1021/ja00538a041
PDF
Thexylchloroborane. A versatile reagent for the preparation of mixed thexyldiorganoboranes
George Zweifel and Norman R. Pearson
pp 5919 - 5920; DOI:
10.1021/ja00538a042
PDF
Structure of goniomine, an alkaloid of a new type biogenetically related to indole alkaloids. X-ray analysis of dihydrogoniomine
A. Chiaroni, L. Randriambola, C. Riche, and H. P. Husson
pp 5920 - 5921; DOI:
10.1021/ja00538a043
PDF
Persulfonium salts: the reaction of a difluoropersulfurane with Lewis acids
Ronald S. Michalak and J. C. Martin
pp 5921 - 5923; DOI:
10.1021/ja00538a044
PDF
Versatile preparation of highly functionalized .alpha.-alkenyl complexes of cyclopentadienyliron. A new route to substituted alkenes
D. L. Reger and P. J. McElligott
pp 5923 - 5924; DOI:
10.1021/ja00538a045
PDF
Arene-metal complexes in organic synthesis: synthesis of acorenone and acorenone B
M. F. Semmelhack and A. Yamashita
pp 5924 - 5926; DOI:
10.1021/ja00538a046
PDF
Stereoselective and regioselective ene reactions of methyl .alpha.-chloroacrylate
Barry B. Snider and John V. Duncia
pp 5926 - 5928; DOI:
10.1021/ja00538a047
PDF
Bis(pentadienyl)iron compounds: the "open ferrocenes"
David R. Wilson, Anthony A. DiLullo, and Richard D. Ernst
pp 5928 - 5930; DOI:
10.1021/ja00538a048
PDF
Enol ether-iron complexes as vinyl cation equivalents. Vinylation of enolates
Tony C. T. Chang, Myron Rosenblum, and Sari B. Samuels
pp 5930 - 5931; DOI:
10.1021/ja00538a049
PDF
A new soft ionization technique for mass spectrometry of complex molecules
C. R. Blakley, J. J. Carmody, and M. L. Vestal
pp 5931 - 5933; DOI:
10.1021/ja00538a050
PDF
Time-resolved proton magnetic resonance studies of polynucleotides
Claude R. Jones
pp 5933 - 5934; DOI:
10.1021/ja00538a051
PDF
Exchange elasticity in copper(II) dinuclear cryptates
O. Kahn, I. Morgenstern-Badarau, J. P. Audiere, J. M. Lehn, and S. A. Sullivan
pp 5935 - 5936; DOI:
10.1021/ja00538a052
PDF
Water penetration into micelles as determined by optical rotary dispersion
F. M. Menger and B. J. Boyer
pp 5936 - 5938; DOI:
10.1021/ja00538a053
PDF
Isocyanide binding to chelated protoheme. Kinetic criteria for distal steric effects in hemoproteins
T. G. Traylor and D. V. Stynes
pp 5938 - 5939; DOI:
10.1021/ja00538a054
PDF
Cyclophane hemes. 3. Magnitudes of distal side steric effects in hemes and hemoproteins
T. G. Traylor, D. Campbell, S. Tsuchiya, M. Mitchell, and D. V. Stynes
pp 5939 - 5941; DOI:
10.1021/ja00538a055
PDF
Enantiomerization trends in 1,8-bis(trimethylelement)naphthalenes
W. Douglas Hounshell, Frank A. L. Anet, Franco Cozzi, James R. Damewood, Constance A. Johnson, Ulf Sjoestrand, and Kurt Mislow
pp 5941 - 5942; DOI:
10.1021/ja00538a056
PDF
Conformational variability in hexaethylbenzene .pi.-complexes. Crystal and molecular structure of tricarbonyl(hexaethylbenzene)chromium(0) and dicarbonyl(hexaethylbenzene)(triphenylphosphine)chromium(0)
Geoffrey Hunter, Daniel J. Iverson, Kurt Mislow, and John F. Blount
pp 5942 - 5943; DOI:
10.1021/ja00538a057
PDF
Preparation of highly reactive metal powders. Direct reaction of nickel, cobalt, and iron metal powders with arene halides
Arunas V. Kavaliunas and Reuben D. Rieke
pp 5944 - 5945; DOI:
10.1021/ja00538a058
PDF
Role of ferryl (FeO2+) complexes in oxygen atom transfer reactions. Mechanism of iron(II) porphyrin catalyzed oxygenation of triphenylphosphine
Der-Hang Chin, Gerd N. La Mar, and Alan L. Balch
pp 5945 - 5947; DOI:
10.1021/ja00538a059
PDF
Macrocyclic hexacarboxylic acid. A highly selective host for uranyl ion
Iwao Tabushi, Yoshiaki Kobuke, Kiyoto Ando, Masanari Kishimoto, and Eiichi Ohara
pp 5947 - 5948; DOI:
10.1021/ja00538a060
PDF
Selective homogeneous catalytic hydrogenation of polynuclear aromatics
Roger A. Grey, Guido P. Pez, and Andrea Wallo
pp 5948 - 5949; DOI:
10.1021/ja00538a061
PDF
Molecular structure of dichloro(5-methylenecycloheptene)platinum(II). "In-plane" coordination of the exocyclic olefin
Laura L. Wright, Richard M. Wing, Michael F. Rettig, and George R. Wiger
pp 5949 - 5950; DOI:
10.1021/ja00538a062
PDF
A new series of alkyldimolybdenum M.tplbond.M compounds: direct observation of rotation about the triple bond and alkyl ligand transfer
Malcolm H. Chisholm and Ian P. Rothwell
pp 5950 - 5952; DOI:
10.1021/ja00538a063
PDF
Identification of the enantioselective step in the asymmetric catalytic hydrogenation of a prochiral olefin
A. S. C. Chan, J. J. Pluth, and Jack Halpern
pp 5952 - 5954; DOI:
10.1021/ja00538a064
PDF
Application of metalated enamines to alkaloid synthesis. An expedient approach to the synthesis of morphine-based analgesics
D. A. Evans, C. H. Mitch, R. C. Thomas, D. M. Zimmerman, and R. L. Robey
pp 5955 - 5956; DOI:
10.1021/ja00538a065
PDF
Cation-medium control of hydride transfer between carbonyl groups
E. W. Warnhoff, P. Reynolds-Warnhoff, and Margaret Y. H. Wong
pp 5956 - 5957; DOI:
10.1021/ja00538a066
PDF
Chemistry of fluorenylidene. Direct observation of, and kinetic measurements on, a singlet and a triplet carbene at room temperature
Joseph J. Zupancic and Gary B. Schuster
pp 5958 - 5960; DOI:
10.1021/ja00538a067
PDF
Cytochalasin support studies. 2. Chiral and stereochemical control via an intramolecular Diels-Alder reaction of a (Z)-diene
Stephen G. Pyne, Mark J. Hensel, Stephen R. Byrn, Ann T. McKenzie, and P. L. Fuchs
pp 5960 - 5962; DOI:
10.1021/ja00538a068
PDF
Effect of photoelectrode crystal structure on output stability of Cd(Se,Te)/polysulfide photoelectrochemical cells
Gary Hodes, Joost Manassen, and David Cahen
pp 5962 - 5964; DOI:
10.1021/ja00538a069
PDF
Biosynthesis of antibiotics of the virginiamycin family. 1. Biosynthesis of virginiamycin M1: determination of the labeling pattern by the use of stable isotope techniques
David G. I. Kingston and Michael X. Kolpak
pp 5964 - 5966; DOI:
10.1021/ja00538a070
PDF
Activation of water molecules. 4. Generation of dihydrogen from water by rhodium(I) hydrido and rhodium(0) carbonyl compounds
T. Yoshida, T. Okano, and S. Otsuka
pp 5966 - 5967; DOI:
10.1021/ja00538a071
PDF
Organoselenium chemistry. Formation of acetylenes and allenes by syn elimination of vinyl selenoxides
Hans J. Reich and William W. Willis
pp 5967 - 5968; DOI:
10.1021/ja00538a072
PDF
Low-temperature ozonation of alkenes adsorbed on silica gel
Ivan E. DenBesten and Thomas H. Kinstle
pp 5968 - 5969; DOI:
10.1021/ja00538a073
PDF
Intramolecular electron-transfer induced carbon-hydrogen bond dissociation in methyl-substituted 1,10-phenanthroline complexes of bis(.eta.5-cyclopentadienyl)titanium
D. R. Corbin, W. S. Willis, E. N. Duesler, and G. D. Stucky
pp 5969 - 5971; DOI:
10.1021/ja00538a074
PDF
Substitutive intramolecular carbonyl insertion in a carbomolybdate cluster: formation of a polycentric, conformationally flexible anion binding cavity
V. W. Day, M. R. Thompson, C. S. Day, W. G. Klemperer, and R. S. Liu
pp 5971 - 5973; DOI:
10.1021/ja00538a075
PDF
A novel .beta.-ketophosphonate 1,4-dianion. Tin/lithium exchange
Ramanuj Goswami
pp 5973 - 5974; DOI:
10.1021/ja00538a076
PDF
The first practical method for asymmetric epoxidation
Tsutomu Katsuki and K. Barry Sharpless
pp 5974 - 5976; DOI:
10.1021/ja00538a077
PDF
2,3-Di-propyl-1,4-dehydrobenzene
Thomas P. Lockhart, Charles B. Mallon, and Robert G. Bergman
pp 5976 - 5978; DOI:
10.1021/ja00538a078
PDF
Allyl sulfones as synthons for 1,1- and 1,3-dipoles via organopalladium chemistry
Barry M. Trost, Norman R. Schmuff, and Michael J. Miller
pp 5979 - 5981; DOI:
10.1021/ja00538a079
PDF
Asymmetric sulfoxidation by dopamine .beta.-hydroxylase, an oxygenase heretofore considered specific for methylene hydroxylation
Sheldon W. May and Robert S. Phillips
pp 5981 - 5983; DOI:
10.1021/ja00538a080
PDF
Efficient, regiospecific synthesis of (.+-.)-daunomycinone
T. Ross Kelly, Jacob Vaya, and L. Ananthasubramanian
pp 5983 - 5984; DOI:
10.1021/ja00538a081
PDF

Issue 19


Heats of formation of the [16] annulene dianion and neutral molecule
Gerald R. Stevenson and Brad E. Forch
pp 5985 - 5988; DOI:
10.1021/ja00539a001
PDF
Unified LCAO MO approach to chemisorption and heterogeneous catalysis. 2. The cluster-solid analogy and surface vs. bulk charge distribution
Evgeny Shustorovich and Roger C. Baetzold
pp 5989 - 5993; DOI:
10.1021/ja00539a002
PDF
Intrinsic barriers in nucleophilic displacements
Mark J. Pellerite and John I. Brauman
pp 5993 - 5999; DOI:
10.1021/ja00539a003
PDF
Conformations of six N-methylated diketopiperazines in solution
W. Radding, B. Donzel, N. Ueyama, and M. Goodman
pp 5999 - 6005; DOI:
10.1021/ja00539a004
PDF
Infrared matrix-isolation studies of the interactions and reactions of Group 3A metal atoms with water
R. H. Hauge, J. W. Kauffman, and J. L. Margrave
pp 6005 - 6011; DOI:
10.1021/ja00539a005
PDF
A nuclear magnetic resonance study of tert-butoxyaluminates
Deane A. Horne
pp 6011 - 6014; DOI:
10.1021/ja00539a006
PDF
Hydrogen-bonding interactions involving metal-bound dioxygen
Russell S. Drago, J. Patrick Cannady, and Kenneth A. Leslie
pp 6014 - 6019; DOI:
10.1021/ja00539a007
PDF
Cis labilization of ligand dissociation. 7. Substitution reactions of acetonitrilepentacarbonylmanganese(I). Cis labilization via nucleophilic attack at metal-bound carbonyl
Peter A. Bellus and Theodore L. Brown
pp 6020 - 6026; DOI:
10.1021/ja00539a008
PDF
Electrode catalysis of the four-electron reduction of oxygen to water by dicobalt face-to-face porphyrins
James P. Collman, Peter Denisevich, Yutaka Konai, Matt Marrocco, Carl Koval, and Fred C. Anson
pp 6027 - 6036; DOI:
10.1021/ja00539a009
PDF
Polyarsenide anions. Synthesis and structure of a salt containing the undecaarsenide(3-) ion
Claude H. E. Belin
pp 6036 - 6040; DOI:
10.1021/ja00539a010
PDF
Transition-metal complexes of vitamin B6 related compounds. 3. X-ray, Moessbauer, and magnetic properties of a binuclear iron(III) complex containing an unusual pyridoxal derivative
Gary J. Long, James T. Wrobleski, Raju V. Thundathil, Don M. Sparlin, and Elmer O. Schlemper
pp 6040 - 6046; DOI:
10.1021/ja00539a011
PDF
Cyclooligomeric phenol-aldehyde condensation products. 2. Stereoselective synthesis and DNMR study of two 1,8,15,22-tetraphenyl[14]metacyclophan-3,5,10,12,17,19,24,26-octols
A. G. Sverker Hoegberg
pp 6046 - 6050; DOI:
10.1021/ja00539a012
PDF
Quenching of the fluorescence of 2-norbornanone and derivatives by electron-rich and electron-poor ethylenes
Nicholas J. Turro and George L. Farrington
pp 6051 - 6055; DOI:
10.1021/ja00539a013
PDF
Photoinduced oxetane formation between 2-norbornanone and derivatives with electron-poor ethylenes
Nicholas J. Turro and George L. Farrington
pp 6056 - 6063; DOI:
10.1021/ja00539a014
PDF
Studies on the spiro[2.5]octadienyl radical and the 2-phenylethyl rearrangement
A. Effio, D. Griller, K. U. Ingold, J. C. Scaiano, and S. J. Sheng
pp 6063 - 6068; DOI:
10.1021/ja00539a015
PDF
Low-lying electronically excited states of cycl[3.3.3]azine, a bridged 12.pi.-perimeter
Werner Leupin and Jakob Wirz
pp 6068 - 6075; DOI:
10.1021/ja00539a016
PDF
Equilibriums and absorption spectra of Schiff bases
Carol M. Metzler, Allen Cahill, and David E. Metzler
pp 6075 - 6082; DOI:
10.1021/ja00539a017
PDF
Electron-transfer photooxygenation. 5. Oxidation of phenyl-substituted alkenes sensitized by cyanoanthracenes
J. Eriksen and C. S. Foote
pp 6083 - 6088; DOI:
10.1021/ja00539a018
PDF
Photoaddition of biacetyl and alkenes. Reaction stereochemistry, multiplicity, and photokinetics
Guilford Jones, Mahalingham Santhanam, and Sheau-Hwa Chiang
pp 6088 - 6095; DOI:
10.1021/ja00539a019
PDF
Solvent modified reactivity of dimethylsilylene
Kent P. Steele and William P. Weber
pp 6095 - 6097; DOI:
10.1021/ja00539a020
PDF
Studies on the reaction mechanism of the photocyclization of N-aryl enamines. Dependence of quantum yields on back and side reactions
Thomas Wolff and Reinhard Waffenschmidt
pp 6098 - 6102; DOI:
10.1021/ja00539a021
PDF
Use of kinetic isotope effects in mechanism studies. Effect of an internal return mechanism on the Arrhenius behavior of primary hydrogen isotope effects
Heinz F. Koch and Donald B. Dahlberg
pp 6102 - 6107; DOI:
10.1021/ja00539a022
PDF
Addition of diphenylmethylene to 1,2-dichloroethylenes. New chemical evidence for a carbene singlet-triplet equilibrium
Peter P. Gaspar, Bonnie L. Whitsel, Maitland Jones, and Joseph B. Lambert
pp 6108 - 6113; DOI:
10.1021/ja00539a023
PDF
Facile synthesis of fucoserratene and the (.+-.)-dictyopterenes B, D, and D' (= ectocarpene): constituents of marine brown algae
Manfred P. Schneider and Michael Goldbach
pp 6114 - 6116; DOI:
10.1021/ja00539a024
PDF
Design and synthesis of multidetachable resin supports for solid-phase peptide synthesis
James P. Tam, Foe S. Tjoeng, and R. B. Merrifield
pp 6117 - 6127; DOI:
10.1021/ja00539a025
PDF
Stable carbocations. 230. 2,5-Diphenyl-2,5-norbornyl dications
George A. Olah, G. K. Surya Prakash, and Tarik N. Rawdah
pp 6127 - 6130; DOI:
10.1021/ja00539a026
PDF
Crystal structure and spectroscopic properties of violet glutathione-copper(II) complex with axial sulfur coordination and two copper sites via a disulfide bridge
Kiyonori Miyoshi, Yukio Sugiura, Kazuhiko Ishizu, Yoichi Iitaka, and Hikaru Nakamura
pp 6130 - 6136; DOI:
10.1021/ja00539a027
PDF
Generalized molecular orbital theory. Application to borane and diborane
T. E. Taylor and M. B. Hall
pp 6136 - 6142; DOI:
10.1021/ja00539a028
PDF
Simultaneous electrochemical and fluorometric monitoring of zinc tetraphenylporphyrin deposited on indium oxide and pyrolytic graphite electrodes
Julie S. Pflug and Larry R. Faulkner
pp 6143 - 6144; DOI:
10.1021/ja00539a029
PDF
The .PI. and .SIGMA.N electronic states of the succinimidyl radical. Can nitrogen-centered radicals have .SIGMA.N ground states? An ab initio study
Yitzhak Apeloig and Ruth Schreiber
pp 6144 - 6146; DOI:
10.1021/ja00539a030
PDF
Hypovalent radicals. 8. Identification of nucleophilic 1,2- and 1,4-addition processes with .alpha.,.beta.-unsaturated molecules in the gas phase
Richard N. McDonald and A. Kasem Chowdhury
pp 6146 - 6147; DOI:
10.1021/ja00539a031
PDF
Activation of a coordinated olefin toward nucleophilic attack
Odile Eisenstein and Roald Hoffmann
pp 6148 - 6149; DOI:
10.1021/ja00539a032
PDF
Titanacyclobutenes
Fred N. Tebbe and Richard L. Harlow
pp 6149 - 6151; DOI:
10.1021/ja00539a033
PDF
Linkage isomerism of a bidentate triphosphate ligand having six- or eight-membered chelate rings
E. A. Merritt, M. Sundaralingam, and R. D. Cornelius
pp 6151 - 6153; DOI:
10.1021/ja00539a034
PDF
Reactions of coordinated dinitrogen. 8. Formation of ammonia by protonation of a molybdenum-dinitrogen complex and isolation and characterization of the molybdenum-containing product
John A. Baumann and T. Adrian George
pp 6153 - 6154; DOI:
10.1021/ja00539a035
PDF
Conversion of an .eta.5-cyclopentadienyl-metal complex to an .eta.1-cyclopentadienyl-metal complex upon addition of trimethylphosphine
Charles P. Casey and William D. Jones
pp 6154 - 6156; DOI:
10.1021/ja00539a036
PDF
Lewis acid-base behavior of dihydrodecacarbonyltriosmium: versatile pathways to mixed-metal clusters
Jeffrey S. Plotkin, Donna G. Alway, Clemens R. Weisenberger, and Sheldon G. Shore
pp 6156 - 6157; DOI:
10.1021/ja00539a037
PDF
General methodology for cis-hydroisoquinoline synthesis: synthesis of reserpine
P. A. Wender, J. M. Schaus, and A. W. White
pp 6157 - 6159; DOI:
10.1021/ja00539a038
PDF
Isolation of diazacycloheptatetraenes from thermal nitrene-nitrene rearrangements
Curt Wentrup and Hans Wilhelm Winter
pp 6159 - 6161; DOI:
10.1021/ja00539a039
PDF
A stereocontrolled synthesis of (+)-thienamycin
Thomas N. Salzmann, R. W. Ratcliffe, B. G. Christensen, and F. A. Bouffard
pp 6161 - 6163; DOI:
10.1021/ja00539a040
PDF
Fragmentation reactions of .alpha.-alkoxy hydroperoxides and application to the synthesis of the macrolide (.+-.)-recifeiolide
Stuart L. Schreiber
pp 6163 - 6165; DOI:
10.1021/ja00539a041
PDF
Isotopic oxygen-18 shifts in phosphorus-31 NMR as a probe of stereochemistry of hydrolysis in phosphate triesters
David G. Gorenstein and Robert Rowell
pp 6165 - 6166; DOI:
10.1021/ja00539a042
PDF
A new process for sensitization of ketone photoreduction: exploitation of low-lying metal-to-ketone charge-transfer excited states
Susan M. Fredericks and Mark S. Wrighton
pp 6166 - 6168; DOI:
10.1021/ja00539a043
PDF
Methyl reactivity in deazalumazines
Ross Stewart, S. J. Gumbley, and R. Srinivasan
pp 6168 - 6169; DOI:
10.1021/ja00539a044
PDF
Mercury(I)/(II): a novel trap for harvesting excited-state energies
B. A. DeGraff and J. N. Demas
pp 6169 - 6171; DOI:
10.1021/ja00539a045
PDF
Synthesis of 3-azacephalosporins
Matsuhiko Aratani and Masashi Hashimoto
pp 6171 - 6172; DOI:
10.1021/ja00539a046
PDF
Calculated spin densities and quadrupole splitting for model horseradish peroxidase compound I: evidence for iron(IV) porphyrin (S = 1) .pi. cation radical electronic structure
Gilda H. Loew and Zelek S. Herman
pp 6173 - 6174; DOI:
10.1021/ja00539a047
PDF
Gas-phase complexes of copper(1+) and silver(1+) via thermionic emission sources
Paul M. Holland and A. W. Castleman
pp 6174 - 6175; DOI:
10.1021/ja00539a048
PDF
Fluxional behavior of [Rh14(CO)25H4-n]n- (n = 3 and 4)
Brian T. Heaton, Charles Brown, David O. Smith, Luisella Strona, Robin J. Goodfellow, Paolo Chini, and Secondo Martinengo
pp 6175 - 6177; DOI:
10.1021/ja00539a049
PDF
Varying selectivities of triplet ketones toward p-cymene: a measure of the extent of charge transfer in triplet exciplexes
Peter J. Wagner and Allen E. Puchalski
pp 6177 - 6178; DOI:
10.1021/ja00539a050
PDF
A chiral synthesis of the left-side aldehyde for lasalocid A synthesis
Robert E. Ireland, Glenn J. McGarvey, Robert C. Anderson, Raphael Badoud, Brian Fitzsimmons, and Suvit Thaisrivongs
pp 6178 - 6180; DOI:
10.1021/ja00539a051
PDF
First successful ENDOR studies of organic radical ions in liquid crystals
B. Kirste and H. Kurreck
pp 6180 - 6181; DOI:
10.1021/ja00539a052
PDF
Reactions of diazomethane on transition-metal surfaces and their relationship to the mechanism of the Fischer-Tropsch reaction
Robert C. Brady and R. Pettit
pp 6181 - 6182; DOI:
10.1021/ja00539a053
PDF
Homogeneous catalysts for utilization of synthesis gas as a reducing agent
T. Cole, R. Ramage, K. Cann, and R. Pettit
pp 6182 - 6184; DOI:
10.1021/ja00539a054
PDF
Intramolecular proton exchange in aqueous histamine. An NMR method for resolving the ammonium and imidazole proton-exchange rates
Earle K. Ralph and John N. Atherton
pp 6184 - 6185; DOI:
10.1021/ja00539a055
PDF
Synthetic methods. 16. Umpolung of alkyl anions by reactions with vinyl azides. In situ generation of primary enamines
Alfred Hassner and Benjamin A. Belinka
pp 6185 - 6186; DOI:
10.1021/ja00539a056
PDF
Book Reviews

pp 6187 - 6188; DOI:
10.1021/ja00539a600
PDF

Issue 20


Collisional activation and metastable ion characteristics. 79. Gaseous HCN+, HNC+, and HCNH+ ions
Fred W. McLafferty and Donald C. McGilvery
pp 6189 - 6190; DOI:
10.1021/ja00540a001
PDF
A multinuclear NMR spin labeling investigation of the solution structure of the base stacked manganese(2+)-AMP complex
George C. Levy and James J. Dechter
pp 6191 - 6196; DOI:
10.1021/ja00540a002
PDF
Role of diffusion in trigger wave propagation in the Belousov-Zhabotinskii reaction
Jacob Jorne
pp 6196 - 6198; DOI:
10.1021/ja00540a003
PDF
Theoretical study of the optical absorption and magnetic circular dichroism spectra of cyclopropane
Elisheva Goldstein, Saraswathy Vijaya, and Gerald A. Segal
pp 6198 - 6204; DOI:
10.1021/ja00540a004
PDF
Triplet methylnitrene: an indefinitely stable species in the absence of collisions
Jean Demuynck, Douglas J. Fox, Yukio Yamaguchi, and Henry F. Schaefer
pp 6204 - 6207; DOI:
10.1021/ja00540a005
PDF
Ab initio self-consistent field calculations on some small amino acids
Lance R. Wright and Raymond R. Borkman
pp 6207 - 6210; DOI:
10.1021/ja00540a006
PDF
pH-modulated pigment antenna in lipid bilayer on photosensitized semiconductor electrode
Peter Fromherz and Wolfgang Arden
pp 6211 - 6218; DOI:
10.1021/ja00540a007
PDF
An empirical valence bond approach for comparing reactions in solutions and in enzymes
Arieh Warshel and Robert M. Weiss
pp 6218 - 6226; DOI:
10.1021/ja00540a008
PDF
Affinities of imidazolate and imidazole ligands for pentacyanoiron(III)
Craig R. Johnson, Rex E. Shepherd, Bonnie Marr, Stephen O'Donnell, and Walter Dressick
pp 6227 - 6235; DOI:
10.1021/ja00540a009
PDF
Multiple metal-carbon bonds. 15. Octahedral alkylidene complexes of niobium and tantalum by ligand-promoted .alpha. abstraction
Gregory A. Rupprecht, Louis W. Messerle, Jere D. Fellmann, and Richard R. Schrock
pp 6236 - 6244; DOI:
10.1021/ja00540a010
PDF
Stereoelectronic properties of metalloenzymes. 6. Effects of anions and ferricyanide on the copper(II) site of the histidine and the tryptophan modified forms of galactose oxidase
Marjorie E. Winkler and Robert D. Bereman
pp 6244 - 6247; DOI:
10.1021/ja00540a011
PDF
The mechanism of substitution of dicobalt octacarbonyl
Ma'mun Absi-Halabi, Jim D. Atwood, Nancy P. Forbus, and Theodore L. Brown
pp 6248 - 6254; DOI:
10.1021/ja00540a012
PDF
On the thermal sigmatropic rearrangement of allenic retinoids: 12,14-retro-retinol
Javier Sueiras and William H. Okamura
pp 6255 - 6259; DOI:
10.1021/ja00540a013
PDF
Studies on vitamin D (calciferol) and its analogs. 18. The vinylallene approach to the 1-hydroxyvitamin D system. New sigmatropic reactions in the vitamin D series
Patrick Condran, Milton L. Hammond, Antonio Mourino, and William H. Okamura
pp 6259 - 6267; DOI:
10.1021/ja00540a014
PDF
Evidence for a solvent-induced change in rate-limiting step in the hydrolysis of benzaldehyde dimethyl acetal
Paul R. Young, Roy C. Bogseth, and Edward G. Rietz
pp 6268 - 6271; DOI:
10.1021/ja00540a015
PDF
Photophysics of aqueous tryptophan: pH and temperature effects
R. J. Robbins, G. R. Fleming, G. S. Beddard, G. W. Robinson, P. J. Thistlethwaite, and G. J. Woolfe
pp 6271 - 6279; DOI:
10.1021/ja00540a016
PDF
Chemical properties of the fulvene radical cation: a cycloaddition with 1,3-butadiene
David H. Russell and M. L. Gross
pp 6279 - 6284; DOI:
10.1021/ja00540a017
PDF
Antiallergenic 8-azapurines. 2. Structural characterization of 2-phenyl-7-methyl-8-azahypoxanthine and 2-phenyl-8-methyl-8-azahypoxanthine
Susan J. Cline and Derek J. Hodgson
pp 6285 - 6288; DOI:
10.1021/ja00540a018
PDF
Applications of artificial intelligence for chemical inference. 33. Computer-assisted elucidation of molecular structure with stereochemistry
James G. Nourse, Dennis H. Smith, Raymond E. Carhart, and Carl Djerassi
pp 6289 - 6295; DOI:
10.1021/ja00540a019
PDF
Mechanisms of elimination reactions. 32. Tritium isotope effects and tunnel effects in the reaction of 2,2-diphenylethyl-2-t derivatives with various bases
Sheena B. Kaldor, Mark E. Fredenburg, and William H. Saunders
pp 6296 - 6299; DOI:
10.1021/ja00540a020
PDF
Mechanism of acid-catalyzed proton exchange in amidinium ions
Charles L. Perrin, Eric R. Johnston, and Jose L. Ramirez
pp 6299 - 6304; DOI:
10.1021/ja00540a021
PDF
Total synthesis of (R)-glycerol acetonide and the antiepileptic and hypotensive drug (-)-.gamma.-amino-.beta.-hydroxybutyric acid (GABOB): use of vitamin C as a chiral starting material
Michael E. Jung and Teresa J. Shaw
pp 6304 - 6311; DOI:
10.1021/ja00540a022
PDF
A short new azulene synthesis
Lawrence T. Scott, Mark A. Minton, and Mark A. Kirms
pp 6311 - 6314; DOI:
10.1021/ja00540a023
PDF
Stereochemistry of indolmycin biosynthesis. Steric course of C- and N-methylation reactions
Ronald W. Woodard, Leonard Mascaro, Rolf Hoerhammer, Stephen Eisenstein, and Heinz G. Floss
pp 6314 - 6318; DOI:
10.1021/ja00540a024
PDF
Enthalpy changes accompanying hydrolysis of 3-(2-furyl)acryloylimidazole by .alpha.-chymotrypsin
J. L. Slightom and D. W. Bolen
pp 6318 - 6324; DOI:
10.1021/ja00540a025
PDF
Enzyme immobilization by condensation copolymerization into crosslinked polyacrylamide gels
Alfred Pollak, Hugh Blumenfeld, Michael Wax, Richard L. Baughn, and George M. Whitesides
pp 6324 - 6336; DOI:
10.1021/ja00540a026
PDF
Free-radical dynamics in organized lipid bilayers
J. S. Winterle and T. Mill
pp 6336 - 6338; DOI:
10.1021/ja00540a027
PDF
Synthesis of new heteropolymetallic compounds with carbonylmetallate anions as bridges between two palladium atoms: x-ray crystal structures of [{PdNMe2CH2C6H4}2.mu.-{Co(CO)4}.mu.Cl] and [{PdNMe2CH2C6H4}2.mu.-{Mo(CO)3(.eta.-C5H5)}.mu.Cl]
Michel Pfeffer, Jean Fischer, Andre Mitschler, and Louis Ricard
pp 6338 - 6339; DOI:
10.1021/ja00540a028
PDF
Total synthesis of (.+-.)-isabelin
Paul A. Wender and John C. Lechleiter
pp 6340 - 6341; DOI:
10.1021/ja00540a029
PDF
Two-dimensional coordination polymers of rhodium(1+) with rigid collinear diisocyanide bridges and stacked layers arrangement
Avi Efraty, Irene Feinstein, Felix Frolow, and Lorenz Wackerle
pp 6341 - 6343; DOI:
10.1021/ja00540a030
PDF
Boron analogs of the .alpha.-amino acids. Synthesis, x-ray crystal structure, and biological activity of ammonia-carboxyborane, the boron analog of glycine
Bernard F. Spielvogel, Mrinal K. Das, Andrew T. McPhail, Kay D. Onan, and Iris H. Hall
pp 6343 - 6344; DOI:
10.1021/ja00540a031
PDF
Synthesis, structure, and equilibration of s-cis- and s-trans- .eta.4-conjugated diene-zirconocene complexes
Gerhard Erker, Joachim Wicher, Klaus Engel, Frank Rosenfeldt, Wolfgang Dietrich, and Carl Krueger
pp 6344 - 6346; DOI:
10.1021/ja00540a032
PDF
Synthesis and reactivity of several trithiocarbamate complexes of osmium(III) and the crystal and molecular structures of [Os2(S3CNMe2)2(S2CNMe2)3]PF6 and Os2(S5)(S3CNEt2)(S2CNEt2)3
L. J. Maheu and L. H. Pignolet
pp 6346 - 6348; DOI:
10.1021/ja00540a033
PDF
Dimolybdenum: nature of the sextuple bond
Bruce E. Bursten, F. Albert Cotton, and Michael B. Hall
pp 6348 - 6349; DOI:
10.1021/ja00540a034
PDF
Evidence for the nonexistence of a (.eta.3-1-silapropenyl)tricarbonyliron complex. A correction
P. Radnia and J. S. McKennis
pp 6349 - 6351; DOI:
10.1021/ja00540a035
PDF
Total synthesis of (.+-.)-hirsutene
Tomas Hudlicky, Toni M. Kutchan, Stephen R. Wilson, and David T. Mao
pp 6351 - 6353; DOI:
10.1021/ja00540a036
PDF
Synthesis of (.+-.)-coronafacic acid. Efficient intramolecular Diels-Alder reaction of latent diene-dienophile functionality via thermal reaction
Akitami Ichihara, Ryoji Kimura, Seiichiro Yamada, and Sadao Sakamura
pp 6353 - 6355; DOI:
10.1021/ja00540a037
PDF
[1,5]-Sigmatropic rearrangement of vinylallenes: a novel route to geometric isomers of the retinoids possessing 11-cis linkages including 9,11,13-tricis-retinal
Christopher G. Knudsen, Stephen C. Carey, and William H. Okamura
pp 6355 - 6356; DOI:
10.1021/ja00540a038
PDF
Resolution of racemic compounds by optically active poly(triphenylmethyl methacrylate)
Heimei Yuki, Yoshio Okamoto, and Ichiro Okamoto
pp 6356 - 6358; DOI:
10.1021/ja00540a039
PDF
Stereochemistry of the enzymic cyclization of copalyl pyrophosphate to kaurene in enzyme preparations from Marah macrocarpus
Robert M. Coates and Patricia L. Cavender
pp 6358 - 6359; DOI:
10.1021/ja00540a040
PDF
Nature of a trimethylenemethane-palladium complex
Barry M. Trost and Dominic M. T. Chan
pp 6359 - 6361; DOI:
10.1021/ja00540a041
PDF
Preparation and characterization of novel dication ether salts: Ar+OAr+.cntdot.2CF3SO3-
Peter J. Stang, Gerhard Maas, and Thomas E. Fisk
pp 6361 - 6362; DOI:
10.1021/ja00540a042
PDF
Transfer of hydrogen from orthoamides. Reduction of protons to molecular hydrogen
Jeanette M. Erhardt and James D. Wuest
pp 6363 - 6364; DOI:
10.1021/ja00540a043
PDF
Tricyclic trisaminomethanes
Thomas J. Atkins
pp 6364 - 6365; DOI:
10.1021/ja00540a044
PDF
Transfer of hydrogen from orthoamides. Synthesis, structure, and reactions of hexahydro-6bH-2a,4a,6a-triazacyclopenta[cd]pentalene and perhydro-3a,6a,9a-triazaphenalene
Jeanette M. Erhardt, Edward R. Grover, and James D. Wuest
pp 6365 - 6369; DOI:
10.1021/ja00540a045
PDF
Reactions with olefins in condensed phases of oxygen(3P) atoms produced by microwave discharge
Elazar Zadok, Dan Amar, and Yehuda Mazur
pp 6369 - 6370; DOI:
10.1021/ja00540a046
PDF
Nonbleachable rhodopsins retaining the full natural chromophore
Hiroyuki Akita, Steven P. Tanis, Michael Adams, Valeria Balogh-Nair, and Koji Nakanishi
pp 6370 - 6372; DOI:
10.1021/ja00540a047
PDF
Enhanced optical activity associated with chiral 1-(1-hydroxyhexyl)pyrene excimer formation
Harry Brittain, Deborah L. Ambrozich, Masahiko Saburi, and Janos H. Fendler
pp 6372 - 6374; DOI:
10.1021/ja00540a048
PDF
Alkane activation and functionalization under mild conditions by a homogeneous manganese(III)porphyrin-iodosylbenzene oxidizing system
Craig L. Hill and Bruce C. Schardt
pp 6374 - 6375; DOI:
10.1021/ja00540a049
PDF
Hydrocarbon oxidations with oxometalloporphinates. Isolation and reactions of a (porphinato)manganese(V) complex
John T. Groves, William J. Kruper, and Robert C. Haushalter
pp 6375 - 6377; DOI:
10.1021/ja00540a050
PDF
Application of tritium NMR spectroscopy in the determination of the stereochemistry of dehydrogenation of isobutyryl CoA in Pseudomonas putida
D. John Aberhart and Chou-Hong Tann
pp 6377 - 6380; DOI:
10.1021/ja00540a051
PDF
Angular momentum, the principle of equal a priori probabilities, and "intermolecular entropy corrections" in equilibriums of ions and molecules in the gas phase
G. G. Meisels
pp 6380 - 6381; DOI:
10.1021/ja00540a052
PDF
Facile generation of a reactive palladium(II) enolate intermediate by the decarboxylation of palladium(II) .beta.-ketocarboxylate and its utilization in allylic acylation
Tetsuo Tsuda, Yoshiki Chujo, Seiichi Nishi, Kunio Tawara, and Takeo Saegusa
pp 6381 - 6384; DOI:
10.1021/ja00540a053
PDF
Mechanism of triazolinedione-olefin reactions. Ene and cycloaddition
Catherine A. Seymour and Frederick D. Greene
pp 6384 - 6385; DOI:
10.1021/ja00540a054
PDF
Reductive phenylation of nitroarenes
Toshiharu Ohta, Ryosuke Machida, Kei Takeda, Yasuyuki Endo, Koichi Shudo, and Toshihiko Okamoto
pp 6385 - 6386; DOI:
10.1021/ja00540a055
PDF
Intramolecular [2 + 2] cycloaddition reactions of indene derivatives as a route to polycyclic strained ring systems
Albert Padwa and Mitchell Pulwer
pp 6386 - 6388; DOI:
10.1021/ja00540a056
PDF
Assignment of proton-decoupled carbon-13 spectra of complex molecules by using polarization transfer spectroscopy. A superior method to off-resonance decoupling
David M. Doddrell and David T. Pegg
pp 6388 - 6390; DOI:
10.1021/ja00540a057
PDF
Book Reviews

pp 6390 - 6392; DOI:
10.1021/ja00540a600
PDF

Issue 21


Internal and external solvation of polyfunctional ions
Michael Meot-Ner, Peter Hamlet, Edward P. Hunter, and Frank H. Field
pp 6393 - 6399; DOI:
10.1021/ja00541a001
PDF
Resonance Raman spectra of bacteriochlorophyll and its electrogenerated cation radical. Excitation of the Soret bands by use of stimulated Raman scattering from hydrogen and deuterium
Therese M. Cotton, Keith D. Parks, and Richard P. Van Duyne
pp 6399 - 6407; DOI:
10.1021/ja00541a002
PDF
Pulsed IR laser study of half-chair to boat interconversion of 2,3-dihydropyran
Dana Garcia and Ernest Grunwald
pp 6407 - 6411; DOI:
10.1021/ja00541a003
PDF
Excited states of methano-bridged [10]-, [14]-, and [18]annulenes. Evidence for strong transannular interaction, and relation to homoaromaticity
Harry J. Dewey, Hans Deger, Wolfgang Froelich, Bernhard Dick, Kenneth A. Klingensmith, Georg Hohlneicher, Emanuel Vogel, and Josef Michl
pp 6412 - 6417; DOI:
10.1021/ja00541a004
PDF
Oxygen-17 nuclear quadrupole double resonance spectroscopy. 3. Results for nitrogen-oxygen, phosphorus-oxygen, and sulfur-oxygen bonds
C. P. Cheng and Theodore L. Brown
pp 6418 - 6421; DOI:
10.1021/ja00541a005
PDF
Effect of hydration and ribose ring puckering on the enthalpy of hydrolysis of cyclic adenosine 3',5'-monophosphate. A quantum-chemical study
Miek M. E. Scheffers-Sap and Henk M. Buck
pp 6422 - 6424; DOI:
10.1021/ja00541a006
PDF
Substituent effect on the fifth overtone of aryl carbon-hydrogen stretching vibrations
Yoshihiro Mizugai and Mikio Katayama
pp 6424 - 6426; DOI:
10.1021/ja00541a007
PDF
Homoconjugation vs. charge dipole interaction effects in the stabilization of carbanions in the gas phase
A. J. Noest and N. M. M. Nibbering
pp 6427 - 6429; DOI:
10.1021/ja00541a008
PDF
A theoretical approach to the Birch reduction. Structures and stabilities of cyclohexadienyl anions
Arthur J. Birch, Alan L. Hinde, and Leo Radom
pp 6430 - 6437; DOI:
10.1021/ja00541a009
PDF
A triple bond between osmium atoms. Preparation and structure of dichlorotetrakis(2-hydroxy-pyridinato)diosmium(III)
F. Albert Cotton and J. Lon Thompson
pp 6437 - 6441; DOI:
10.1021/ja00541a010
PDF
Intersystem-crossing dynamics and coordination geometry changes observed by ultrasonic and laser temperature-jump relaxation of the 2T .dblharw. 6A spin equilibrium of hexadentate iron(III) complexes in solution
Robert A. Binstead, James K. Beattie, T. G. Dewey, and Douglas H. Turner
pp 6442 - 6451; DOI:
10.1021/ja00541a011
PDF
Dynamic properties of phosphinehydridorhodium(I) complexes and the structure of tris(triisopropylphosphine)hydridorhodium(I), RhH(P(i-Pr)3)3
T. Yoshida, David L. Thorn, T. Okano, Sei Otsuka, and James A. Ibers
pp 6451 - 6457; DOI:
10.1021/ja00541a012
PDF
Mechanism of thermal decomposition of trans-diethylbis(tertiary phosphine)palladium(II). Steric effects of tertiary phosphine ligands on the stability of diethylpalladium complexes
Fumiyuki Ozawa, Takashi Ito, and Akio Yamamoto
pp 6457 - 6463; DOI:
10.1021/ja00541a013
PDF
.alpha.-Deuterium isotope effects in benzyl halides. 2. Reaction of nucleophiles with substituted benzyl bromides. Evidence for a change in transition-state structure with electron-donating substituents
V. P. Vitullo, J. Grabowski, and S. Sridharan
pp 6463 - 6465; DOI:
10.1021/ja00541a014
PDF
Nonenforced concerted general-acid catalysis of the dehydration step in formaldehyde thiosemicarbazone formation
John L. Palmer and William P. Jencks
pp 6466 - 6472; DOI:
10.1021/ja00541a015
PDF
Secondary .alpha.-deuterium isotope effects for the cleavage of formaldehyde hemiacetals through concerted and specific-base-catalyzed pathways
John L. Palmer and William P. Jencks
pp 6472 - 6481; DOI:
10.1021/ja00541a016
PDF
.pi.-Facial stereoselectivity: rates and stereoselectivities of cycloadditions of hexachlorocyclopentadiene to 7-substituted norbornadienes and photoelectron spectral and molecular orbital computation investigations of norbornadienes
Paul H. Mazzocchi, Barbara Stahly, John Dodd, Nelson G. Rondan, L. N. Domelsmith, Melvin D. Rozeboom, Pierluigi Caramella, and K. N. Houk
pp 6482 - 6490; DOI:
10.1021/ja00541a017
PDF
Hypovalent radicals. 4. Gas-phase studies of the ion-molecule reactions of cyclopentadienylidene anion radical in a flowing afterglow
Richard N. McDonald, A. Kasem Chowdhury, and D. W. Setser
pp 6491 - 6498; DOI:
10.1021/ja00541a018
PDF
Oxidation of amines by a 4a-hydroperoxyflavin
Sheldon Ball and Thomas C. Bruice
pp 6498 - 6503; DOI:
10.1021/ja00541a019
PDF
Thallium in organic synthesis. 58. Regiospecific intermolecular oxidative dehydrodimerization of aromatic compounds to biaryls using thallium(III) trifluoroacetate
Alexander McKillop, Andrew G. Turrell, Derek W. Young, and Edward C. Taylor
pp 6504 - 6512; DOI:
10.1021/ja00541a020
PDF
Thallium in organic synthesis. 59. Alkaloid synthesis via intramolecular nonphenolic oxidative coupling. Preparation of (.+-.)-ocoteine, (.+-.)-acetoxyocoxylonine, (.+-.)-3-methoxy-n-acetylnornantenine, (.+-.)-neolitsine, (.+-.)-kreysigine, (.+-.)-O-methylkreysigine, and (.+-.)-multifloramine
Edward C. Taylor, Juan G. Andrade, Gerhardus J. H. Rall, and Alexander McKillop
pp 6513 - 6519; DOI:
10.1021/ja00541a021
PDF
Reaction of 1-chloro-2-alkylcycloalkenes with organolithium reagents. A novel cyclopropanation reaction involving the generation of carbenes from vinyl halides
Paul G. Gassman, Joseph J. Valcho, Gary S. Proehl, and Charles F. Cooper
pp 6519 - 6526; DOI:
10.1021/ja00541a022
PDF
Mechanistic characterization of the intermediates in the thermal and photochemical deazetation of two isomeric methylenepyrazolines, 7-isopropylidene-2,3-diazabicyclo[2.2.1]hept-2-ene and 2,2-dimethyl-3,4-diazabicyclo[3.3.0]octa-3,8-diene. An aproach to the generation and capture of protoplanar and protobisected trimethylene methanes
Dorothy A. Cichra, Charles D. Duncan, and Jerome A. Berson
pp 6527 - 6533; DOI:
10.1021/ja00541a023
PDF
Mechanistic aspects of the electrochemical oxidation of dihydronicotinamide adenine dinucleotide (NADH)
Jacques Moiroux and Philip J. Elving
pp 6533 - 6538; DOI:
10.1021/ja00541a024
PDF
Synthesis of nonreducible bicyclic analogs of somatostatin
Ruth F. Nutt, Daniel F. Veber, and Richard Saperstein
pp 6539 - 6545; DOI:
10.1021/ja00541a025
PDF
Kinetic studies on reactions of iron-sulfur proteins. 3. Oxidation of the reduced form of Clostridium pasteurianum 8-iron ferredoxin with inorganic complexes. Observation of single-stage kinetics for a difunctional protein reactant
Fraser A. Armstrong, Richard A. Henderson, and A. Geoffrey Sykes
pp 6545 - 6551; DOI:
10.1021/ja00541a026
PDF
Origin of macrocyclic enthalpy
Robert D. Hancock and Gloria J. McDougall
pp 6551 - 6553; DOI:
10.1021/ja00541a027
PDF
Mechanism of ejection of organic molecules from surfaces by keV ion bombardment
Barbara J. Garrison
pp 6553 - 6555; DOI:
10.1021/ja00541a028
PDF
An efficient photocathode for semiconductor liquid junction cells: 9.4% solar conversion efficiency with p-InP/VCl3-VCl2-HCl/C
A. Heller, B. Miller, H. J. Lewerenz, and K. J. Bachmann
pp 6555 - 6556; DOI:
10.1021/ja00541a029
PDF
Theoretical study of a low-energy UV transition in a 2,6-dithiaadamantane derivative
Samuel Braverman, Drora Cohen, David Reisman, and Harold Basch
pp 6556 - 6558; DOI:
10.1021/ja00541a030
PDF
Chelation of the sodium cation by polyamines: a novel approach to preferential solvation, and to the understanding of sodium-23 chemical shifts and quadrupolar coupling constants
Alfred Delville, Christian Detellier, Andre Gerstmans, and Pierre Laszlo
pp 6558 - 6559; DOI:
10.1021/ja00541a031
PDF
Mediated photochemical oxidative dimerization
Marye Anne Fox and Robert C. Owen
pp 6559 - 6561; DOI:
10.1021/ja00541a032
PDF
Possibility of .pi.-electron donation by the electron-withdrawing substituents CN, CHO, CF3, and +NH3
Michael N. Paddon-Row, Cielo Santiago, and K. N. Houk
pp 6561 - 6563; DOI:
10.1021/ja00541a033
PDF
Dynamics and energetics of the singlet-triplet interconversion of diphenylcarbene
K. B. Eisenthal, N. J. Turro, M. Aikawa, J. A. Butcher, C. DuPuy, G. Hefferon, W. Hetherington, G. M. Korenowski, and M. J. McAuliffe
pp 6563 - 6565; DOI:
10.1021/ja00541a034
PDF
Mobility of solvent molecules in a nonaqueous lyotropic liquid crystal
David W. Larsen, Stig E. Friberg, and Hugo Christenson
pp 6565 - 6566; DOI:
10.1021/ja00541a035
PDF
Theory versus experiment: the case of glycine
Lothar Schaefer, H. L. Sellers, F. J. Lovas, and R. D. Suenram
pp 6566 - 6568; DOI:
10.1021/ja00541a036
PDF
Molecular structure of Mo(CO)2[S2CN-i-Pr2]2. A trigonal-prismatic electron-deficient molybdenum(II) carbonyl derivative
Joseph L. Templeton and Bennett C. Ward
pp 6568 - 6569; DOI:
10.1021/ja00541a037
PDF
An osmium-carbyne complex
George R. Clark, Karen Marsden, Warren R. Roper, and L. James Wright
pp 6570 - 6571; DOI:
10.1021/ja00541a038
PDF
1:14 Heteropolyvanadate of phosphorus: preparation and structure
R. Kato, A. Kobayashi, and Y. Sasaki
pp 6571 - 6572; DOI:
10.1021/ja00541a039
PDF
Olefin metathesis reaction: characterization of an active catalyst precursor, CH3WOCl3.O(C2H5)2, from the WOCl4-(CH3)2Mg reaction
E. Band and E. L. Muetterties
pp 6572 - 6574; DOI:
10.1021/ja00541a040
PDF
Positive halogen cryptate: complexation of iodine with [2.2.2]cryptand
Jean Louis Pierre, Henri Handel, Pierre Labbe, and Raymond Le Goaller
pp 6574 - 6575; DOI:
10.1021/ja00541a041
PDF
Metal-metal distances in a platinum acetamide blue
M. P. Laurent, J. Biscoe, and H. H. Patterson
pp 6575 - 6576; DOI:
10.1021/ja00541a042
PDF
Interception of the Cope chairlike transition-state product during the tandem Cope-Claisen rearrangement: a route to an ambrosanolide synthon
Frederick E. Ziegler and John J. Piwinski
pp 6576 - 6577; DOI:
10.1021/ja00541a043
PDF
Total synthesis of pseudomonic acid C: application of the alkoxyselenation reaction in organic synthesis
A. P. Kozikowski, R. J. Schmiesing, and K. L. Sorgi
pp 6577 - 6580; DOI:
10.1021/ja00541a044
PDF
Stereoselective synthesis of brassinolide: a plant growth promoting steroidal lactone
Steven Fung and John B. Siddall
pp 6580 - 6581; DOI:
10.1021/ja00541a045
PDF
New manganese(III)-containing acid phosphatase. Evidence for an intense charge-transfer band and tyrosine phenolate coordination
Yukio Sugiura, Hideo Kawabe, and Hisashi Tanaka
pp 6581 - 6582; DOI:
10.1021/ja00541a046
PDF
Stereochemistry of chlorinolysis of the phosphorus-sulfur bond in thiolesters of organic phosphorus thio acids. Reaction of S-methyl tert-(butylphenylphosphino)thiolate with halogens and sulfuryl chloride
B. Krawiecka, J. Michalski, and E. Tadeusiak
pp 6582 - 6584; DOI:
10.1021/ja00541a047
PDF
Arene-metal complexes in organic synthesis: addition to styrene-type ligands
M. F. Semmelhack, Walter Seufert, and Leonard Keller
pp 6584 - 6586; DOI:
10.1021/ja00541a048
PDF
Oxidative decomposition of a mononitrobenzenesulfenate ion in 15.3 M potassium hydroxide via a stable Meisenheimer complex
Robert L. Blakeley and Burt Zerner
pp 6586 - 6587; DOI:
10.1021/ja00541a049
PDF
Photochemistry of 4-hydroxybenzothiazole: a model for pheomelanin photodegradation
Miles R. Chedekel, Edward J. Land, Roy S. Sinclair, David Tait, and T. George Truscott
pp 6587 - 6590; DOI:
10.1021/ja00541a050
PDF
Preequilibrium carbon protonation in the acid-catalyzed hydrolysis of a phenylketene dithioacetal
Tadashi Okuyama and Takayuki Fueno
pp 6590 - 6591; DOI:
10.1021/ja00541a051
PDF
Structure elucidation with lanthanide-induced shifts. 8. Geometry of europium-ketone complexes
Douglas J. Raber, Christopher M. Janks, Milton D. Johnston, and Nancy K. Raber
pp 6591 - 6594; DOI:
10.1021/ja00541a052
PDF
Oxygen chiral phosphodiesters. 2. Enzymic synthesis and configurational analysis of [.alpha.-18O]-2'-deoxyadenosine 5'-diphosphate
Jeffrey A. Coderre and John A. Gerlt
pp 6594 - 6597; DOI:
10.1021/ja00541a053
PDF
Total synthesis of (.+-.)-maytansinol. The common precursor to the maytansinoids
A. I. Meyers, Paul J. Reider, and Arthur L. Campbell
pp 6597 - 6598; DOI:
10.1021/ja00541a054
PDF
Possible mechanisms of demethylation of 14.alpha.-methyl sterols in cholesterol biosynthesis
Robert A. Pascal, Peter Chang, and George J. Schroepfer
pp 6599 - 6601; DOI:
10.1021/ja00541a055
PDF
Determination of the absolute configuration of [16O,17O,18O]phosphate monoesters by using phosphorus-31 NMR
Stephen L. Buchwald and Jeremy R. Knowles
pp 6601 - 6602; DOI:
10.1021/ja00541a056
PDF
Bioorganic synthesis and absolute configuration of faranal
Masaki Kobayashi, Tanetoshi Koyama, Kyozo Ogura, Shuichi Seto, F. J. Ritter, and I. E. M. Brueggemann-Rotgans
pp 6602 - 6604; DOI:
10.1021/ja00541a057
PDF
Conformational and electronic control of anionic rearrangements of 4-hydroxycyclohex-2-en-1-ones
John R. Scheffer and Yiu-Fai Wong
pp 6604 - 6605; DOI:
10.1021/ja00541a058
PDF
Biosynthesis of lipoic acid: extent of incorporation of deuterated hydroxy- and thiooctanoic acids into lipoic acid
Robert H. White
pp 6605 - 6607; DOI:
10.1021/ja00541a059
PDF
Simple synthesis of the 11,12-oxido and 14,15-oxido analogs of leukotriene A and the corresponding conjugates with glutathione and cysteinylglycine, analogs of leukotrienes C and D
E. J. Corey, Giichi Goto, and Anthony Marfat
pp 6607 - 6608; DOI:
10.1021/ja00541a060
PDF
Tantalum-neopentylidene hydride and tantalum-neopentylidyne hydride complexes
J. D. Fellmann, H. W. Turner, and R. R. Schrock
pp 6608 - 6609; DOI:
10.1021/ja00541a061
PDF
Total synthesis of (.+-.)-zoapatanol
R. Chen and D. A. Rowand
pp 6609 - 6611; DOI:
10.1021/ja00541a062
PDF
Total synthesis of (.+-.)-zoapatanol
K. C. Nicolaou, D. A. Claremon, and W. E. Barnette
pp 6611 - 6612; DOI:
10.1021/ja00541a063
PDF
Total synthesis of maytansine
E. J. Corey, Leland O. Weigel, A. Richard Chamberlin, Hidetsura Cho, and Duy H. Hua
pp 6613 - 6615; DOI:
10.1021/ja00541a064
PDF
An equilibrium between carbene and a metal-carbene complex. Homogeneous catalysis by mercury(II)
Joseph B. Lambert, Paul H. Mueller, and Peter P. Gaspar
pp 6615 - 6616; DOI:
10.1021/ja00541a065
PDF
Cobalt-nitro complexes as oxygen transfer agents: oxidation of olefins
Benjamin S. Tovrog, Frank Mares, and Steven E. Diamond
pp 6616 - 6618; DOI:
10.1021/ja00541a066
PDF
A direct NMR method for the determination of correlation times in enzyme complexes involving monovalent cations and paramagnetic centers
Frank M. Raushel and Joseph J. Villafranca
pp 6618 - 6619; DOI:
10.1021/ja00541a067
PDF
Theoretical models for transition-state structure and catalysis in carbonyl addition
Ian H. Williams, Dale Spangler, Douglas A. Femec, Gerald M. Maggiora, and Richard L. Schowen
pp 6619 - 6621; DOI:
10.1021/ja00541a068
PDF
Clusterification of reactive species generated through chemical reduction of metallocenes: synthesis and stereochemical characterization of a new hexameric series of metal-cyclopentadienyl clusters, [Ni6(.eta.5-C5H5)6]n (n = 0, + 1)
Michael S. Paquette and Lawrence F. Dahl
pp 6621 - 6623; DOI:
10.1021/ja00541a069
PDF
Photochemical formation and stereochemical characterization of two electronically equivalent but structurally different series of triangular dicobalt-metal clusters, MCo2(.eta.5-C5Me5)2(.mu.-CO)3(.mu.3-CO) [M = Cr(.eta.6-C6H5Me), Mn(.eta.5-C5H4Me), Fe(.eta.4-C4H4)] and MCo2(.eta.5-C5Me5)2(.mu.-CO)2(.mu.3-CO) [M = Fe(CO)3, Co(.eta.5(C5H4Me)]: a rational synthesis of mixed-metal clusters by photogenerated metal-fragment addition across a metal-metal multiple-bonded dimer
Larry M. Cirjak, Jin-Shun Huang, Zhong-He Zhu, and Lawrence F. Dahl
pp 6623 - 6626; DOI:
10.1021/ja00541a070
PDF
General strategy for gibberellin synthesis: total syntheses of (.+-.)-gibberellin A1 and gibberellic acid
Luciano Lombardo, Lewis N. Mander, and John V. Turner
pp 6626 - 6628; DOI:
10.1021/ja00541a071
PDF
Total synthesis of gibberellic acid. The hydrofluorene route
James M. Hook, Lewis N. Mander, and Rudolf Urech
pp 6628 - 6629; DOI:
10.1021/ja00541a072
PDF
Synthesis of the pyrimidine moiety of bleomycin
Yoji Umezawa, Hajime Morishima, Seiichi Saito, Tomohisa Takita, Hamao Umezawa, Susumu Kobayashi, Masami Otsuka, Masatoshi Narita, and Masaji Ohno
pp 6630 - 6631; DOI:
10.1021/ja00541a073
PDF
Synthesis of the pyrimidine moieties of bleomycin and epi-bleomycin
Heihachiro Arai, William K. Hagmann, H. Suguna, and Sidney M. Hecht
pp 6631 - 6633; DOI:
10.1021/ja00541a074
PDF
5H-(Perfluoropentamethyl)cyclopentadiene, an extraordinary carbon acid
Evan D. Laganis and David M. Lemal
pp 6633 - 6634; DOI:
10.1021/ja00541a075
PDF
Stereospecific 1,3-dipolar cycloelimination in strained pyrazolines
Evan D. Laganis and David M. Lemal
pp 6634 - 6636; DOI:
10.1021/ja00541a076
PDF
Tricyclo[4.2.2.01,6]decane-tricyclo[4.2.2.01,5]decane interconversions. [4.2.2]propellane rearrangements and a nonphotochemical propellane synthesis
Philip E. Eaton, Patrick G. Jobe, and Kayson Nyi
pp 6636 - 6638; DOI:
10.1021/ja00541a077
PDF
Polymerized vesicles
Steven L. Regen, Bronislaw Czech, and Alok Singh
pp 6638 - 6640; DOI:
10.1021/ja00541a078
PDF
Stable carbocations. 232. Significant mesomeric nitrenium ion character of the cyanodiphenylmethyl cation. The first long-lived cyanocarbenium ion
George A. Olah, G. K. Surya Prakash, and Massoud Arvanaghi
pp 6640 - 6641; DOI:
10.1021/ja00541a079
PDF
Polymer films on electrodes. 4. Nafion-coated electrodes and electrogenerated chemiluminescence of surface-attached tris(2,2'-bipyridine)ruthenium(2+)
Israel Rubinstein and Allen J. Bard
pp 6641 - 6642; DOI:
10.1021/ja00541a080
PDF
Unique properties of chromophore-containing bilayer aggregates: enhanced chirality and photochemically induced morphological change
T. Kunitake, N. Nakashima, M. Shimomura, Y. Okahata, K. Kano, and T. Ogawa
pp 6642 - 6644; DOI:
10.1021/ja00541a081
PDF
Successful isolation of a reduced tetrathiometallate complex. Synthesis and structural characterization of the [(MoS4)2Fe]3- trianion
D. Coucouvanis, E. D. Simhon, and N. C. Baenziger
pp 6644 - 6646; DOI:
10.1021/ja00541a082
PDF
Exceptional micellar stereoselectivity in esterolysis reactions: the micelle-enzyme analogy
Robert A. Moss, Yoon-Sik Lee, and K. W. Alwis
pp 6646 - 6648; DOI:
10.1021/ja00541a083
PDF
Metal clusters with exposed and low-coordinate nitride nitrogen atoms
M. Tachikawa, Judith Stein, E. L. Muetterties, R. G. Teller, Mark A. Beno, E. Gebert, and Jack M. Williams
pp 6648 - 6649; DOI:
10.1021/ja00541a084
PDF
Bisannelation of arenes with bis-aryne equivalents
Harold Hart, Chung-Yin Lai, Godson Nwokogu, Shamouil Shamouilian, Avraham Teuerstein, and Chana Zlotogorski
pp 6649 - 6651; DOI:
10.1021/ja00541a085
PDF
Thiapen chemistry: synthesis of higher homologs of tetrathiafulvalene
Robert R. Schumaker and Edward M. Engler
pp 6651 - 6652; DOI:
10.1021/ja00541a086
PDF
Chemistry of exciplexes. 10. Role of excimers in photocycloadditions of arenes to 1,3-dienes
Nien-chu C. Yang, Hansen Shou, Toyuan Wang, and John Masnovi
pp 6652 - 6654; DOI:
10.1021/ja00541a087
PDF
2-(Diphenylphosphino)pyridine as a bridging ligand. Synthesis and structure of Rh2(Ph2Ppy)2(.mu.-CO)Cl2 and RhPd(Ph2Ppy)2(CO)Cl3
James P. Farr, Marilyn M. Olmstead, and Alan L. Balch
pp 6654 - 6656; DOI:
10.1021/ja00541a088
PDF
Book Reviews

pp 6656 - 6658; DOI:
10.1021/ja00541a600
PDF

Issue 22


Electronic interaction between the methyl group and trigonal carbon
Joseph B. Lambert and Ronald J. Nienhuis
pp 6659 - 6665; DOI:
10.1021/ja00542a001
PDF
Some differences between thermokinetic and chemical oscillating reactions
C. Vidal and A. Noyau
pp 6666 - 6671; DOI:
10.1021/ja00542a002
PDF
Low-temperature carbon-13 magnetic resonance of solids. 1. Alkenes and cycloalkenes
Kurt W. Zilm, Robert T. Conlin, David M. Grant, and Josef Michl
pp 6672 - 6676; DOI:
10.1021/ja00542a003
PDF
Dynamics of the primary events in bacterial photosynthesis
Joshua Jortner
pp 6676 - 6686; DOI:
10.1021/ja00542a004
PDF
Molecular orbital study of sulfur-nitrogen and sulfur-carbon conjugation: mode of bonding in (SN)x and related compounds
R. C. Haddon, S. R. Wasserman, F. Wudl, and G. R. J. Williams
pp 6687 - 6693; DOI:
10.1021/ja00542a005
PDF
Excitation profiles, absorption and resonance Raman spectra of the carotenoprotein ovorubin, and a resonance Raman study of some other astaxanthin proteins
Robin J. H. Clark, Norman R. D'Urso, and Peter F. Zagalsky
pp 6693 - 6698; DOI:
10.1021/ja00542a006
PDF
Oxygen-18-isotope effect in carbon-13 nuclear magnetic resonance spectroscopy. 3. Additivity effects and steric effects
John M. Risley and Robert L. Van Etten
pp 6699 - 6702; DOI:
10.1021/ja00542a007
PDF
Chemical, spectral, structural, and charge transport properties of the "molecular metals" produced by iodination of nickel phthalocyanine
Charles J. Schramm, Raymond P. Scaringe, Djordje R. Stojakovic, Brian M. Hoffman, James A. Ibers, and Tobin J. Marks
pp 6702 - 6713; DOI:
10.1021/ja00542a008
PDF
Mechanism of thermal decomposition of dineopentylbis(triethylphosphine)platinum(II): formation of bis(triethylphosphine)-3,3-dimethylplatinacyclobutane
Paul Foley, Robert DiCosimo, and George M. Whitesides
pp 6713 - 6725; DOI:
10.1021/ja00542a009
PDF
Complexation of metal ions by monensin. Crystal and molecular structure of hydrated and anhydrous crystal forms of sodium monensin
William L. Duax, G. David Smith, and Phyllis D. Strong
pp 6725 - 6729; DOI:
10.1021/ja00542a010
PDF
Imidazolate complexes of iron and manganese tetraphenylporphyrins
John T. Landrum, K. Hatano, W. Robert Scheidt, and Christopher A. Reed
pp 6729 - 6735; DOI:
10.1021/ja00542a011
PDF
Transition-metal complexes of pyrrole pigments. 16. Cobalt complexes of 1,19-dimethyldehydrocorrins as vitamin B12 models
Yukito Murakami, Yasuhiro Aoyama, and Koji Tokunaga
pp 6736 - 6744; DOI:
10.1021/ja00542a012
PDF
Multiple metal-carbon bonds. 17. Preparation of monocyclopentadienyl benzylidene complexes of tantalum and the crystal structure of Ta(.eta.5-C5Me5)(CHPh)(CH2Ph)2
L. W. Messerle, P. Jennische, R. R. Schrock, and G. Stucky
pp 6744 - 6752; DOI:
10.1021/ja00542a013
PDF
Photoelectron study of the interaction of carbon monoxide with zinc oxide
Robert R. Gay, Mark H. Nodine, Victor E. Henrich, H. J. Zeiger, and Edward I. Solomon
pp 6752 - 6761; DOI:
10.1021/ja00542a014
PDF
Studies of energy-transfer and electron-transfer processes involving the 3A2u excited states of binuclear rhodium isocyanide complexes
Steven J. Milder, Robert A. Goldbeck, David S. Kliger, and Harry B. Gray
pp 6761 - 6764; DOI:
10.1021/ja00542a015
PDF
Thermochemistry and dissociation dynamics of state selected C4H4X ions. 1. Thiophene
James J. Butler and Tomas Baer
pp 6764 - 6769; DOI:
10.1021/ja00542a016
PDF
Thermochemistry and dissociation dynamics of state-selected C4H4X ions. 2. Furan and 3-butyn-2-one
Gary D. Willett and Tomas Baer
pp 6769 - 6773; DOI:
10.1021/ja00542a017
PDF
Thermochemistry and dissociation dynamics of state-selected C4H4X ions. 3. C4H5N+
Gary D. Willett and Tomas Baer
pp 6774 - 6779; DOI:
10.1021/ja00542a018
PDF
Origin of the Z-value scale of solvent "ionizing power". Solvation of the ground and Franck-Condon excited state of 1-ethyl-4-cyanopyridinium iodide
John W. Larsen, Anna G. Edwards, and Peter Dobi
pp 6780 - 6783; DOI:
10.1021/ja00542a019
PDF
Kinetics and mechanism of the Bamberger cleavage of imidazole and of histidine derivatives by diethyl pyrocarbonate in aqueous solution
M. E. Grace, M. J. Loosemore, M. L. Semmel, and R. F. Pratt
pp 6784 - 6789; DOI:
10.1021/ja00542a020
PDF
Mechanism of reactions of N-(methoxymethyl)-N,N-dimethylanilinium ions with nucleophilic reagents
Barry L. Knier and William P. Jencks
pp 6789 - 6798; DOI:
10.1021/ja00542a021
PDF
A case of fully diffusion-controlled exothermic triplet excitation transfer
Jack Saltiel, Patrick T. Shannon, Oliver C. Zafiriou, and Anthony K. Uriarte
pp 6799 - 6808; DOI:
10.1021/ja00542a022
PDF
Carbanion photochemistry. 3. Electron transfer and radical-anion control in the photochemistry of triphenylmethyl anion
Laren M. Tolbert
pp 6808 - 6813; DOI:
10.1021/ja00542a023
PDF
Extended unsaturated carbenes. Generation and nature of alkadienylidenecarbenes
Peter J. Stang and Thomas E. Fisk
pp 6813 - 6816; DOI:
10.1021/ja00542a024
PDF
Stereochemical aspects of the biosynthesis of spectinomycin
Hideaki Otsuka, Oreste A. Mascaretti, Laurence H. Hurley, and Heinz G. Floss
pp 6817 - 6820; DOI:
10.1021/ja00542a025
PDF
The relationship between complex stability constants and rates of cation transport through liquid membranes by macrocyclic carriers
J. D. Lamb, J. J. Christensen, J. L. Oscarson, B. L. Nielsen, B. W. Asay, and R. M. Izatt
pp 6820 - 6824; DOI:
10.1021/ja00542a026
PDF
Structure of 3.alpha.-hydroxy-15-rippertene. Evidence for 1,2-methyl migration during biogenesis of a tetracyclic diterpene in termites
Glenn D. Prestwich, Stephen G. Spanton, Joseph W. Lauher, and Jan Vrkoc
pp 6825 - 6828; DOI:
10.1021/ja00542a027
PDF
Structure-reactivity studies on the equilibrium reaction between phenolate ions and 2-aryloxazolin-5-ones: data consistent with a concerted acyl-group-transfer mechanism
Terence C. Curran, Charles R. Farrar, Omima Niazy, and Andrew Williams
pp 6828 - 6837; DOI:
10.1021/ja00542a028
PDF
Electron spin resonance studies on tris(3,5-di-tert-butylphenyl)silyl and germyl radicals
Hideki Sakurai, Hiroshi Umino, and Hisashi Sugiyama
pp 6837 - 6840; DOI:
10.1021/ja00542a029
PDF
Mechanism of action of porphobilinogen deaminase: ordered addition of the four porphobilinogen molecules in the formation of preuroporphyrinogen
J. S. Seehra and P. M. Jordan
pp 6841 - 6846; DOI:
10.1021/ja00542a030
PDF
Kinetic study of the interaction of methylmercury with the Fe2S2(SR)4 cluster of adrenodoxin
Sumio Arakawa, Robert D. Bach, and Tokuji Kimura
pp 6847 - 6849; DOI:
10.1021/ja00542a031
PDF
First synthesis, characterization, and x-ray structural determination of the macrocyclic phosphineamine complex [Ni(Me2[16]dieneN2P2)](PF6)2.0.5H2O
L. G. Scanlon, Y. Y. Tsao, S. C. Cummings, K. Toman, and D. W. Meek
pp 6849 - 6851; DOI:
10.1021/ja00542a032
PDF
Neutral products of ion-molecule reactions
Mark A. Smith, Robert M. Barkley, and G. Barney Ellison
pp 6851 - 6852; DOI:
10.1021/ja00542a033
PDF
Facile syntheses of tetraalkylchlorin and tetraalkylporphyrin complexes and comparison of the structures of the tetramethylchlorin and tetramethylporphyrin complexes of nickel(II)
Abraham Ulman, Judith Gallucci, Diane Fisher, and James A. Ibers
pp 6852 - 6854; DOI:
10.1021/ja00542a034
PDF
Reality of electron transfer in slow organic reactions
Cheves Walling
pp 6854 - 6855; DOI:
10.1021/ja00542a035
PDF
Hydrogenation of carbon monoxide to methanol and ethylene glycol by homogeneous ruthenium catalysts
B. Duane Dombek
pp 6855 - 6857; DOI:
10.1021/ja00542a036
PDF
Resonance Raman spectra of (dioxygen)(porphyrinato)(hindered imidazole)iron(II) complexes: implications for hemoglobin cooperativity
Marc A. Walters, Thomas G. Spiro, Kenneth S. Suslick, and James P. Collman
pp 6857 - 6858; DOI:
10.1021/ja00542a037
PDF
Circular dichroism spectra of a single chirally perturbed naphthalene chromophore
Piero Salvadori, Oreste Piccolo, Carlo Bertucci, Rita Menicagli, and Luciano Lardicci
pp 6859 - 6860; DOI:
10.1021/ja00542a038
PDF
Remote and selective electrophilic fluorinations at the carbon-hydrogen single bond
Shlomo Rozen, Chava Gal, and Yonah Faust
pp 6860 - 6861; DOI:
10.1021/ja00542a039
PDF
[3.1.1]Propellane
Paul G. Gassman and Gary S. Proehl
pp 6862 - 6863; DOI:
10.1021/ja00542a040
PDF
Synthesis and reactions of 2-lithio-3-chlorobicyclo[2.2.1]hept-2-ene. Generation of the trimer of bicyclo[2.2.1]hept-2-yne
Paul G. Gassman and Irene Gennick
pp 6863 - 6864; DOI:
10.1021/ja00542a041
PDF
Mixed valence and magnetically coupled vanadate domains in heteropoly tungstate anions
Magdi M. Mossoba, Charles J. O'Connor, Michael T. Pope, Ekk Sinn, Gilbert Herve, and Andre Teze
pp 6864 - 6866; DOI:
10.1021/ja00542a042
PDF
Retention of ring structure in cyclopentane and alkylcyclopentane molecular cations
L. Wayne Sieck, M. Meot-Ner, and P. Ausloos
pp 6866 - 6867; DOI:
10.1021/ja00542a043
PDF
Deuterium isotope effect on the carbon-13 NMR spectrum of the bicyclo[2.2.1]heptyl cation. Nonclassical norbornyl cation
Martin Saunders and Mandes R. Kates
pp 6867 - 6868; DOI:
10.1021/ja00542a044
PDF
Deuterium isotope effects on the cyclobutyl-cyclopropylcarbinyl cation
Martin Saunders and Hans Ullrich Siehl
pp 6868 - 6869; DOI:
10.1021/ja00542a045
PDF
Cyclization dynamics of polymers. 2. Dynamics and thermodynamics of end-to-end cyclization of polystyrene in a .THETA. solvent
A. E. C. Redpath and Mitchell A. Winnik
pp 6869 - 6871; DOI:
10.1021/ja00542a046
PDF
Electronic excited-state analysis by magnetic circular dichroism of d6 (alkylamino)pentacarbonyl complexes, [M(CO)5A]0 (M = chromium, molybdenum, tungsten)
A. F. Schreiner, S. Amer, W. M. Duncan, G. Ober, R. M. Dahlgren, and J. Zink
pp 6871 - 6872; DOI:
10.1021/ja00542a047
PDF
Organic photochemistry with 6.7-eV photons: rigid homoallylic alcohols. An inverse Norrish type II rearrangement
Joel Studebaker, R. Srinivasan, Jose A. Ors, and Thomas Baum
pp 6872 - 6874; DOI:
10.1021/ja00542a048
PDF
Quenching of emission and of photochemistry of pentacarbonyl(4-cyanopyridino)tungsten(0)
Alistair J. Lees and Arthur W. Adamson
pp 6874 - 6876; DOI:
10.1021/ja00542a049
PDF
Titanium metallacarbene-metallacyclobutane reactions: stepwise metathesis
T. R. Howard, J. B. Lee, and R. H. Grubbs
pp 6876 - 6878; DOI:
10.1021/ja00542a050
PDF
A model for coenzyme-metal ion-apoenzyme interactions: crystal structure of the ternary complex [(thiamine pyrophosphate)(1,10-phenanthroline)aquacopper]-dinitrate-water
Katsuyuki Aoki and Hiroshi Yamazaki
pp 6878 - 6880; DOI:
10.1021/ja00542a051
PDF
Chemical field ionization. Effect of chemically bonded surface groups in field ionization mass spectrometry
Tim L. Youngless, Maurice M. Bursey, and Lee G. Pedersen
pp 6881 - 6882; DOI:
10.1021/ja00542a052
PDF
Temporary negative ions of methyl-substituted ethylenes: trends in the electron affinities, ionization potentials, and excitation energies
K. D. Jordan and P. D. Burrow
pp 6882 - 6883; DOI:
10.1021/ja00542a053
PDF
Carbon-13 nuclear magnetic resonance comparison of the crystalline and solution states of carbonyl hemoglobin A
G. E. Maciel, M. P. Shatlock, R. A. Houtchens, and W. S. Caughey
pp 6884 - 6885; DOI:
10.1021/ja00542a054
PDF
Silicon in synthesis: an exceptionally short synthesis of dl-11.alpha.-hydroxyestrone methyl ether
Stevan Djuric, Tarun Sarkar, and Philip Magnus
pp 6885 - 6886; DOI:
10.1021/ja00542a055
PDF
Detection and characterization of radical cations resulting from the oxidation of methyl and acetyl iron complexes
Roy H. Magnuson, Samu Zulu, Wen-Ming T'sai, and Warren P. Giering
pp 6887 - 6888; DOI:
10.1021/ja00542a056
PDF
Photochemical preparation of an O-sulfinato complex of cobalt(III)
Helmut Maecke, Virginia Houlding, and Arthur W. Adamson
pp 6888 - 6889; DOI:
10.1021/ja00542a057
PDF
Claisen rearrangements of lactonic (silyl) enolates: a new route to functionalized cycloalkenes
Samuel Danishefsky, Raymond L. Funk, and James F. Kerwin
pp 6889 - 6891; DOI:
10.1021/ja00542a058
PDF
Control of remote relative chiralities: a stereospecific total synthesis of dl-widdrol
Samuel Danishefsky and Kazuo Tsuzuki
pp 6891 - 6893; DOI:
10.1021/ja00542a059
PDF
Simple, efficient total synthesis of cantharidin via a high-pressure Diels-Alder reaction
William G. Dauben, Carl R. Kessel, and Kazuo H. Takemura
pp 6893 - 6894; DOI:
10.1021/ja00542a060
PDF
Silicon-directed Baeyer-Villiger reactions. Stereospecific synthesis of olefinic acids and esters
Paul F. Hudrlik, Anne M. Hudrlik, Gopalpur Nagendrappa, Tilahun Yimenu, Edward T. Zellers, and Evelyn Chin
pp 6894 - 6896; DOI:
10.1021/ja00542a061
PDF
Competitive condensation and proton-transfer processes in the reaction of tert-C4H9+ ions with ammonia in gaseous systems at atmospheric pressure
Marina Attina, Fulvio Cacace, Pierluigi Giacomello, and Maurizio Speranza
pp 6896 - 6898; DOI:
10.1021/ja00542a062
PDF
Visible light driven generation of chlorine and bromine. Photooxidation of chloride and bromide in aqueous solution at illuminated n-type semiconducting molybdenum diselenide and molybdenum disulfide electrodes
Clifford P. Kubiak, Lynn F. Schneemeyer, and Mark S. Wrighton
pp 6898 - 6900; DOI:
10.1021/ja00542a063
PDF
A general preparative method for .alpha.-lithioethers and its application to a concise, practical synthesis of brevicomin
Theodore Cohen and James R. Matz
pp 6900 - 6902; DOI:
10.1021/ja00542a064
PDF
Aziridine-2,3-diones
Hiromu Aoyama, Masami Sakamoto, and Yoshimori Omote
pp 6902 - 6903; DOI:
10.1021/ja00542a065
PDF
Isolation of an entire set of the three possible isomers of trans-diammine(triethylenetetraamine)cobalt(III) ion
Shunji Utsuno, Yukio Sakai, Yuzo Yoshikawa, and Hideo Yamatera
pp 6903 - 6904; DOI:
10.1021/ja00542a066
PDF
Book Reviews

pp 6905 - 6908; DOI:
10.1021/ja00542a600
PDF

Issue 23


Molecular structure of mercurous halides: mercurous fluoride and mercurous chloride
Daniel A. Kleier and Williard R. Wadt
pp 6909 - 6913; DOI:
10.1021/ja00543a001
PDF
Intramolecular proton tunneling in the ground and lowest excited singlet states of 9-hydroxyphenalenone
R. Rossetti, R. C. Haddon, and L. E. Brus
pp 6913 - 6916; DOI:
10.1021/ja00543a002
PDF
Excited-state prototropic reactivity in salicylamide and salicylanilide
G. J. Woolfe and P. J. Thistlethwaite
pp 6917 - 6923; DOI:
10.1021/ja00543a003
PDF
Electrochemical production of chlorophyll a and pheophytin a excited states
Michael R. Wasielewski, Rebecca L. Smith, and Arthur G. Kostka
pp 6923 - 6928; DOI:
10.1021/ja00543a004
PDF
Theoretical studies on the conformation of saccharides. 3. Conformational properties of the glycosidic linkage in solution and their relation to the anomeric and exoanomeric effects
Igor Tvaroska and Tibor Kozar
pp 6929 - 6936; DOI:
10.1021/ja00543a005
PDF
Kinetic study of the equilibrium HO2 + NO .dblarw. OH + NO2 and the thermochemistry of HO2
Carleton J. Howard
pp 6937 - 6941; DOI:
10.1021/ja00543a006
PDF
Influence of substituents having lone pairs on the structure of cyclopropanes
Sueleyman Durmaz and Herbert Kollmar
pp 6942 - 6945; DOI:
10.1021/ja00543a007
PDF
Charge distributions and chemical effects. 23. The chemical bond, a theory of electron density
Sandor Fliszar
pp 6946 - 6953; DOI:
10.1021/ja00543a008
PDF
Gas-phase ion/molecule isotope-exchange reactions: methodology for counting hydrogen atoms in specific organic structural environments by chemical ionization mass spectrometry
Donald F. Hunt and Satinder K. Sethi
pp 6953 - 6963; DOI:
10.1021/ja00543a009
PDF
n-Type molybdenum diselenide-based photoelectrochemical cells: evidence for Fermi level pinning and comparison of the efficiency for conversion of light to electricity with various solvent/halogen/halide combinations
Lynn F. Schneemeyer and Mark S. Wrighton
pp 6964 - 6971; DOI:
10.1021/ja00543a010
PDF
Circular dichroism of an optically active olefin chromophore: (R)-3-methylcyclopentene
M. Levi, D. Cohen, V. Schurig, Harold Basch, and A. Gedanken
pp 6972 - 6975; DOI:
10.1021/ja00543a011
PDF
General method for the assignment of stereochemistry of 1,3-disubstituted 1,2,3,4-tetrahydro-.beta.-carbolines by carbon-13 spectroscopy
F. Ungemach, D. Soerens, R. Weber, M. DiPierro, O. Campos, P. Mokry, J. M. Cook, and J. V. Silverton
pp 6976 - 6984; DOI:
10.1021/ja00543a012
PDF
Natural-abundance nitrogen-15 nuclear magnetic resonance spectroscopy of coronands, cryptands, and some of their complexes with diamagnetic metal ions
Hans G. Foerster and John D. Roberts
pp 6984 - 6988; DOI:
10.1021/ja00543a013
PDF
Organometallic chemistry. 17. Silicon-29 and carbon-13 NMR spectroscopic study of phenylsilyl anions. The question of silicon-carbon p.pi.-p.pi.-electron delocalization and comparison with related carbanions
George A. Olah and Ronald J. Hunadi
pp 6989 - 6992; DOI:
10.1021/ja00543a014
PDF
An electronic spectroscopic study of iron coordination in hemerythrin
Joann Sanders Loehr, Thomas M. Loehr, A. Grant Mauk, and Harry B. Gray
pp 6992 - 6996; DOI:
10.1021/ja00543a015
PDF
Synthesis, structures, stabilities, and reactions of cationic olefin complexes of palladium(II) containing the .eta.5-cyclopentadienyl ligand
Hideo Kurosawa, Tetsuro Majima, and Naonori Asada
pp 6996 - 7003; DOI:
10.1021/ja00543a016
PDF
Substitution, alkyl-transfer, and thermal decomposition reactions of .eta.5-cyclopentadienyl(triphenylphosphine)dimethylcobalt(III)
Eric R. Evitt and Robert G. Bergman
pp 7003 - 7011; DOI:
10.1021/ja00543a017
PDF
11-Membered macrocycles containing the diarsa moiety
Evan P. Kyba and Shang-Shing P. Chou
pp 7012 - 7014; DOI:
10.1021/ja00543a018
PDF
Chemical-structural properties of tetracycline derivatives. 9. 7-Chlorotetracycline derivatives with modified stereochemistry
Roland Prewo and John J. Stezowski
pp 7015 - 7020; DOI:
10.1021/ja00543a019
PDF
Chemical-structural properties of tetracycline derivatives. 10. The 6-thiatetracyclines
Roland Prewo, John J. Stezowski, and Richard Kirchlechner
pp 7021 - 7026; DOI:
10.1021/ja00543a020
PDF
Synthesis of .beta.-lactams from substituted hydroxamic acids
Marvin J. Miller, Phillip G. Mattingly, Marjorie A. Morrison, and James F. Kerwin
pp 7026 - 7032; DOI:
10.1021/ja00543a021
PDF
Carbon-carbon bond formation by condensation of CpFe(CO)2(.eta.1-allyl) complexes with CpFe(CO)2(.eta.2-olefin) cations. Regio- and stereospecificity, sequential reactions leading to cycloadducts
Patrick J. Lennon, Allan Rosan, Myron Rosenblum, Jean Tancrede, and Paul Waterman
pp 7033 - 7038; DOI:
10.1021/ja00543a022
PDF
Cation-anion combination reactions. 18. Reactions of nucleophiles with an ion pair
Calvin D. Ritchie and Thomas C. Hofelich
pp 7039 - 7044; DOI:
10.1021/ja00543a023
PDF
Conformational analysis of linear peptides. 2. A vapor-pressure osmometry study of self-association in chloroform
Neal Sugawara, E. S. Stevens, G. M. Bonora, and C. Toniolo
pp 7044 - 7047; DOI:
10.1021/ja00543a024
PDF
Conformational analysis of linear peptides. 3. Temperature dependence of NH chemical shifts in chloroform
E. S. Stevens, N. Sugawara, G. M. Bonora, and C. Toniolo
pp 7048 - 7050; DOI:
10.1021/ja00543a025
PDF
Carbon-13, proton spin-spin coupling. 7. Pyridinium ion
Horst Seel and Harald Guenther
pp 7051 - 7054; DOI:
10.1021/ja00543a026
PDF
Superiority of very weakly basic amines as catalysts for alpha-proton abstraction via iminium ion formation
Rex D. Roberts, Herbert E. Ferran, Michael J. Gula, and Thomas A. Spencer
pp 7054 - 7058; DOI:
10.1021/ja00543a027
PDF
Effects of solvation on the nucleophilic reaction of stable carbanions with diaryl disulfides
H. F. Gilbert
pp 7059 - 7065; DOI:
10.1021/ja00543a028
PDF
Acid-base kinetics of pyridine studied with a slow spectrophotometric indicator in methanol
David B. Marshall, Edward M. Eyring, Frank Strohbusch, and Robert D. White
pp 7065 - 7067; DOI:
10.1021/ja00543a029
PDF
Photoreduction of hemin in alcohol-containing mixed solvents
Carlo Bartocci, Franco Scandola, Albertino Ferri, and Vittorio Carassiti
pp 7067 - 7072; DOI:
10.1021/ja00543a030
PDF
Some caged oxaazaphosphoranes
Donald B. Denney, Dorothy Z. Denney, Dragan M. Gavrilovic, Philip J. Hammond, Chialang Huang, and Kuo-Shu Tseng
pp 7072 - 7075; DOI:
10.1021/ja00543a031
PDF
Regioselective ring opening in substituted benzocyclopropenes. An alternative or complementary mechanism for electrophilic substitution involving attack at .alpha. bond
Lim Keow Bee, Peter J. Garratt, and Muzamil M. Mansuri
pp 7076 - 7079; DOI:
10.1021/ja00543a032
PDF
Chiroptical properties of proteins. I. Near-ultraviolet circular dichroism of ribonuclease S
Warren J. Goux and Thomas M. Hooker
pp 7080 - 7087; DOI:
10.1021/ja00543a033
PDF
Calcium(II) and the trivalent lanthanide ion complexes of the bleomycin antibiotics. Potentiometric, fluorescence and proton NMR studies
R. E. Lenkinski, B. E. Peerce, R. P. Pillai, and J. D. Glickson
pp 7088 - 7093; DOI:
10.1021/ja00543a034
PDF
Structural studies of ristocetin A (ristomycin A): carbohydrate-aglycone linkages
Ferenc Sztaricskai, Constance M. Harris, Andras Neszmelyi, and Thomas M. Harris
pp 7093 - 7099; DOI:
10.1021/ja00543a035
PDF
Anomalous metalloporphyrin and chlorophyll a activated chemiluminescence of dimethyldioxetanone. Chemically initiated electron-exchange luminescence
Steven P. Schmidt and Gary B. Schuster
pp 7100 - 7103; DOI:
10.1021/ja00543a036
PDF
Photolytic generation of a 1,8-naphthoquinodimethane biradical. Time-resolved and polarization electron spin resonance studies
William P. Chisholm, S. I. Weissman, Michael N. Burnett, and Richard M. Pagni
pp 7103 - 7104; DOI:
10.1021/ja00543a037
PDF
Enzyme-catalyzed organic synthesis: NADH regeneration by using formate dehydrogenase
Ze'ev Shaked and George M. Whitesides
pp 7104 - 7105; DOI:
10.1021/ja00543a038
PDF
Unexpected features in the chemistry of six and seven coordinate alkyl isocyanide complexes of chromium
William S. Mialki, Thomas E. Wood, and Richard A. Walton
pp 7105 - 7107; DOI:
10.1021/ja00543a039
PDF
Erythro-selective addition of crotyltrialkyltins to aldehydes regardless of the geometry of the crotyl unit. Stereoselection independent of the stereochemistry of precursors
Yoshinori Yamamoto, Hidetaka Yatagai, Yoshinori Naruta, and Kazuhiro Maruyama
pp 7107 - 7109; DOI:
10.1021/ja00543a040
PDF
Hydrido-formyl complexes of iridium. The first cationic formyl complex and its reduction to a stable cis-hydrido-methyl compound
David L. Thorn
pp 7109 - 7110; DOI:
10.1021/ja00543a041
PDF
Metal-metal bonded complexes of the early transition metals: synthesis of a binuclear tantalum(III) trimethylphosphine complex and its reactions with hydrogen and ethylene
A. P. Sattelberger, R. B. Wilson, and John C. Huffman
pp 7111 - 7113; DOI:
10.1021/ja00543a042
PDF
Isolation and structure elucidation of 22(S),23(S)-methylenecholesterol. Evidence for direct bioalkylation of 22-dehydrocholesterol
Pierre Alain Blanc and Carl Djerassi
pp 7113 - 7114; DOI:
10.1021/ja00543a043
PDF
Crystal and molecular structure of cofacial dicopper hexyldiporphyrin-7
Marcos H. Hatada, A. Tulinsky, and C. K. Chang
pp 7115 - 7116; DOI:
10.1021/ja00543a044
PDF
Biomimetic synthesis of macroline
Robert W. Esmond and Philip W. Le Quesne
pp 7116 - 7117; DOI:
10.1021/ja00543a045
PDF
Use of holography to investigate photochemical reactions
D. M. Burland, G. C. Bjorklund, and D. C. Alvarez
pp 7117 - 7119; DOI:
10.1021/ja00543a046
PDF
Direct cyanation of aromatics
Ying-Hung So and Larry L. Miller
pp 7119 - 7120; DOI:
10.1021/ja00543a047
PDF
Differential quenching of chromium(III) photochemistry
A. D. Kirk, L. A. Frederick, and S. G. Glover
pp 7120 - 7122; DOI:
10.1021/ja00543a048
PDF
Optical resolution of the D- and L-amino acid family by liquid-solid chromatography
Akira Dobashi, Kitaro Oka, and Shoji Hara
pp 7122 - 7123; DOI:
10.1021/ja00543a049
PDF
Direct evidence for ketocarbene-ketocarbene interconversion
Hideo Tomioka, Hiroshi Okuno, Shingo Kondo, and Yasuji Izawa
pp 7123 - 7125; DOI:
10.1021/ja00543a050
PDF
.alpha.-Substitution of amines via dipole stabilized carbanions from formamidines
A. I. Meyers and Wolter Ten Hoeve
pp 7125 - 7126; DOI:
10.1021/ja00543a051
PDF
A mechanism for mitochondrial monoamine oxidase catalyzed amine oxidation
Richard B. Silverman, Stephen J. Hoffman, and William B. Catus
pp 7126 - 7128; DOI:
10.1021/ja00543a052
PDF
Ruthenium(II) tris(bipyrazyl) dication - a new photocatalyst
R. J. Crutchley and A. B. P. Lever
pp 7128 - 7129; DOI:
10.1021/ja00543a053
PDF
Characterization of complexes of butanes with transition-metal atomic ions in the gas phase
R. B. Freas and D. P. Ridge
pp 7129 - 7131; DOI:
10.1021/ja00543a054
PDF
Facile liquid-phase denitrogenation of "reluctant" azoalkanes on photolysis with 185-nm radiation
Waldemar Adam and Francois Mazenod
pp 7131 - 7132; DOI:
10.1021/ja00543a055
PDF
Synthesis and crystal structure of a stable bis(borane)aminophosphane adduct: the unusually strong basic character of a nitrogen atom bound to phosphorus
Dominique Grec, Liliane G. Hubert-Pfalzgraf, Jean G. Riess, and Andre Grand
pp 7133 - 7134; DOI:
10.1021/ja00543a056
PDF
Formation of o-(9-fluorenyl)phenylnitrene in the photoisomerization of 1-azatriptycene
Tadashi Sugawara and Hiizu Iwamura
pp 7134 - 7136; DOI:
10.1021/ja00543a057
PDF
2-(Hydroxymethyl) aspartic acid: synthesis, crystal structure, and reaction with a transaminase
John J. Walsh, David E. Metzler, Douglas Powell, and R. A. Jacobson
pp 7136 - 7138; DOI:
10.1021/ja00543a058
PDF
Quenching of triplet ketones by alcohol hydroxy bonds
Peter J. Wagner and Allen E. Puchalski
pp 7138 - 7140; DOI:
10.1021/ja00543a059
PDF
Importance of mass transfer and intraparticle diffusion in polymer-supported phase-transfer catalysis
M. Tomoi and Warren T. Ford
pp 7140 - 7141; DOI:
10.1021/ja00543a060
PDF
Structure and stereochemistry of novel endoperoxides isolated from the sensitized photooxidation of methyl linoleate. Implications for prostaglandin biosynthesis
Edward D. Mihelich
pp 7141 - 7143; DOI:
10.1021/ja00543a061
PDF
Primary electron acceptors in plant photosynthesis
J. Fajer, M. S. Davis, A. Forman, V. V. Klimov, E. Dolan, and B. Ke
pp 7143 - 7145; DOI:
10.1021/ja00543a062
PDF
Stereocontrol in the intramolecular Diels-Alder reaction. 1. An application to the total synthesis of (.+-.) marasmic acid
Robert K. Boeckman and Soo Sung Ko
pp 7146 - 7149; DOI:
10.1021/ja00543a063
PDF
Structures of the bacteriochlorophyll c homologs: solution to a longstanding problem
Kevin M. Smith, Lisa A. Kehres, and Hani D. Tabba
pp 7149 - 7151; DOI:
10.1021/ja00543a064
PDF
Carbon-13 enriched S-methyl probe at the active site of an enzyme: [S-[13C]methylmethionine-192]-.alpha.-chymotrypsin (MSMC)
H. Neal Bramson, Nancy Thomas, William F. DeGrado, Patricia A. Henderson, Mark W. Russo, and Richard L. Thomas
pp 7151 - 7152; DOI:
10.1021/ja00543a065
PDF
Tetracoordinate planar carbon: a singlet biradical
Debbie C. Crans and James P. Snyder
pp 7152 - 7154; DOI:
10.1021/ja00543a066
PDF
Total synthesis of (.+-.)-gephyrotoxin
Roger Fujimoto, Yoshito Kishi, and John F. Blount
pp 7154 - 7156; DOI:
10.1021/ja00543a067
PDF
Development of a convenient spectrophotometric assay for peptide phosphorylation catalyzed by adenosine 3',5'-monophosphate dependent protein kinase
H. Neal Bramson, Nancy Thomas, William F. DeGrado, and E. T. Kaiser
pp 7156 - 7157; DOI:
10.1021/ja00543a068
PDF
Biomimetic 8.alpha. functionalization of riboflavin
John W. Frost and William H. Rastetter
pp 7157 - 7159; DOI:
10.1021/ja00543a069
PDF
Induced .alpha. helix in a peptide system by introduction of a nucleus
Ryoichi Katakai
pp 7159 - 7161; DOI:
10.1021/ja00543a070
PDF
Book Reviews

pp 7161 - 7172; DOI:
10.1021/ja00543a600
PDF

Issue 24


Microwave, infrared, Raman and NMR spectra, structure, dipole moment, and barrier to internal rotation of cyclopropyldifluoroborane
J. D. Odom, Z. Szafran, S. A. Johnston, Y. S. Li, and J. R. Durig
pp 7173 - 7180; DOI:
10.1021/ja00544a001
PDF
Millimeter wave spectrum of glycine. A new conformer
R. D. Suenram and F. J. Lovas
pp 7180 - 7184; DOI:
10.1021/ja00544a002
PDF
Intermolecular self-consistent-field perturbation theory for organic reactions. I. Theory and implementation; nucleophilic attack on carbonyl compounds
A. J. Stone and R. W. Erskine
pp 7185 - 7192; DOI:
10.1021/ja00544a003
PDF
Is there a particle-size dependence for the mediation by colloidal redox catalysts of the light-induced hydrogen evolution from water?
P. Keller and A. Moradpour
pp 7193 - 7196; DOI:
10.1021/ja00544a004
PDF
A QSAR investigation of dihydrofolate reductase inhibition by Baker triazines based upon molecular shape analysis
A. J. Hopfinger
pp 7196 - 7206; DOI:
10.1021/ja00544a005
PDF
Photoassisted water-gas shift reaction over platinized titanium dioxide catalysts
S. Sato and J. M. White
pp 7206 - 7210; DOI:
10.1021/ja00544a006
PDF
Natural hybrid orbitals
J. P. Foster and F. Weinhold
pp 7211 - 7218; DOI:
10.1021/ja00544a007
PDF
Electronic control of stereoselectivity. 4. Effects of neighboring fused bicyclic frameworks on the stereochemical outcome of Diels-Alder cycloadditions to cyclopentadiene rings
Michael C. Boehm, Richard V. C. Carr, Rolf Gleiter, and Leo A. Paquette
pp 7218 - 7228; DOI:
10.1021/ja00544a008
PDF
Chiral perturbation of olefins by deuterium substitution. The optical activity and circular dichroism behavior of (1S)-[2-2H]norbornene and deuterated apobornenes
Leo A. Paquette, Christopher W. Doecke, Francis R. Kearney, Alex F. Drake, and Stephen F. Mason
pp 7228 - 7233; DOI:
10.1021/ja00544a009
PDF
Deuterium isotope effects on the carbon-13 chemical shifts of carbocations
Kenneth L. Servis and Feng-Fang Shue
pp 7233 - 7240; DOI:
10.1021/ja00544a010
PDF
Importance of (p-d).pi. bonding in the siloxane bond
Heinz Oberhammer and James E. Boggs
pp 7241 - 7244; DOI:
10.1021/ja00544a011
PDF
Low-temperature infrared study of d0 carbonyl complexes
John A. Marsella, Calvin J. Curtis, John E. Bercaw, and Kenneth G. Caulton
pp 7244 - 7246; DOI:
10.1021/ja00544a012
PDF
Annelides. 3. Complexation of dioxygen in organized cobaltous complex assemblies. A new approach to kinetic studies in micellar phases
J. Simon, J. Le Moigne, D. Markovitsi, and J. Dayantis
pp 7247 - 7252; DOI:
10.1021/ja00544a013
PDF
Solar energy storage reactions. Thermal and photochemical redox reactions of polynuclear rhodium isocyanide complexes
I. S. Sigal, Kent R. Mann, and Harry B. Gray
pp 7252 - 7256; DOI:
10.1021/ja00544a014
PDF
Electronic relaxation in azurin: picosecond reverse charge transfer
Jay M. Wiesenfeld, Erich P. Ippen, Alan Corin, and Richard Bersohn
pp 7256 - 7258; DOI:
10.1021/ja00544a015
PDF
Quenching of pyrene fluorescence by single and multivalent metal ions in micellar solutions
Franz Grieser and Robert Tausch-Treml
pp 7258 - 7264; DOI:
10.1021/ja00544a016
PDF
Determination of rate constants for photosolvation reactions: solvent dependence of chloride substitution rates for excited states of cis-dichlorobis(2,2'-bipyridine)iridium(III)
B. Divisia, P. C. Ford, and R. J. Watts
pp 7264 - 7268; DOI:
10.1021/ja00544a017
PDF
Pressure effect on rate and equilibrium constants of reversible anionic .sigma.-complex formation between polynitroaromatics and lyate ions of water and methanol
Muneo Sasaki, Noboru Takisawa, Fujitsugu Amita, and Jiro Osugi
pp 7268 - 7272; DOI:
10.1021/ja00544a018
PDF
A kinetic study of sensitized 9,10-dibromoanthracene fluorescence produced by energy transfer from triplet ketones. 1. Acetophenone as donor
Therese Wilson and Arthur M. Halpern
pp 7272 - 7279; DOI:
10.1021/ja00544a019
PDF
A kinetic study of sensitized 9,10-dibromoanthracene fluorescence produced by energy transfer from triplet ketones. 2. Acetone as donor: complications in benzene
Therese Wilson and Arthur M. Halpern
pp 7279 - 7283; DOI:
10.1021/ja00544a020
PDF
Complexation and oxidation of glycine and related compounds by silver(II)
Anil Kumar and P. Neta
pp 7284 - 7289; DOI:
10.1021/ja00544a021
PDF
Electron-transfer activation in electrophilic mechanisms. Cleavage of alkylmetals by mercury(II) complexes
S. Fukuzumi and J. K. Kochi
pp 7290 - 7297; DOI:
10.1021/ja00544a022
PDF
Transition-state effects in the divalent metal ion catalyzed hydrolysis of esters. Hydrolysis of 2-pyridylmethyl hydrogen phthalate
Thomas H. Fife and Theodore J. Przystas
pp 7297 - 7300; DOI:
10.1021/ja00544a023
PDF
Some comments on the possibility of achieving asymmetric synthesis from achiral reactants in a rotating vessel
C. Alden Mead and Albert Moscowitz
pp 7301 - 7302; DOI:
10.1021/ja00544a024
PDF
Hydrolysis of diazomethane-kinetics and mechanism
John F. McGarrity and Timothy Smyth
pp 7303 - 7308; DOI:
10.1021/ja00544a025
PDF
Transient fluorine-proton Overhauser effects in (4-(trifluoromethyl)benzenesulfonyl)-.alpha.-chymotrypsin
J. T. Gerig
pp 7308 - 7312; DOI:
10.1021/ja00544a026
PDF
Reduction of flavins by thiols. 1. Reaction mechanism from the kinetics of the attack and breakdown steps
Edward L. Loechler and Thomas C. Hollocher
pp 7312 - 7321; DOI:
10.1021/ja00544a027
PDF
Reduction of flavins by thiols. 2. Spectrophotometric evidence for a thiol-C(4a) flavin adduct and the kinetics of deprotonation of the -SH group of the dithiothreitol adduct
Edward L. Loechler and Thomas C. Hollocher
pp 7322 - 7327; DOI:
10.1021/ja00544a028
PDF
Reduction of flavins by thiols. 3. The case for concerted N,S-acetal formation in attack and an early transition state in breakdown
Edward L. Loechler and Thomas C. Hollocher
pp 7328 - 7334; DOI:
10.1021/ja00544a029
PDF
The pKa's of saxitoxin
R. Scott Rogers and Henry Rapoport
pp 7335 - 7339; DOI:
10.1021/ja00544a030
PDF
Chemical and spectroscopic studies of the binuclear copper active site of Neurospora tyrosinase: comparison to hemocyanins
Richard S. Himmelwright, Nancy C. Eickman, Cynthia D. LuBien, Edward I. Solomon, and Konrad Lerch
pp 7339 - 7344; DOI:
10.1021/ja00544a031
PDF
Stereospecificity of enzymic dehydrogenation during tiglate biosynthesis
Richard K. Hill, Sung-Whi Rhee, Edward Leete, and Brian A. McGaw
pp 7344 - 7348; DOI:
10.1021/ja00544a032
PDF
Superoxide dismutase-thiocyanate: a study of the binding sites of anions on copper(II) in superoxide dismutase
I. Bertini, C. Luchinat, and A. Scozzafava
pp 7349 - 7353; DOI:
10.1021/ja00544a033
PDF
Conformational characteristics of rigid cyclic nucleotides. 3. The solution conformation of .beta.-lyxonucleoside cyclic 2',5'- and 3',5'-monophosphates and of .alpha.-arabinonucleoside cyclic 2',5'-monophosphates. Implications for evaluation of the solution properties of nucleoside analogs
Malcolm MacCoss, Clinton F. Ainsworth, Gregory Leo, Fouad S. Ezra, and Steven S. Danyluk
pp 7353 - 7361; DOI:
10.1021/ja00544a034
PDF
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
Barbara J. Fisher and Richard Eisenberg
pp 7361 - 7363; DOI:
10.1021/ja00544a035
PDF
Transfer of optical activity in the decomposition of (+)- and (-)- trans-3,5-diphenyl-1-pyrazoline: competing "biradical" and "cycloreversion" pathways
Manfred P. Schneider and Herbert Bippi
pp 7363 - 7365; DOI:
10.1021/ja00544a036
PDF
Vafzelin and uvafzelin, novel constituents of Uvaria afzelii
Charles D. Hufford, Babajide O. Oguntimein, Donna Van Engen, David Muthard, and Jon Clardy
pp 7365 - 7367; DOI:
10.1021/ja00544a037
PDF
Chiral discrimination in the quenching of an enzyme-bound fluorescent NAD+ analog by an optically active quencher
Ari Gafni
pp 7367 - 7368; DOI:
10.1021/ja00544a038
PDF
Stereochemical course of .gamma. replacement on an amino acid substrate in a pyridoxal phosphate dependent enzymic reaction
Michael N. T. Chang and Christopher Walsh
pp 7368 - 7370; DOI:
10.1021/ja00544a039
PDF
Periodate oxidation of N-(p-bromobenzoyl)palytoxin
Richard E. Moore, Frank X. Woolard, and Giovanni Bartolini
pp 7370 - 7372; DOI:
10.1021/ja00544a040
PDF
Structural and spectroscopic evidence that cobalt to carbon bond lengths are influenced by conformational effects in cobaloximes. The longest cobalt-carbon bond in a vitamin B12 model: trans-bis(dimethylglyoximato)(isopropyl)(triphenylphosphine)cobalt(III)
Lucio Randaccio, Nevenka Bresciani-Pahor, Paul J. Toscano, and Luigi G. Marzilli
pp 7372 - 7373; DOI:
10.1021/ja00544a041
PDF
Occurrence of a 1,2 shift during enzymic and chemical oxidation of a terminal acetylene
Paul R. Ortiz de Montellano and Kent L. Kunze
pp 7373 - 7375; DOI:
10.1021/ja00544a042
PDF
Product ratios dependent on and independent of the left group in a single series: potassium metal-provoked reactions of aryl halides with amide and acetone enolate ions that occur during mixing
Michael J. Tremelling and J. F. Bunnett
pp 7375 - 7377; DOI:
10.1021/ja00544a043
PDF
Restricted rotational isomerization in polymethylene chains
T. H. Huang, R. P. Skarjune, R. J. Wittebort, R. G. Griffin, and E. Oldfield
pp 7377 - 7379; DOI:
10.1021/ja00544a044
PDF
Differentiation between Criegee rearrangement and dioxetane rearrangement mechanisms for the decomposition of .alpha.,.beta.-unsaturated hydroperoxides
Shigeaki Muto and Thomas C. Bruice
pp 7379 - 7381; DOI:
10.1021/ja00544a045
PDF
Regio-controlled coupling of (.pi.-allyl) palladium complexes with organozirconium species: a new steroid synthesis
James S. Temple and Jeffrey Schwartz
pp 7381 - 7382; DOI:
10.1021/ja00544a046
PDF
A dialkoxyarylbrominane. The first example of an organic 10-Br-3 species
Tuyen T. Nguyen and J. C. Martin
pp 7382 - 7383; DOI:
10.1021/ja00544a047
PDF
Highly luminescent polypyridyl complexes of osmium(II)
Edward M. Kober, B. Patrick Sullivan, Walter J. Dressick, Jonathan V. Caspar, and Thomas J. Meyer
pp 7383 - 7385; DOI:
10.1021/ja00544a048
PDF
Remote asymmetric induction. A stereoselective approach to acyclic diols via cyclic hydroboration
W. Clark Still and Kevin P. Darst
pp 7385 - 7387; DOI:
10.1021/ja00544a049
PDF
Ultraviolet photoelectron spectrum of the phenoxy radical
Michael J. S. Dewar and Donald E. David
pp 7387 - 7389; DOI:
10.1021/ja00544a050
PDF
Asymmetric synthesis in a spinning vessel
Asher Peres
pp 7389 - 7390; DOI:
10.1021/ja00544a051
PDF
Quintet state triplet-triplet radical pairs. 2
H. Murai, M. Torres, and O. P. Strausz
pp 7390 - 7391; DOI:
10.1021/ja00544a052
PDF
An efficient, high conversion photoinduced emulsion polymerization. Magnetic field effects on polymerization efficiency and polymer molecular weight
Nicholas J. Turro, Ming-Fea Chow, Chao-Jen Chung, and Chen-Ho Tung
pp 7391 - 7393; DOI:
10.1021/ja00544a053
PDF
Activation of methane with photoexcited metal atoms
W. E. Billups, Mark M. Konarski, Robert H. Hauge, and John L. Margrave
pp 7393 - 7394; DOI:
10.1021/ja00544a054
PDF
A simple highly efficient asymmetric synthesis. Preparation and absolute configuration of 3(S)-(tert-butoxycarbonylamino)-1(S)-methyltetrahydrothiophenium tosylate
Kazuhide Tani, Sei Otsuka, Masaru Kido, and Iwao Miura
pp 7394 - 7396; DOI:
10.1021/ja00544a055
PDF
High resolution NMR studies of solid state effects on fluxional behavior: semibullvalene
R. D. Miller and C. S. Yannoni
pp 7396 - 7397; DOI:
10.1021/ja00544a056
PDF
An organotransition-metal synthesis of naphthoquinones
Lanny S. Liebeskind, Sherrol L. Baysdon, and Michael S. South
pp 7397 - 7398; DOI:
10.1021/ja00544a057
PDF
Binding in subunit systems
J. Rebek, R. V. Wattley, T. Costello, R. Gadwood, and L. Marshall
pp 7398 - 7400; DOI:
10.1021/ja00544a058
PDF
Highly stabilized radicals: benzylic radicals in polycyclic aromatic systems
Donald F. McMillen, Paula L. Trevor, and David M. Golden
pp 7400 - 7402; DOI:
10.1021/ja00544a059
PDF
Book Reviews

pp 7403 - 7410; DOI:
10.1021/ja00544a600
PDF

Issue 25


Calculations of kinetic isotope effects in the Hofmann eliminations of substituted (2-phenylethyl)trimethylammonium ions
David E. Lewis, L. B. Sims, Hiroshi Yamataka, and James McKenna
pp 7411 - 7419; DOI:
10.1021/ja00545a001
PDF
Ring strain in cyclopropane, cyclopropene, silacyclopropane, and silacyclopropene
Mark S. Gordon
pp 7419 - 7422; DOI:
10.1021/ja00545a002
PDF
Electronic structure and photoelectron spectra of S2Fe2(CO)6
E. L. Andersen, T. P. Fehlner, A. E. Foti, and D. R. Salahub
pp 7422 - 7429; DOI:
10.1021/ja00545a003
PDF
The proton in dimethyl sulfoxide and acetone. Results from gas-phase ion equilibriums involving (Me2SO)nH+ and (Me2CO)nH+
Y. K. Lau, P. P. S. Saluja, and P. Kebarle
pp 7429 - 7433; DOI:
10.1021/ja00545a004
PDF
The solution conformational preferences of the sugar and sugar phosphate constituents of RNA and DNA
John A. Gerlt and A. Virginia Youngblood
pp 7433 - 7438; DOI:
10.1021/ja00545a005
PDF
Theory and application of photoelectron spectroscopy. Part 91. Conformational study of 1,2-dimethylhexahydropyridazine by variable-temperature photoelectron spectroscopy
Armin Schweig, Nikolaus Thon, Stephen F. Nelsen, and Loretta A. Grezzo
pp 7438 - 7441; DOI:
10.1021/ja00545a006
PDF
Time-resolved resonance Raman spectroscopy: the excited triplet state of all-trans-.beta.-carotene
Niels Henrik Jensen, Robert Wilbrandt, Palle B. Pagsberg, A. H. Sillesen, and K. B. Hansen
pp 7441 - 7444; DOI:
10.1021/ja00545a007
PDF
Intermediate molecular species in the oxidation of hydrogen sulfide. An ab initio configuration interaction study
S. Besnainou and J. L. Whitten
pp 7444 - 7448; DOI:
10.1021/ja00545a008
PDF
Preparation and properties of phosphine complexes of nickel-containing cyclic amides and esters [(PR3)nNiCH2CH(R1)COZ (Z = NR2, O)]
Takakazu Yamamoto, Kohji Igarashi, Sanshiro Komiya, and Akio Yamamoto
pp 7448 - 7456; DOI:
10.1021/ja00545a009
PDF
Characterization of reactions of hydrogen with coordinated sulfido ligands
M. Rakowski DuBois, M. C. VanDerveer, D. L. DuBois, R. C. Haltiwanger, and W. K. Miller
pp 7456 - 7461; DOI:
10.1021/ja00545a010
PDF
Protonation reactions of molybdenum and tungsten dinitrogen complexes with halogen acids. Hydride hydrazido(2-) and diazenido complexes as intermediate stages of reduction
Tamotsu Takahashi, Yasushi Mizobe, Maki Sato, Yasuzo Uchida, and Masanobu Hidai
pp 7461 - 7467; DOI:
10.1021/ja00545a011
PDF
Tricyclo[4.2.0.01,4]octane
Kenneth B. Wiberg, Larry K. Olli, Nancy Golembeski, and Richard D. Adams
pp 7467 - 7475; DOI:
10.1021/ja00545a012
PDF
Isocyanide insertion reactions. The reaction of Mn(CO)4CNCH3 anion with iodomethane and the crystal and molecular structure of (CH3)N=C(CH3)(CH3)C=N(CH3)Mn(CO)3Mn(CO)3
Richard D. Adams
pp 7476 - 7479; DOI:
10.1021/ja00545a013
PDF
Kinetics and mechanism of the reaction of cyclohexene with bromine in the presence of pyridine: competition between different electrophiles
Giuseppe Bellucci, Giancarlo Berti, Roberto Bianchini, Giovanni Ingrosso, and Roberto Ambrosetti
pp 7480 - 7486; DOI:
10.1021/ja00545a014
PDF
Mechanism of addition of neat trifluoroacetic acid to protoadamantene
J. Eric Nordlander, Jerome E. Haky, and John P. Landino
pp 7487 - 7493; DOI:
10.1021/ja00545a015
PDF
Structure and biosynthesis of setomimycin, a novel 9,9'-bianthryl antibiotic
Katsumi Kakinuma, Nobutaka Imamura, Nobuo Ikekawa, Haruo Tanaka, Shizuko Minami, and Satoshi Omura
pp 7493 - 7498; DOI:
10.1021/ja00545a016
PDF
Stereocontrolled total synthesis of an .alpha.-methylene guaianolide in the 4,5-epoxyosmitopsin family
Gary H. Posner, Kevin A. Babiak, Gary L. Loomis, W. Jack Frazee, Ramsharan D. Mittal, and Isabella L. Karle
pp 7498 - 7505; DOI:
10.1021/ja00545a017
PDF
Total synthesis of (+)-furanomycin and stereoisomers
J. Edward Semple, Pen C. Wang, Zenon Lysenko, and Madeleine M. Joullie
pp 7505 - 7510; DOI:
10.1021/ja00545a018
PDF
Spin trapping of molecules adsorbed on zinc oxide
Tokuo Matsuzaki, Taizo Uda, Akio Kazusaka, George W. Keulks, and Russell F. Howe
pp 7511 - 7513; DOI:
10.1021/ja00545a019
PDF
Vinylic cations from solvolysis. 30. Bromide exchange as a reactivity-selectivity probe in vinylic solvolysis
Frits I. M. Van Ginkel, Eppo R. Hartman, Gerrit Lodder, Jeremy Greenblatt, and Zvi Rappoport
pp 7514 - 7519; DOI:
10.1021/ja00545a020
PDF
Reactions of difluorosilylene with halogen-substituted ethylenes. A reinvestigation of the reaction mechanism
Tsai-Lih Hwang, Yi-Ming Pai, and Chao-Shiuan Liu
pp 7519 - 7524; DOI:
10.1021/ja00545a021
PDF
Catalysis of .alpha.-hydrogen exchange. 21. Stereoselective bifunctional catalysis of the dedeuteration of 3-pentanone-2,2,4,4-d4
Jack Hine and James P. Zeigler
pp 7524 - 7529; DOI:
10.1021/ja00545a022
PDF
Reaction progress at the transition state for nucleophilic attack on esters
Ildiko M. Kovach, James P. Elrod, and Richard L. Schowen
pp 7530 - 7534; DOI:
10.1021/ja00545a023
PDF
Acetone-sensitized photocoupling of 5-bromouridine to tryptophan derivatives via electron-transfer process
Satoru Ito, Isao Saito, and Teruo Matsuura
pp 7535 - 7541; DOI:
10.1021/ja00545a024
PDF
Dominant disrotatory double rotation in the thermally induced 1,2-dimethylspiropentane geometric isomerization
Joseph J. Gajewski and Ming Jing Chang
pp 7542 - 7545; DOI:
10.1021/ja00545a025
PDF
Reactions and properties of some trimethyleneplatinum(IV) complexes. 9. Chemistry of platinacyclobutanes derived from 1,2-disubstituted cyclopropanes
Razak J. Al-Essa, Richard J. Puddephatt, Peter J. Thompson, and Charles F. H. Tipper
pp 7546 - 7553; DOI:
10.1021/ja00545a026
PDF
Response of syn-1,2,3,4,5,6,7,8-octahydro-1,4:5,8-dimethanonaphthalene and related molecules to oxidation with ozone, singlet oxygen, and triplet oxygen. Strain and steric effects as controllers of reactivity
Leo A. Paquette and Richard V. C. Carr
pp 7553 - 7559; DOI:
10.1021/ja00545a027
PDF
Dioxygen transfer from 4a-hydroperoxyflavin anion. 3. Oxygen transfer to the 3-position of substituted indoles
Shigeaki Muto and Thomas C. Bruice
pp 7559 - 7564; DOI:
10.1021/ja00545a028
PDF
Synthesis and x-ray structural characterization of the [Rh22(.mu.3-CO)7(.mu.-CO)18(CO)12]4- anion, containing a large close-packed cluster with an ABAC sequence of compact layers
Secondo Martinengo, Gianfranco Ciani, and Angelo Sironi
pp 7564 - 7565; DOI:
10.1021/ja00545a029
PDF
Picosecond dynamics of the photoreduction of benzophenone by triethylamine
C. G. Schaefer and K. S. Peters
pp 7566 - 7567; DOI:
10.1021/ja00545a030
PDF
Synthesis of (.+-.)-illudol
M. F. Semmelhack, Shuji Tomoda, and K. M. Hurst
pp 7567 - 7568; DOI:
10.1021/ja00545a031
PDF
A convenient, stereospecific synthesis of (-)-phytuberin from (-)-2-carone
D. Caine and Troy L. Smith
pp 7568 - 7570; DOI:
10.1021/ja00545a032
PDF
Extension of the Woodward-Hoffmann rules to heterocyclic systems: stereospecific thermal isomerization of 1-azacyclobutene 1-oxides
M. L. M. Pennings, D. N. Reinhoudt, S. Harkema, and G. J. Van Hummel
pp 7570 - 7571; DOI:
10.1021/ja00545a033
PDF
Catalytically active models for the active site in carbonic anhydrase
J. Huguet and R. S. Brown
pp 7571 - 7572; DOI:
10.1021/ja00545a034
PDF
The ozonolysis of trifluoroethylene, 1,1-difluoroethylene, and perfluoroethylene. Epoxide and ozonide formation
John W. Agopovich and Charles W. Gillies
pp 7572 - 7574; DOI:
10.1021/ja00545a035
PDF
Serial cyclization of peroxy free radicals: models for polyolefin oxidation
Ned A. Porter, A. Nicholas Roe, and Andrew T. McPhail
pp 7574 - 7576; DOI:
10.1021/ja00545a036
PDF
Absolute rate constants for additions of phenylchlorocarbene to alkenes
Nicholas J. Turro, Jared A. Butcher, Robert A. Moss, Wenjeng Guo, Ramesh C. Munjal, and Michal Fedorynski
pp 7576 - 7578; DOI:
10.1021/ja00545a037
PDF
Reagents for organic synthesis: use of organostannyl oxides as catalytic neutral esterification agents in the preparation of macrolides
Kosta Steliou, A. Szczygielska-Nowosielska, A. Favre, M. A. Poupart, and Stephen Hanessian
pp 7578 - 7579; DOI:
10.1021/ja00545a038
PDF
The chemistry of tetrahedral intermediates. 5. Stereoelectronic control in the breakdown of hemiortho thio esters, RC(OR')SH
Moses K. Kaloustian and Farid Khouri
pp 7579 - 7581; DOI:
10.1021/ja00545a039
PDF
[20.10]-, [22.10]-, and [26.10]Betweenanenes, conformationally flexible bicyclic alkenes: synthesis, chemistry and optical resolution
James A. Marshall and T. Howard Black
pp 7581 - 7583; DOI:
10.1021/ja00545a040
PDF
An efficient total synthesis of (.+-.)-brefeldin-A
Andrew E. Greene, Claude Le Drian, and Pierre Crabbe
pp 7583 - 7584; DOI:
10.1021/ja00545a041
PDF
Cyclopropane-hydrogen chloride dimer: identification and geometry from its rotational spectrum
A. C. Legon, P. D. Aldrich, and W. H. Flygare
pp 7584 - 7585; DOI:
10.1021/ja00545a042
PDF
Total synthesis of dl-quassin
Paul A. Grieco, Sergio Ferrino, and Giovanni Vidari
pp 7586 - 7587; DOI:
10.1021/ja00545a043
PDF
Complete transfer of chirality in the [3,3]-sigmatropic rearrangement of allylic acetates catalyzed by palladium(II). Application to stereocontrolled syntheses of prostaglandins possessing either the C-15(S) or C-15(R) configuration
Paul A. Grieco, Tetsuo Takigawa, Shannon L. Bongers, and Hideo Tanaka
pp 7587 - 7588; DOI:
10.1021/ja00545a044
PDF
.alpha.-Chloro boronic esters from homologation of boronic esters
Donald S. Matteson and Debesh Majumdar
pp 7588 - 7590; DOI:
10.1021/ja00545a045
PDF
Directed chiral synthesis with pinanediol boronic esters
Donald S. Matteson and Rahul Ray
pp 7590 - 7591; DOI:
10.1021/ja00545a046
PDF
Superoxide-ion oxidation of hydrophenazines, reduced flavins, hydroxylamine, and related substrates via hydrogen-atom transfer
Edward J. Nanni and Donald T. Sawyer
pp 7591 - 7593; DOI:
10.1021/ja00545a047
PDF
Free radical and electron-transfer mechanisms for tertiary amine oxidation
Frederick D. Lewis and J. Thomas Simpson
pp 7593 - 7595; DOI:
10.1021/ja00545a048
PDF
A model for asymmetric induction in the Diels-Alder reaction
Barry M. Trost, David O'Krongly, and John L. Belletire
pp 7595 - 7596; DOI:
10.1021/ja00545a049
PDF
Changeover from rate-determining electron transfer to rate-determining proton transfer in the oxidation of alkyl aromatic compounds by ceric ammonium nitrate
Enrico Baciocchi, Luigi Mandolini, and Cesare Rol
pp 7597 - 7598; DOI:
10.1021/ja00545a050
PDF
Polyoxoanion-supported metal carbonyls: syntheses of the [(OC)3M(Nb2W4O19)]3- anions (M = rhenium and manganese)
C. J. Besecker and W. G. Klemperer
pp 7598 - 7600; DOI:
10.1021/ja00545a051
PDF
Hydrogen evolution from homogeneous reaction systems containing reduced molybdenum-iron-sulfur clusters
G. Christou, R. V. Hageman, and R. H. Holm
pp 7600 - 7601; DOI:
10.1021/ja00545a052
PDF
Ion pairing and solvent effects in the reactivity of anions towards free radicals
Glen A. Russell, Francisco Ros, and Boguslaw Mudryk
pp 7601 - 7603; DOI:
10.1021/ja00545a053
PDF
Substitution reactions of vinylmercurials by a free-radical chain mechanism
Glen A. Russell and James Hershberger
pp 7603 - 7604; DOI:
10.1021/ja00545a054
PDF
Reduction of carbon dioxide to carbon monoxide by transition-metal dianions
John M. Maher and N. John Cooper
pp 7604 - 7606; DOI:
10.1021/ja00545a055
PDF
Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning
Gary E. Maciel and Dean W. Sindorf
pp 7606 - 7607; DOI:
10.1021/ja00545a056
PDF
Chirality as a probe for the structure of 1,2-cycloheptadiene and 1,2-cyclohexadiene
Metin Balci and W. M. Jones
pp 7607 - 7608; DOI:
10.1021/ja00545a057
PDF
Macrocyclic inclusion complexes. Synthesis, complexation and x-ray crystal structures of binuclear cation complexes of dipyridine crown ethers
George R. Newkome, Dalip K. Kohli, Frank R. Fronczek, Brian J. Hales, Ellen E. Case, and Giacomo Chiari
pp 7608 - 7610; DOI:
10.1021/ja00545a058
PDF
Observation of large solvent effects on the phosphorus-31 NMR chemical shifts of nucleotides
Deborah B. Lerner and David R. Kearns
pp 7611 - 7612; DOI:
10.1021/ja00545a059
PDF
Total synthesis of (.+-.)-stemodin and (.+-.)-stemodinone
E. J. Corey, Marcus A. Tius, and Jagabandhu Das
pp 7612 - 7613; DOI:
10.1021/ja00545a060
PDF
Solvolysis of adamantanone cyanohydrin sulfonates. An evaluation of H/.alpha.-CN versus H/.beta.-CN rate ratios
Paul G. Gassman, Katsuhiro Saito, and John J. Talley
pp 7613 - 7615; DOI:
10.1021/ja00545a061
PDF
Enzymatic monooxygenation of halogen atoms: cytochrome P-450 catalyzed oxidation of iodobenzene by iodosobenzene
Leo T. Burka, Alice Thorsen, and F. Peter Guengerich
pp 7615 - 7616; DOI:
10.1021/ja00545a062
PDF
Enhanced stability of the imidazolate-bridged dicopper(II) ion in a binucleating macrocycle
P. K. Coughlin, S. J. Lippard, A. E. Martin, and J. E. Bulkowski
pp 7616 - 7617; DOI:
10.1021/ja00545a063
PDF
Additions and Corrections - Determination of the Absolute Configuration of a Secondary Hydroxy Group in a Chiral Secondary Alcohol Using Glycosidation Shifts in Carbon-13 Nuclear Magnetic Resonance Spectroscopy
S. Seo, Y. Tomita, K. Tori, and Y. Yoshimura
pp 7618 - 7618; DOI:
10.1021/ja00545a600
PDF
Additions and Corrections - Conformational Mobility and Optical Rotation Effects of Aromatic Nuclei
James H. Brewster, and J. George Buta
pp 7618 - 7618; DOI:
10.1021/ja00545a601
PDF
Additions and Corrections - Mechanistic Studies on the Catalysis of Isomerization of Olefins by (PPh3)3NiX
M. J. D'Aniello, Jr., and E. Kent Barefield
pp 7618 - 7618; DOI:
10.1021/ja00545a602
PDF
Additions and Corrections - N1'-Methylthiaminium Diiodide. Model Study on the Effect of Coenzyme Bound Positive Charge on Reaction Mechanism Requiring Thiamin Pyrophosphate
Frank Jordan, and Yitbarek H. Mariam
pp 7618 - 7618; DOI:
10.1021/ja00545a603
PDF
Additions and Corrections - Conformational Analysis of Tertiary Cycloalkyl (C6, C7, C8) Carbocations. Unexpected Preference for the Twist-Boat Conformation in the Cyclobexyl Case
Roger P. Kirchen, and Ted S. Sorensen
pp 7618 - 7618; DOI:
10.1021/ja00545a604
PDF
Additions and Corrections - Homogeneous Catalysis of the Water Gas Shift Reaction by Mixed Metal(Iron/Ruthenium) Catalysts
P. C. Ford, R. G. Rinker, C. Ungermann, R. J. Laine, V. Landis, and S. A. Moya
pp 7618 - 7618; DOI:
10.1021/ja00545a605
PDF
Additions and Corrections - Asymmetric Synthesis in a Confined Vortex: Gravitational Fields Can Cause Asymmetric Synthesis
Deborah Edwards, Keith Cooper, and Ralph C. Dougherty
pp 7618 - 7618; DOI:
10.1021/ja00545a606
PDF
Additions and Corrections - Chemistry at Liquid-Liquid Interfaces. Evidence for an SN1 Reaction Occuring at a Toulene-Water Interface
S. L. Regen, and J. J. Besse
pp 7619 - 7619; DOI:
10.1021/ja00545a607
PDF
Additions and Corrections - Deriving Intermolecular Potential Functions for the Water Dimer from Ab Initio Calculations
William L. Jorgensen
pp 7619 - 7619; DOI:
10.1021/ja00545a608
PDF
Additions and Corrections - An Investigation of the Reduction of Arydrazonium Ions by Hydrazines
W. T. Evanochko, and P. B. Shevlin
pp 7619 - 7619; DOI:
10.1021/ja00545a609
PDF
Additions and Corrections - Asymmetric Addition of Hydrogen Cyanide to Alkenes Catalyzed by a Zerovalent Palladium Compound
Patricia S. Elmes, and Roy Jackson
pp 7619 - 7619; DOI:
10.1021/ja00545a610
PDF
Additions and Corrections - Organic Electronic Spectral Data. Volume XV

pp 7619 - 7619; DOI:
10.1021/ja00545a611
PDF
Additions and Corrections - Monomeric Methyl Metaphosphate: Reactions with Carbonyl Groups.
Arnold C. Satterthwait, and F. H. Westheimer
pp 7619 - 7619; DOI:
10.1021/ja00545a612
PDF
Additions and Corrections - Photocalorimetric Studies of Singlet Oxygen Reactions
John Olmsted, III
pp 7619 - 7619; DOI:
10.1021/ja00545a613
PDF
Additions and Corrections - Competitive Oxidation Processes in the Reaction between (Dicyclopentadienyl)zirconium Bis(phosphine) Complexes and ALkyl Halides
G. M. Williams, K. I. Gell, and J. Schwartz
pp 7619 - 7619; DOI:
10.1021/ja00545a614
PDF
Additions and Corrections - Stereoselective Bifunctional Catalysis of Dedeuteration of Cyclopentanone-2,25,5,-d4 by (1R, 2S,3R, 4R)-3-Dimethylaminomethyl-1,7,7-trimethyl-2-norbornanamine
Jack Hine, Wu-Shyong Li, and James P. Zeigler
pp 7619 - 7619; DOI:
10.1021/ja00545a615
PDF
Additions and Corrections - Disproportionation among Aryloxyphosphoranes.
Irving S. Sigal, and F. H. Westheimer
pp 7619 - 7619; DOI:
10.1021/ja00545a616
PDF
Book Reviews

pp 7620 - 7628; DOI:
10.1021/ja00545a617
PDF

Issue 26


Electronic and photoelectron spectral studies of electroactive species attached to silanized carbon and platinum electrodes
K. W. Willman, R. D. Rocklin, R. Nowak, K. N. Kuo, F. A. Schultz, and Royce W. Murray
pp 7629 - 7634; DOI:
10.1021/ja00546a001
PDF
Carbon-13 nuclear magnetic resonance chemical shifts and polypeptide structure
Alan E. Tonelli
pp 7635 - 7637; DOI:
10.1021/ja00546a002
PDF
Determination of the absolute rates of decay of arylcarbenes in various low temperature matrixes by electron spin resonance spectroscopy
V. P. Senthilnathan and Matthew S. Platz
pp 7637 - 7643; DOI:
10.1021/ja00546a003
PDF
Methylsilylene, silaethylene, and silylmethylene: energies, structures, and unimolecular reactivities
John D. Goddard, Yasunori Yoshioka, and Henry F. Schaefer
pp 7644 - 7650; DOI:
10.1021/ja00546a004
PDF
An ab initio study of the electronic structure of the ground triplet and low-lying singlet states of formylnitrene, HCON and formylphosphinidene, HCOP
Aristides Mavridis and James F. Harrison
pp 7651 - 7655; DOI:
10.1021/ja00546a005
PDF
An ab initio study on ketene, hydroxyacetylene, formylmethylene, oxirene, and their rearrangement paths
Kiyoshi Tanaka and M. Yoshimine
pp 7655 - 7662; DOI:
10.1021/ja00546a006
PDF
Methoxy group rotation in alkylanisyl carbenium ions as a probe of the relative charge delocalization abilities of phenyl, cyclopropyl, and methyl groups
Roland Jost, Jean Sommer, Carin Engdahl, and Per Ahlberg
pp 7663 - 7667; DOI:
10.1021/ja00546a007
PDF
Unusual metal-carbon-hydrogen angles, carbon-hydrogen bond activation, and .alpha.-hydrogen abstraction in transition-metal carbene complexes
Richard J. Goddard, Roald Hoffmann, and Eluvathingal D. Jemmis
pp 7667 - 7676; DOI:
10.1021/ja00546a008
PDF
The role of Coulomb forces in the crystal packing of amides. A study based on experimental electron densities
Ziva Berkovitch-Yellin and Leslie Leiserowitz
pp 7677 - 7690; DOI:
10.1021/ja00546a009
PDF
Isolation and structural characterization of the triiron undecacarbonyl dianion [Fe3(CO)11]2-: stereochemical interrelationship with triiron dodecacarbonyl and the triiron undecacarbonyl hydride monoanion
Frederick Yip-Kwai Lo, Giuliano Longoni, Paolo Chini, Loren D. Lower, and Lawrence F. Dahl
pp 7691 - 7701; DOI:
10.1021/ja00546a010
PDF
Optical emission and absorption studies of silver atoms in rare gas matrixes at 12 K; silver atom cryophotoaggregation
S. A. Mitchell, J. Farrell, G. A. Kenney-Wallace, and G. A. Ozin
pp 7702 - 7709; DOI:
10.1021/ja00546a011
PDF
Solid-state resolution of binaphthyl: crystal and molecular structures of the chiral (A)1 form and racemic (B)1 form and the study of the rearrangement of single crystals. Requirements for development of hemihedral faces for enantiomer identification
Ruth B. Kress, Eileen N. Duesler, Margaret C. Etter, Iain C. Paul, and David Y. Curtin
pp 7709 - 7714; DOI:
10.1021/ja00546a012
PDF
Structure and behavior of spermidine siderophores
T. Peterson, Karl Erik Falk, Sally A. Leong, Melvin P. Klein, and J. B. Neilands
pp 7715 - 7718; DOI:
10.1021/ja00546a013
PDF
Molecular and crystal structure of the linear tricatechol siderophore, agrobactin
D. L. Eng-Wilmot and Dick Van der Helm
pp 7719 - 7725; DOI:
10.1021/ja00546a014
PDF
Role of epoxides in vicinal diol dehydrations. 5. A nuclear magnetic resonance kinetic and product study of the ring opening of propylene oxide. Nucleophilic and general catalysis by phosphate
Y. Pocker, B. P. Ronald, and L. Ferrin
pp 7725 - 7732; DOI:
10.1021/ja00546a015
PDF
The mechanism of hydrolysis of a cobalt(III)-bound phosphate ester: transphosphorylation from oxygen to nitrogen
John MacB. Harrowfield, David R. Jones, Leonard F. Lindoy, and Alan M. Sargeson
pp 7733 - 7741; DOI:
10.1021/ja00546a016
PDF
Steric effects on conformationally mobile systems. The iodomethylation of 1-methyl-2-arylpyrrolidines related to nicotine
Jeffrey I. Seeman, Henry V. Secor, Homer Hartung, and Roseanne Galzerano
pp 7741 - 7747; DOI:
10.1021/ja00546a017
PDF
Solvent effects in the photochemistry of xanthone
J. C. Scaiano
pp 7747 - 7753; DOI:
10.1021/ja00546a018
PDF
An electrically neutral .sigma.-sulfuranyl radical from the homolysis of a perester with neighboring sulfenyl sulfur: 9-S-3 species
C. W. Perkins, J. C. Martin, A. J. Arduengo, W. Lau, A. Alegria, and J. K. Kochi
pp 7753 - 7759; DOI:
10.1021/ja00546a019
PDF
Chemical and biological oxidation of organohalides. Peracid oxidation of alkyl iodides
Timothy L. Macdonald, N. Narasimhan, and Leo T. Burka
pp 7760 - 7765; DOI:
10.1021/ja00546a020
PDF
Photostimulated nucleophilic aromatic substitution for halides with carbon nucleophiles. Preparative and mechanistic aspects
M. F. Semmelhack and Thomas Bargar
pp 7765 - 7774; DOI:
10.1021/ja00546a021
PDF
Formation of a nonchemiluminescent excited-state species in the decomposition of 4a-(alkylperoxy)flavins
Peter T. Shepherd and Thomas C. Bruice
pp 7774 - 7776; DOI:
10.1021/ja00546a022
PDF
Effect of intercalating ligands on the phosphorus-31 chemical shift of DNA
Robert L. Jones and W. David Wilson
pp 7776 - 7778; DOI:
10.1021/ja00546a023
PDF
Singlet oxygen and spin trapping with nitrones
John R. Harbour, Sandra L. Issler, and Michael L. Hair
pp 7778 - 7779; DOI:
10.1021/ja00546a024
PDF
Evidence for an electron transfer mechanism in the reduction of ketones by main group metal hydrides
Eugene C. Ashby, Anil B. Goel, and Robert N. DePriest
pp 7779 - 7780; DOI:
10.1021/ja00546a025
PDF
Naphthonitrile-alkene exciplexes. Use of tethered chromophores to probe geometric factors in exciplex formation and decay
John J. McCullough, W. Keith MacInnis, Colin J. L. Lock, and Rommulo Faggiani
pp 7780 - 7782; DOI:
10.1021/ja00546a026
PDF
Copper(II) complexes of the antiulcer drug cimetidine
F. T. Greenaway, L. M. Brown, J. C. Dabrowiak, M. R. Thompson, and V. W. Day
pp 7782 - 7784; DOI:
10.1021/ja00546a027
PDF
Coordination stabilization of organic intermediates. Crystal structure of {[(en)2Co(SCH2CH2NH2)]2I}(NO3)5.4H2O, a stable complex of iodine(I)
Dennis L. Nosco, Mary Jane Heeg, Milton D. Glick, R. C. Elder, and Edward Deutsch
pp 7784 - 7786; DOI:
10.1021/ja00546a028
PDF
Further verification of fluorescence-detected circular dichroism
Eric W. Lobenstine and Douglas H. Turner
pp 7786 - 7787; DOI:
10.1021/ja00546a029
PDF
Cationic alkylidyne trirhodium cluster complexes. Crystal structure [(.eta.5-C5H5)3Rh3(.mu.-CO)2(.mu.3-CH)]PF6[tris(.eta.5-cyclopentadienyl)-bis(.mu.2-carbonyl)-.mu.3-methylidyne-trirhodium] hexafluorophosphate
P. A. Dimas, E. N. Duesler, R. J. Lawson, and J. R. Shapley
pp 7787 - 7789; DOI:
10.1021/ja00546a030
PDF
Reaction of diaryldiazomethanes with a metal-metal triple bond: synthesis, structural characterizations, and reactivity of novel bridging diazoalkane and alkylidene complexes
Louis Messerle and M. David Curtis
pp 7789 - 7791; DOI:
10.1021/ja00546a031
PDF
Antioxidant activity of vitamin E and related phenols. Importance of stereoelectronic factors
G. W. Burton, Y. Le Page, E. J. Gabe, and K. U. Ingold
pp 7791 - 7792; DOI:
10.1021/ja00546a032
PDF
Autoxidation of a model membrane. A comparison of the autoxidation of egg lecithin phosphatidylcholine in water and in chlorobenzene
L. R. C. Barclay and K. U. Ingold
pp 7792 - 7794; DOI:
10.1021/ja00546a033
PDF
Mechanistic aspects of the photochemistry of metal-metal bonds. Evidence for the intervention of two different primary photoproducts in the photochemistry of bis(.eta.5-cyclopentadienyl)tetracarbonyldiiron
Jonathan V. Caspar and Thomas J. Meyer
pp 7794 - 7795; DOI:
10.1021/ja00546a034
PDF
Hydrogen-bond and deprotonation effects on the resonance Raman iron-imidazole mode in deoxyhemoglobin models: implications for hemoglobin cooperativity
Paul Stein, Melody Mitchell, and Thomas G. Spiro
pp 7795 - 7797; DOI:
10.1021/ja00546a035
PDF
Correlation of kinetic isotope effects with free energies of reaction
A. J. Kresge
pp 7797 - 7798; DOI:
10.1021/ja00546a036
PDF
Hydroxymercuration of non-conjugated dienes in aqueous micelles
Cynthia M. Link, David K. Jansen, and Chaim N. Sukenik
pp 7798 - 7799; DOI:
10.1021/ja00546a037
PDF
Vinyl fluoride function as a terminator of biomimetic polyene cyclizations leading to steroids
William S. Johnson, G. William Daub, Terry A. Lyle, and Mineo Niwa
pp 7800 - 7802; DOI:
10.1021/ja00546a038
PDF
Reactions of .eta.5-C5H5(CO)2FeCHC6H5+ with alkenes and alkynes. Observation of efficient benzylidene-transfer reactions
M. Brookhart, M. B. Humphrey, H. J. Kratzer, and G. O. Nelson
pp 7802 - 7803; DOI:
10.1021/ja00546a039
PDF
Acepleiadylene dianion and tetraanion
Bernd C. Becker, Walter Huber, and Klaus Muellen
pp 7803 - 7805; DOI:
10.1021/ja00546a040
PDF
Synthesis of nicotinamide adenine dinucleotide (NAD) from adenosine monophosphate (AMP)
David R. Walt, Victor M. Rios-Mercadillo, Jacques Auge, and George M. Whitesides
pp 7805 - 7806; DOI:
10.1021/ja00546a041
PDF
Stereoselective generation of Z-enolates of thioamides: its application to diastereoselective aldol condensations and thio-Claisen rearrangements
Yoshinao Tamaru, Toshiro Harada, Seiichi Nishi, Masato Mizutani, Takeshi Hioki, and Zenichi Yoshida
pp 7806 - 7808; DOI:
10.1021/ja00546a042
PDF
Tantalum imido complexes
S. M. Rocklage and R. R. Schrock
pp 7808 - 7809; DOI:
10.1021/ja00546a043
PDF
Tantalum complexes containing diimido bridging dinitrogen ligands
Howard W. Turner, Jere D. Fellmann, Scott M. Rocklage, Richard R. Schrock, Melvyn Rowen Churchill, and Harvey J. Wasserman
pp 7809 - 7811; DOI:
10.1021/ja00546a044
PDF
Transformation of a molybdenum-alkylidyne complex into molecules containing vinylalkylidene and alkylidene ligands. Crystal and molecular structure of chelate [IMo:C(CH2CMe3)P(0)(0Me)2(P(0Me)3)(.eta.5-C5H5)]
Paul K. Baker, Geoffrey K. Barker, Michael Green, and Alan J. Welch
pp 7811 - 7812; DOI:
10.1021/ja00546a045
PDF
Crystal structure of a tetranuclear copper(II)-inosine monophosphate-o-phenanthroline complex: first unambiguous example of O6 coordination in a metal-6-oxopurine complex
Robert W. Gellert, Beda E. Fischer, and Robert Bau
pp 7812 - 7815; DOI:
10.1021/ja00546a046
PDF
Rearrangement of penicillin sulfoxides in base. Penicillin-derived sulfines
Jack E. Baldwin, Stephen R. Herchen, Guenter Schulz, Christopher P. Falshaw, and Trevor J. King
pp 7815 - 7816; DOI:
10.1021/ja00546a047
PDF
Hydrophobic acceleration of Diels-Alder reactions
Darryl C. Rideout and Ronald Breslow
pp 7816 - 7817; DOI:
10.1021/ja00546a048
PDF
Temperature and matrix effects on migratory aptitude and stereochemistry in 1,2-migration to a divalent carbon
Hideo Tomioka, Hiroaki Ueda, Shingo Kondo, and Yasuji Izawa
pp 7817 - 7818; DOI:
10.1021/ja00546a049
PDF
Accurate and sensitive determination, by a new cobalt-59 nuclear magnetic resonance method, of electron acceptance and hydrogen bond donation by protic solvents
Pierre Laszlo and Armel Stockis
pp 7818 - 7820; DOI:
10.1021/ja00546a050
PDF
Book Reviews

pp 7820 - 7830; DOI:
10.1021/ja00546a600
PDF

Issue 27


Theoretical models for mechanism and catalysis in carbonyl addition
Ian H. Williams, Gerald M. Maggiora, and Richard L. Schowen
pp 7831 - 7839; DOI:
10.1021/ja00547a001
PDF
The role of nonadiabatic coupling and sudden polarization in the photoisomerization of olefins
Maurizio Persico
pp 7839 - 7845; DOI:
10.1021/ja00547a002
PDF
ESR and optical studies of the interaction of alkali metal cryptates with the 9-fluorenone anion radical. Solvent effect on the equilibrium between contact and cryptand-separated ion pairs
Kazuo Nakamura
pp 7846 - 7848; DOI:
10.1021/ja00547a003
PDF
Gear effect. 9. Steric anisotropy of space through "Januslike" substituents. A dynamic proton and carbon-13 NMR study of 1,3-dibenzyl-4,5-diisopropylimidazoline-2-thione
Ulf Berg and Christian Roussel
pp 7848 - 7853; DOI:
10.1021/ja00547a004
PDF
Bromine as a partial oxidant. Oxidation state and charge transport in brominated nickel and palladium bis(diphenylglyoximates). A comparison with the iodinated materials and resonance Raman structure-spectra correlations for polybromides
Davida W. Kalina, Joseph W. Lyding, Mark T. Ratajack, Carl R. Kannewurf, and Tobin J. Marks
pp 7854 - 7862; DOI:
10.1021/ja00547a005
PDF
Synthesis and structure determination of 2-azabicyclo[2.2.1]hept-2-enes and their derivatives. W effect on chemical shifts
Michael E. Jung and Jerel J. Shapiro
pp 7862 - 7866; DOI:
10.1021/ja00547a006
PDF
Hypovalent radicals. 6. Electroreduction of diazodiphenylmethane - intermediacy of Ph2CN2-.cntdot. and Ph2C-.cntdot.
Richard N. McDonald, F. M. Triebe, J. R. January, K. J. Borhani, and M. D. Hawley
pp 7867 - 7872; DOI:
10.1021/ja00547a007
PDF
Crystal structures of the cyclic oligoesters from 6,8-dioxabicyclo[3.2.1]octan-7-one. 1. The cyclic dimer and the optically active cyclic tetramer
Isao Tanaka, Ichiro Tajima, Yasuhiro Hayakawa, Masahiko Okada, Masami Bitoh, Tamaichi Ashida, and Hiroshi Sumitomo
pp 7873 - 7876; DOI:
10.1021/ja00547a008
PDF
Decarboxylation of 6-nitrobenzisoxazole-3-carboxylate catalyzed by ammonium bilayer membranes. A comparison of the catalytic behavior of micelles, bilayer membranes, and other aqueous aggregates
Toyoki Kunitake, Yoshio Okahata, Reiko Ando, Seiji Shinkai, and Shinichi Hirakawa
pp 7877 - 7881; DOI:
10.1021/ja00547a009
PDF
Migration and partitioning of pyrene and perylene between lipid vesicles in aqueous solution studied with a fluorescence stopped-flow technique
Mats Almgren
pp 7882 - 7887; DOI:
10.1021/ja00547a010
PDF
Elimination and addition reactions. 36. Acceleration of nucleophilic eliminative ring fission by bond strain
Robert J. Palmer and Charles J. M. Stirling
pp 7888 - 7892; DOI:
10.1021/ja00547a011
PDF
Ground- and excited-state oxidation-reduction chemistry of (triphenyltin)- and (triphenylgermanium)tricarbonyl(1,10-phenanthroline)rhenium and related compounds
John C. Luong, Robert A. Faltynek, and Mark S. Wrighton
pp 7892 - 7900; DOI:
10.1021/ja00547a012
PDF
Ordered structure in dilute solutions of ionic biopolymers. 2. Small-angle x-ray scattering study of sodium polyacrylate solution
Norio Ise, Tsuneo Okubo, Kazuyuki Yamamoto, Hiromichi Kawai, Takeji Hashimoto, Mineo Fujimura, and Yuzuru Hiragi
pp 7901 - 7906; DOI:
10.1021/ja00547a013
PDF
Proximity of metal ions and hydrocarbon side chains of chelated .alpha.-amino acids and peptides
Per Ivar Vestues and R. Bruce Martin
pp 7906 - 7909; DOI:
10.1021/ja00547a014
PDF
1-(Arylthio)cyclopropanecarboxaldehydes. Conjunctive reagents for secoalkylation
Barry M. Trost and Louis N. Jungheim
pp 7910 - 7925; DOI:
10.1021/ja00547a015
PDF
Ultrasounds in organic syntheses. 1. Effect on the formation of lithium organometallic reagents
Jean Louis Luche and Jean Claude Damiano
pp 7926 - 7927; DOI:
10.1021/ja00547a016
PDF
Experimental proof for the gas-phase existence of the C.cntdot..cntdot..cntdot.C ring-opened trimethylene oxide cation: A new stable C3H6O+. isomer
Bruno C. Baumann, John K. MacLeod, and Leo Radom
pp 7927 - 7928; DOI:
10.1021/ja00547a017
PDF
Cyclic 4.pi. stabilization. Combined Moebius-Hueckel aromaticity in doubly lithium bridged R4C4Li2 systems
Alexander J. Kos and Paul von Rague Schleyer
pp 7928 - 7929; DOI:
10.1021/ja00547a018
PDF
Thionium ions as carbonyl substitutes. Synthesis of cyclic imino thioethers and lactams
Barry M. Trost, Michel Vaultier, and Maria L. Santiago
pp 7929 - 7932; DOI:
10.1021/ja00547a019
PDF
Synthesis of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acids
A. Miyashita, A. Yasuda, H. Takaya, K. Toriumi, T. Ito, T. Souchi, and R. Noyori
pp 7932 - 7934; DOI:
10.1021/ja00547a020
PDF
High-resolution solid-state phosphorus-31 nuclear magnetic resonance of some triphenylphosphine transition-metal complexes
J. W. Diesveld, E. M. Menger, H. T. Edzes, and W. S. Veeman
pp 7935 - 7936; DOI:
10.1021/ja00547a021
PDF
Deactivation of the fluorescent state of 9-tert-butylanthracene. 9-tert-Butyl-9,10(Dewar anthracene)
H. Guesten, M. Mintas, and L. Klasinc
pp 7936 - 7937; DOI:
10.1021/ja00547a022
PDF
Practical enzymic syntheses of ribulose 1,5 bisphosphate and ribose 5-phosphate
Chi-Huey Wong, Stephen D. McCurry, and George M. Whitesides
pp 7938 - 7939; DOI:
10.1021/ja00547a023
PDF
A photochromic swinging gate: platinum(II) chelate with a labile aldehyde
William G. Rohly and Kristin Bowman Mertes
pp 7939 - 7940; DOI:
10.1021/ja00547a024
PDF
Induction of olefin metathesis by acetylenes
Thomas J. Katz, Steven J. Lee, Mridula Nair, and Edward B. Savage
pp 7940 - 7942; DOI:
10.1021/ja00547a025
PDF
Reactivities of metal carbenes toward alkenes and alkynes
Thomas J. Katz, Edward B. Savage, Steven J. Lee, and Mridula Nair
pp 7942 - 7944; DOI:
10.1021/ja00547a026
PDF
Unusual interaction of iron-bleomycin with cyanide
Yukio Sugiura, Satoshi Ogawa, and Isao Morishima
pp 7944 - 7945; DOI:
10.1021/ja00547a027
PDF
An external point-charge model for bacteriorhodopsin to account for its purple color
Koji Nakanishi, Valeria Balogh-Nair, Maria Arnaboldi, Kazuo Tsujimoto, and Barry Honig
pp 7945 - 7947; DOI:
10.1021/ja00547a028
PDF
Opsin shifts in bovine rhodopsin and bacteriorhodopsin. Comparison of two external point-charge models
Michael G. Motto, Mordechai Sheves, Kazuo Tsujimoto, Valeria Balogh-Nair, and Koji Nakanishi
pp 7947 - 7949; DOI:
10.1021/ja00547a029
PDF
Reductive vinylation .alpha. to ketones
Conrad J. Kowalski and Jen-Sen Dung
pp 7950 - 7951; DOI:
10.1021/ja00547a030
PDF
Alkylaluminum chloride induced cyclization of unsaturated carbonyl compounds
Michael Karras and Barry B. Snider
pp 7951 - 7953; DOI:
10.1021/ja00547a031
PDF
Myricoside, an African armyworm antifeedant: separation by droplet countercurrent chromatography
Raymond Cooper, Philippa H. Solomon, Isao Kubo, Koji Nakanishi, James N. Shoolery, and John L. Occolowitz
pp 7953 - 7955; DOI:
10.1021/ja00547a032
PDF
Use of kinetic isotope effects in mechanism studies. 3. Measurement of hydrogen isotope effects on the primary chlorine isotope effect during elimination reactions
H. F. Koch, J. G. Koch, W. Tumas, D. J. McLennan, B. Dobson, and G. Lodder
pp 7955 - 7956; DOI:
10.1021/ja00547a033
PDF
Photoinduced electron-transfer reactions. Radical cations of the 1,2-diphenylcyclopropanes
Heinz D. Roth and Marcia L. Manion Schilling
pp 7956 - 7958; DOI:
10.1021/ja00547a034
PDF
Why is tetra-tert-butylcyclobutadiene almost square?
Weston Thatcher Borden and Ernest R. Davidson
pp 7958 - 7960; DOI:
10.1021/ja00547a035
PDF
Surface-enhanced resonance Raman scattering from cytochrome c and myoglobin adsorbed on a silver electrode
Therese M. Cotton, Steven G. Schultz, and Richard P. Van Duyne
pp 7960 - 7962; DOI:
10.1021/ja00547a036
PDF
Total synthesis of rifamycins. 1. Stereocontrolled synthesis of the aliphatic building block
H. Nagaoka, W. Rutsch, G. Schmid, H. Iio, M. R. Johnson, and Y. Kishi
pp 7962 - 7965; DOI:
10.1021/ja00547a037
PDF
Total synthesis of rifamycins. 2. Total synthesis of racemic rifamycin S
H. Iio, H. Nagaoka, and Y. Kishi
pp 7965 - 7967; DOI:
10.1021/ja00547a038
PDF
Chemistry of sulfenic acids. 2. Formation of hydrogen peroxide from sulfenic acids
Franklin A. Davis and Robert H. Jenkins
pp 7967 - 7969; DOI:
10.1021/ja00547a039
PDF
Reactions of metal complexes with carbohydrates. 1. Synthesis and characterization of novel blue paramagnetic nickel(II) complexes containing N-glycosides
Satoshi Takizawa, Hisashi Sugita, Shigenobu Yano, and Sadao Yoshikawa
pp 7969 - 7971; DOI:
10.1021/ja00547a040
PDF
Short syntheses of hirsutine and geissoschizine
Ernest Wenkert, Yashwant D. Vankar, and Jhillu S. Yadav
pp 7971 - 7972; DOI:
10.1021/ja00547a041
PDF
A new geometrical form for germanium. Synthesis and structure of tetraethylammonium 2-chloro-2,2'-spirobis(1,3,2-benzodioxa) germole (IV)
Arjun C. Sau, Roberta O. Day, and Robert R. Holmes
pp 7972 - 7973; DOI:
10.1021/ja00547a042
PDF
Synthesis and structural characterization of bimetallic iron-platinum carbonyl clusters: their relationship with bimetallic iron-palladium carbonyl clusters
Giuliano Longoni, Mario Manassero, and Mirella Sansoni
pp 7973 - 7974; DOI:
10.1021/ja00547a043
PDF
Evidence against phosphacylium cation participation in nucleophilic displacement at tetracoordinated phosphorus
J. Michalski, C. Radziejewski, Z. Skrzypczynski, and W. Dabkowski
pp 7974 - 7976; DOI:
10.1021/ja00547a044
PDF
Dissociation of the ethylene cation: mechanism of energy randomization
J. C. Lorquet, C. Sannen, and G. Raseev
pp 7976 - 7977; DOI:
10.1021/ja00547a045
PDF
Photochemical transformations. 29. Stereochemistry of photorearrangements and photosolvolyses in some dibenzobicyclooctadiene and benzotricyclooctene systems
Stanley J. Cristol, Robert J. Opitz, Thomas H. Bindel, and Wayne A. Dickenson
pp 7977 - 7978; DOI:
10.1021/ja00547a046
PDF
Reaction of tert-butylisocyanide with hexamethyltungsten. Synthesis and x-ray crystal structure of W-N(But)CMe2(Me)(NBut){N(But)(CMe:CMe2)}
Kwok W. Chiu, Richard A. Jones, Geoffrey Wilkinson, Anita M. R. Galas, and Michael B. Hursthouse
pp 7978 - 7979; DOI:
10.1021/ja00547a047
PDF
Radical rearrangements in the pyrolysis of allyldisilanes
Thomas J. Barton and Stephanie A. Jacobi
pp 7979 - 7981; DOI:
10.1021/ja00547a048
PDF
A new family of cation-binding compounds: threo-.alpha.,.omega.-poly(cyclooxalkane)diyl
William J. Schultz, Margaret C. Etter, Alphonsus V. Pocius, and Samuel Smith
pp 7981 - 7982; DOI:
10.1021/ja00547a049
PDF
Further characterization of the oxidation and spin states of iron in the nitrogen-bridged metalloporphyrin .mu.-nitrido-bis[(5,10,15,20-tetraphenylporphinato)iron]
G. Alan Schick and David F. Bocian
pp 7982 - 7984; DOI:
10.1021/ja00547a050
PDF
Leukotriene B. Total synthesis and assignment of stereochemistry
E. J. Corey, Anthony Marfat, Giichi Goto, and Francis Brion
pp 7984 - 7985; DOI:
10.1021/ja00547a051
PDF
Total Synthesis of 6-Trans, 10-cis and (plus or minus) -6-Trans,8-cis Isomers of Leukotriene B
E. J. Corey, Paul B. Hopkins, John E. Munroe, Anthony Marfat, and Shun-ichi Hashimoto
pp 7986 - 7987; DOI:
10.1021/ja00547a600
PDF
Stereospecific synthesis of dl-isoepoxydon, a new metabolite of importance to the patulin pathway
David Teh-Wei Chou and Bruce Ganem
pp 7987 - 7988; DOI:
10.1021/ja00547a052
PDF
Taft .sigma.* values of alkyl groups: an artifact
DeLos F. DeTar
pp 7988 - 7990; DOI:
10.1021/ja00547a053
PDF
Triangular triniobium cluster in aqueous solution
Avi Bino
pp 7990 - 7991; DOI:
10.1021/ja00547a054
PDF
Isolation and structure of spatol, a potent inhibitor of cell replication from the brown seaweed Spatoglossum schmittii
William H. Gerwick, William Fenical, Donna Van Engen, and Jon Clardy
pp 7991 - 7993; DOI:
10.1021/ja00547a055
PDF
Stereospecific synthesis of retronecine by imidate methylide cycloaddition
E. Vedejs and G. R. Martinez
pp 7993 - 7994; DOI:
10.1021/ja00547a056
PDF
Thermal reactions of 2,3-diazabicyclo[2.2.0]hex-2-ene. The first example of a disrotatory diazacyclobutene ring opening
Eva A. Wildi, Donna Van Engen, and Barry K. Carpenter
pp 7994 - 7996; DOI:
10.1021/ja00547a057
PDF
Book Reviews

pp 7996 - 7998; DOI:
10.1021/ja00547a601
PDF